IP Library Granted Patent US 12,558,825
Granted Patent B2
US 12,558,825 · App. 17/752,275 · Granted Feb 24, 2026

Mechanical reticulation of polymeric-based closed cell foams

Inventors: Jennifer N. Rodriguez (Lathrop, CA); Duncan J. Maitland (College Station, TX); Thomas S. Wilson (San Leandro, CA)
Assignees: Lawrence Livermore National Security, LLC; The Texas A&M University System
B29C44/5663A61L31/06A61L31/146B29C66/02242B32B5/18B32B5/32C08G18/3228C08G18/3278C08G18/3284C08G18/73C08J9/38C08L75/04A61L2400/16B29C2793/0045B29K2075/00B29K2105/046B29K2995/0093B32B2266/0278B32B2266/08B32B2535/00C08G2101/00C08J2205/052C08J2207/10C08J2375/04C08L2201/12C08L2203/14
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Quick Facts
Patent No.
US 12,558,825
App. No.
17/752,275
Granted
Feb 24, 2026
Kind
B2
Abstract

Polymeric based closed cell foams, such as shape memory polymer foams, contain bubbles. Making these bubbles continuous is called reticulation. Disclosed are embodiments of a device and method to controllably reticulate polymer-based closed cell foams by puncturing the membranes of these polymer-based closed cell foams.

Claims (58)

1 . A method comprising:

coupling a polymeric-based closed cell foam to a vibrator, wherein the foam includes: (a)(i) first and second cells that share a ring of struts, the ring of struts providing structural support for the first and second cells, and (a)(ii) a membrane directly contacting the ring of struts;

coupling an array of needles to the foam;

vibrating the foam with the vibrator;

in response to vibrating the foam and gravitational forces pulling at least one of the needles down through at least a portion of the foam, (b)(i) contacting the at least one of the needles against at least one of the struts, (b)(ii) decoupling the at least one of the needles from the at least one of the struts and then coupling the at least one of the needles to the membrane, and (b)(iii) puncturing the membrane with the at least one of the needles and then puncturing additional membranes, also included in the foam, with the at least one of the needles.

2 . The method of claim 1 comprising:

coupling an additional polymeric-based closed cell foam to the vibrator, wherein the additional foam includes: (a)(i) additional first and second cells that share an additional ring of additional struts, the additional ring of additional struts providing structural support for the additional first and second cells, and (a)(ii) an additional membrane directly contacting the additional ring of additional struts;

coupling an additional array of needles to the additional foam;

vibrating the additional foam with the vibrator;

in response to vibrating the additional foam and gravitational forces pulling at least one of the additional array of needles down through at least a portion of the additional foam, (b)(i) contacting the at least one of the additional array of needles against at least one of the additional struts, (b)(ii) decoupling the at least one of the additional array of needles from the at least one of the additional struts and then coupling the at least one of the additional array of needles to the additional membrane, and (b)(iii) puncturing the additional membrane with the at least one of the additional array of needles;

wherein the foam and the additional foam have different chemical compositions;

wherein the array of needles includes a first number of needle systems having a first collective mass and the additional array of needles includes a second number of needle systems, equal to the first number of needle systems, having a second collective mass unequal to the first collective mass.

3 . The method of claim 2 , wherein:

vibrating the foam with the vibrator includes oscillating the foam at at least one of a first frequency and a first amplitude;

vibrating the additional foam with the vibrator includes oscillating the additional foam at at least one of a second frequency and a second amplitude;

at least one of (a) the first and second frequencies are unequal, (b) the first and second amplitudes are unequal, or (c) combinations thereof.

4 . The method of claim 3 , wherein the needles are superelastic when contacting at least one of the needles against at least one of the struts.

5 . The method of claim 1 comprising:

coupling an additional polymeric-based closed cell foam to the vibrator, wherein the additional foam includes: (a)(i) additional first and second cells that share an additional ring of additional struts, the additional ring of additional struts providing structural support for the additional first and second cells, and (a)(ii) an additional membrane directly contacts the additional ring of additional struts;

coupling an additional array of needles to the additional foam;

vibrating the additional foam with the vibrator;

in response to vibrating the additional foam and gravitational forces pulling at least one of the additional array of needles down through at least a portion of the additional foam, (b)(i) contacting the at least one of the additional array of needles against at least one of the additional struts, (b)(ii) decoupling the at least one of the additional array of needles from the at least one of the additional struts and then coupling the at least one of the additional array of needles to the additional membrane, and (b)(iii) puncturing the additional membrane with the at least one of the additional array of needles;

wherein the foam and the additional foam have equivalent chemical compositions;

wherein the array of needles includes a first number of needle systems having a first collective mass and the additional array of needles includes a second number of needle systems, equal to the first number of needle systems, having a second collective mass unequal to the first collective mass;

wherein the foam with the punctured membranes is at least 10% more permeable than the additional foam with the additional punctured membrane.

6 . The method of claim 5 , wherein:

vibrating the foam with the vibrator includes oscillating the foam at at least one of a first frequency and a first amplitude;

vibrating the additional foam with the vibrator includes oscillating the additional foam at at least one of a second frequency and a second amplitude;

at least one of (a) the first and second frequencies are unequal, (b) the first and second amplitudes are unequal, or (c) combinations thereof.

7 . The method of claim 6 , wherein the needles are superelastic when contacting at least one of the needles against at least one of the struts.

8 . The method of claim 1 comprising:

coupling an additional polymeric-based closed cell foam to the vibrator, wherein the additional foam includes: (a)(i) additional first and second cells that share an additional ring of additional struts, the additional ring of additional struts providing structural support for the additional first and second cells, and (a)(ii) an additional membrane directly contacts the additional ring of additional struts;

coupling an additional array of needles to the additional foam;

vibrating the additional foam with the vibrator;

in response to vibrating the additional foam and gravitational forces pulling at least one of the additional array of needles down through at least a portion of the additional foam, (b)(i) contacting the at least one of the additional array of needles against at least one of the additional struts, (b)(ii) decoupling the at least one of the additional array of needles from the at least one of the additional struts and then coupling the at least one of the additional array of needles to the additional membrane, and (b)(iii) puncturing the additional membrane with the at least one of the additional array of needles;

wherein the foam and the additional foam have equivalent chemical compositions;

wherein vibrating the foam with the vibrator includes oscillating the foam at at least one of a first frequency and a first amplitude;

wherein vibrating the additional foam with the vibrator includes oscillating the additional foam at at least one of a second frequency and a second amplitude;

wherein at least one of (a) the first and second frequencies is unequal, (b) the first and second amplitudes are unequal, or (c) combinations thereof.

9 . The method of claim 8 , wherein the needles are superelastic when contacting at least one of the needles against at least one of the struts.

10 . A method comprising:

coupling a closed cell foam to a vibrator, wherein the foam includes: (a)(i) first and second cells that share a strut, and (a)(ii) a membrane directly contacting the strut;

coupling first and second needles to the foam;

vibrating the foam with the vibrator;

in response to vibrating the foam and gravitational forces pulling the first needle through at least a portion of the foam, (b)(i) contacting the first needle against the strut, (b)(ii) decoupling the first needle from the strut and then coupling the first needle to the membrane, and (b)(iii) puncturing the membrane with the first needle and then puncturing additional membranes, also included in the foam, with the first needle to form a contiguous fluid path within the foam.

11 . The method of claim 10 comprising:

coupling an additional closed cell foam to the vibrator, wherein the additional foam includes: (a)(i) additional first and second cells that share an additional strut, and (a)(ii) an additional membrane directly contacting the additional strut;

coupling additional first and second needles to the additional foam;

vibrating the additional foam with the vibrator;

in response to vibrating the additional foam and gravitational forces pulling the additional first needle through at least a portion of the additional foam, (b)(i) contacting the additional first needle against the additional strut, (b)(ii) decoupling the additional first needle from the additional strut and then coupling the additional first needle to the additional membrane, and (b)(iii) puncturing the additional membrane with the additional first needle;

wherein the foam and the additional foam have different chemical compositions;

wherein the first and second needles are included in first and second needle systems having a first collective mass and the additional first and second needles are included in additional first and second needle systems having a second collective mass unequal to the first collective mass.

12 . The method of claim 11 , wherein:

vibrating the foam with the vibrator includes oscillating the foam at at least one of a first frequency and a first amplitude;

vibrating the additional foam with the vibrator includes oscillating the additional foam at at least one of a second frequency and a second amplitude;

at least one of (a) the first and second frequencies are unequal, (b) the first and second amplitudes are unequal, or (c) combinations thereof.

13 . The method of claim 1 including coupling the array of needles respectively into an array of channels of a platform, wherein the array of needles are slidingly engaged with the array of channels.

14 . The method of claim 10 including coupling the first and second needles respectively into first and second channels of one or more platforms, wherein the first and second needles are slidingly engaged with the first and second channels.

Assignments (3)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 26, 2026
From: RODRIGUEZ, JENNIFER N.; WILSON, THOMAS S.
To: LAWRENCE LIVERMORE NATIONAL SECURITY, LLC
Reel/Frame 074754/0330 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 26, 2026
From: RODRIGUEZ, JENNIFER N.; MAITLAND, DUNCAN J.
To: THE TEXAS A&M UNIVERSITY SYSTEM
Reel/Frame 074754/0356 →
CONFIRMATORY LICENSE (SEE DOCUMENT FOR DETAILS) Recorded Aug 31, 2022
From: LAWRENCE LIVERMORE NATIONAL SECURITY, LLC
To: U.S. DEPARTMENT OF ENERGY
Reel/Frame 061361/0738 →
Continuity (4)
Continuation 16870094 · May 8, 2020
Continuation 15232619 · Aug 9, 2016
Provisional Application 62203297 · Aug 10, 2015
Related Publication 20220288822A1 · Sep 15, 2022
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