Self-assembled borophene/graphene nanoribbon mixed-dimensional heterostructures and method of synthesizing same
This invention in one aspect relates to a method of synthesizing a self-assembled mixed-dimensional heterostructure including 2D metallic borophene and 1D semiconducting armchair-oriented graphene nanoribbons (aGNRs). The method includes depositing boron on a substrate to grow borophene thereon at a substrate temperature in an ultrahigh vacuum (UHV) chamber; sequentially depositing 4,4″-dibromo-p-terphenyl on the borophene grown substrate at room temperature in the UHV chamber to form a composite structure; and controlling multi-step on-surface coupling reactions of the composite structure to self-assemble a borophene/graphene nanoribbon mixed-dimensional heterostructure. The borophene/aGNR lateral heterointerfaces are structurally and electronically abrupt, thus demonstrating atomically well-defined metal-semiconductor heterojunctions.
1. A composition, comprising:
a self-assembled mixed-dimensional heterostructure comprising 2D metallic borophene and 1D semiconducting armchair-oriented graphene nanoribbons (aGNRs) defining a borophene/aGNR lateral heterostructure in which a borophene domain is in direct contact with at least one of the aGNRs.
2. The composition of claim 1 , wherein the borophene/aGNR lateral heterostructure comprises aligned, armchair-oriented graphene nanoribbons that are three carbon atoms wide (3-aGNRs) with structural heterointerfaces with borophene.
3. The composition of claim 2 , wherein a width of the aGNRs is about 0.5 nm, and an average distance between two adjacent 3-aGNRs is about 1.0 nm ±0.1 nm.
4. The composition of claim 2 , wherein the borophene/aGNR lateral heterostructure has apparently dimmer rows located between adjacent parallel 3-aGNRs including Br atoms.
5. The composition of claim 2 , wherein an orientation of the 3-aGNRs is 30° rotated with respect to a boron row direction in borophene.
6. The composition of claim 2 , wherein the borophene/aGNR lateral heterostructure has characteristics of metallic borophene on a borophene side, and a semiconducting bandgap on a 3-aGNR side.
7. The composition of claim 6 , wherein a metal-semiconductor heterojunction between borophene and 3-aGNRs is electronically abrupt with no evidence of interface states.