Method for preparing an inverse emulsion comprising two cationic polymers
This invention relates to a process for preparing an inverse emulsion comprising mixing an aqueous solution comprising a water-soluble (co)polymer A synthesized from at least one cationic monomer and an inverse EMI 2 emulsion comprising a water-soluble (co)polymer B synthesized from at least one cationic monomer, optionally followed by distillation. This invention also relates to the inverse emulsion thus obtained, a detergent or cosmetic or softening composition comprising such an inverse emulsion, as well as the use of such an inverse emulsion to improve the softening properties of a fabric softening composition.
1. A process for preparing an inverse EMI 1 emulsion comprising the following step:
forming an inverse EMI 1 emulsion by mixing an aqueous solution of water-soluble (co)polymer A of at least one cationic monomer and an inverse EMI 2 emulsion of water-soluble (co)polymer B of at least one cationic monomer.
2. The process for the preparation of an inverse emulsion according to claim 1 , wherein water-soluble (co)polymers A and B are synthetic (co)polymers obtained, independently of each other, from at least one cationic monomer and at least one non-ionic monomer and/or of at least one anionic monomer.
3. The process for the preparation of an inverse emulsion according to claim 1 , wherein water-soluble (co)polymers A and B are, independently of each other, synthetic (co)polymers of at least one cationic monomer selected from quaternized dimethylaminoethyl acrylate (ADAME), quaternized dimethylaminoethyl methacrylate (MADAME), dimethyldiallylammonium chloride (DADMAC), acrylamido propyltrimethyl ammonium chloride (APTAC), methacrylamido propyltrimethyl ammonium chloride (MAPTAC), and mixtures thereof.
4. The process for the preparation of an inverse emulsion according to claim 1 , wherein water-soluble (co)polymer A and water-soluble (co)polymer B are, independently of each other, (co)polymers:
of at least one cationic monomer, and
of at least one non-ionic monomer and/or at least one anionic monomer, the non-ionic monomer being chosen from acrylamide, methacrylamide, N-isopropylacrylamide, N,N-dimethylacrylamide and N-methylolacrylamide, N-vinylformamide, N-vinyl acetamide, N-vinylpyridine and N-vinylpyrrolidone, acryloyl morpholine (ACMO), diacetone acrylamide, and mixtures thereof.
5. The process for the preparation of an inverse emulsion according to claim 1 , wherein water-soluble (co)polymer A and water-soluble (co)polymer B are, independently of each other, (co)polymers:
of at least one cationic monomer, and
of at least one anionic monomer and/or at least one non-ionic monomer the anionic monomer chosen from acrylic acid, methacrylic acid, itaconic acid, maleic acid, 2-acrylamido-2-methylpropane sulfonic acid (ATBS), vinylsulfonic acid, vinylphosphonic acid and mixtures thereof, said anionic monomer being non-salified, partially or totally salified, and the salts of 3-sulfopropyl methacrylate.
6. The process for the preparation of an inverse emulsion according to claim 1 , wherein water-soluble (co)polymer A is a water-soluble (co)polymer synthesized from at least one cationic monomer and from at least one anionic monomer, water-soluble (co)polymer A having an overall cationic charge.
7. The process for the preparation of an inverse emulsion according to claim 1 , wherein water-soluble (co)polymer B is a cross-linked water-soluble (co)polymer.
8. The process for the preparation of an inverse emulsion according to claim 1 , wherein the inverse EMI 1 emulsion comprises a total concentration of water-soluble (co)polymers A and B of between 5 and 50% weight relative to the total weight of the inverse EMI 1 emulsion.
9. The process for the preparation of an inverse emulsion according to claim 1 , wherein the process comprises a subsequent step of forming an inverse EMI 3 emulsion by distillation of the inverse EMI 1 emulsion.
10. The process for the preparation of an inverse emulsion according to claim 1 , wherein the process comprises a subsequent step of forming an inverse EMI 3 emulsion by distillation of the inverse EMI 1 emulsion, the inverse EMI 3 emulsion with a total concentration of water-soluble (co)polymers A and B of between 20 and 80% by weight relative to the total weight of the inverse EMI 3 emulsion.
11. The process for the preparation of an inverse emulsion according to claim 1 , wherein the process comprises a subsequent step of forming an inverse EMI 3 emulsion by distillation of the inverse EMI 1 emulsion, the inverse EMI 3 emulsion having a total concentration of water-soluble (co)polymers A and B of between 35 and 60% by weight relative to the total weight of the inverse EMI 3 emulsion.
12. The process for the preparation of an inverse emulsion according to claim 11 , wherein the inverse EMI 1 or EMI 3 emulsion has a mass ratio between the water-soluble (co)polymer B and water-soluble (co)polymer A between 1 and 100.
13. The process for the preparation of an inverse emulsion according to claim 6 , wherein water-soluble (co)polymer B is a cross-linked water-soluble (co)polymer.
14. The process for the preparation of an inverse emulsion according to claim 2 , wherein:
the at least one cationic monomer is selected from quaternized dimethylaminoethyl acrylate (ADAME), quaternized dimethylaminoethyl methacrylate (MADAME), dimethyldiallylammonium chloride (DADMAC), acrylamido propyltrimethyl ammonium chloride (APTAC), methacrylamido propyltrimethyl ammonium chloride (MAPTAC), and mixtures thereof;
the at least one non-ionic monomer is selected from acrylamide, methacrylamide, N-isopropylacrylamide, N,N-dimethylacrylamide and N-methylolacrylamide, N-vinylformamide, N-vinyl acetamide, N-vinylpyridine and N-vinylpyrrolidone, acryloyl morpholine (ACMO), diacetone acrylamide, and mixtures thereof; and
the at least one anionic monomer is selected from acrylic acid, methacrylic acid, itaconic acid, maleic acid, 2-acrylamido-2-methylpropane sulfonic acid (ATBS), vinylsulfonic acid, vinylphosphonic acid and mixtures thereof, said anionic monomer being non-salified, partially or totally salified, and the salts of 3-sulfopropyl methacrylate.
15. The process for the preparation of an inverse emulsion according to claim 14 , wherein water-soluble (co)polymer A is a water-soluble (co)polymer synthesized from at least one cationic monomer and from at least one anionic monomer, water-soluble (co)polymer A having an overall cationic charge.
16. The process for the preparation of an inverse emulsion according to claim 5 , wherein water-soluble (co)polymer B is a cross-linked water-soluble (co)polymer.
17. The process for the preparation of an inverse emulsion according to claim 16 , wherein:
the inverse EMI 1 emulsion comprises a total concentration of water-soluble (co)polymers A and B of between 5 and 50% weight relative to the total weight of the inverse EMI 1 emulsion;
the process comprises a subsequent step of forming an inverse EMI 3 emulsion by distillation of the inverse EMI 1 emulsion, the inverse EMI 3 emulsion with a total concentration of water-soluble (co)polymers A and B of between 35 and 60% by weight relative to the total weight of the inverse EMI 3 emulsion; and
the inverse EMI 1 or EMI 3 emulsion has a mass ratio between the water-soluble (co)polymer B and water-soluble (co)polymer A between 5 and 14.