IP Library › Granted Patent US 11,802,194
Granted Patent B2
US 11,802,194 · App. 17/746,489 · Granted Oct 31, 2023

Rubber composition including a specific hydrocarbon resin

Inventors: Benoit De Gaudemaris (Clermont-Ferrand, FR); Alain Hut (Clermont-Ferrand, FR)
Assignee: COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELIN
C08L9/00B60C1/0016C08K3/013C08L21/00C08L45/00
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Quick Facts
Patent No.
US 11,802,194
App. No.
17/746,489
Granted
Oct 31, 2023
Kind
B2
Abstract

A rubber composition is based on at least one elastomer, a reinforcing filler, a crosslinking system and an optionally hydrogenated hydrocarbon-based resin, predominantly composed of units selected from the group consisting of cyclopentadiene, dicyclopentadiene, methylcyclopentadiene and mixtures thereof, said hydrocarbonbased resin having an average molecular weight Mz of less than 2000 g/mol and a glass transition temperature Tg, expressed in ° C., such that: Tg≥80−2*(% HA), wherein % HA represents the content of aromatic protons of said resin, the content of said hydrocarbon-based resin being within a range extending from 15 to 150 phr.

Claims (27)

1. A tire comprising a rubber composition present in all or part of the tread of the tire, the rubber composition being based on:

at least one elastomer;

a reinforcing filler;

a crosslinking system; and

an optionally hydrogenated hydrocarbon-based resin, predominantly composed of units selected from the group consisting of cyclopentadiene, dicyclopentadiene, methylcyclopentadiene and mixtures thereof, the hydrocarbon-based resin having an average molecular weight Mz of less than 2000 g/mol and a glass transition temperature Tg, expressed in ° C., such that Tg≥ 80−2*(% HA), wherein % HA represents the content of aromatic protons of the hydrocarbon-based resin,

wherein the rubber composition comprises 100 phr of the at least one elastomer, the at least one elastomer having a Tg of between −80° C. and −110° C. and being an essentially unsaturated diene elastomer selected from the group consisting of polybutadienes, copolymers of butadiene and styrene, and mixtures thereof,

wherein the content of the hydrocarbon-based resin is within a range extending from 40 to 115 phr, and

wherein the reinforcing filler is a combination of silica and carbon black, and a content of the reinforcing filler is present within a range extending from 40 to 160 phr, the silica being present in a content within a range extending from 40 to 150 phr.

2. The tire according to claim 1 , wherein said hydrocarbon-based resin has an Mz of less than 1500 g/mol.

3. The tire according to claim 1 , wherein said hydrocarbon-based resin has a glass transition temperature Tg, expressed in ° C., such that Tg≥85−2*(% HA).

4. The tire according to claim 1 , wherein said hydrocarbon-based resin has a polydispersity index PI of less than 1.7.

5. The tire according to claim 4 , wherein said hydrocarbon-based resin has a polydispersity index PI of less than 1.6.

6. The tire according claim 1 , wherein said hydrocarbon-based resin has a content of aromatic protons of less than 50%.

7. The tire according to claim 6 , wherein said hydrocarbon-based resin has a content of aromatic protons within a range extending from 0% to 20%.

8. The tire according to claim 7 , wherein said hydrocarbon-based resin has a content of aromatic protons within a range extending from 0% to 15%.

9. The tire according to claim 8 , wherein said hydrocarbon-based resin has a content of aromatic protons of less than 5%.

10. The tire according to claim 9 , wherein said hydrocarbon-based resin has a content of aromatic protons within a range extending from 0% to 4%.

11. The tire according to claim 10 , wherein said hydrocarbon-based resin has a content of aromatic protons within a range extending from 0% to 2%.

12. The tire according to claim 11 , wherein said hydrocarbon-based resin has a content of aromatic protons of 0%.

13. The tire according to claim 7 , wherein said hydrocarbon-based resin has a content of aromatic protons within a range extending from 3% to 15%.

14. The tire according to claim 13 , wherein said hydrocarbon-based resin has a content of aromatic protons within a range extending from 5% to 10%.

15. The tire according to claim 1 , wherein said hydrocarbon-based resin has a content of ethylenic protons of less than 0.5%.

16. The tire according to claim 15 , wherein said hydrocarbon-based resin has a content of ethylenic protons of less than 0.1%.

17. The tire according to claim 15 , wherein said hydrocarbon-based resin does not comprise any ethylenic units.

18. The tire according to claim 1 , wherein the at least one elastomer predominantly comprises an elastomer having a glass transition temperature Tg of between −90° C. and −110° C.

19. The tire according to claim 1 , wherein the content of said hydrocarbon-based resin is within a range extending from 25 to 120 phr.

20. The tire according to claim 19 , wherein the content of said hydrocarbon-based resin is within a range extending from 40 to 115 phr.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 19, 2023
From: DE GAUDEMARIS, BENOIT; HUT, ALAIN
To: COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELIN
Reel/Frame 064957/0263 →
Priority Claims (1)
FR 1559874 · Oct 16, 2015 · national
Continuity (2)
Continuation 15768114
Related Publication 20220363875A1 · Nov 17, 2022