Method for parameter estimation in an impedance model of a lithium ion cell

1. A method for ascertaining parameters of an equivalent circuit diagram for representing an impedance of a lithium ion cell, wherein the equivalent circuit diagram comprises at least one RC element having an ohmic resistance R 1 , a capacitance C 1 , and a series resistance Rs, and the parameters comprise the ohmic resistance R 1 , the capacitance C 1 , and the series resistance Rs, the method comprising the steps of:

(a) performing a first measurement in order to determine at least a real part of the impedance of the cell at a first frequency above 300 Hz;

(b) ascertaining the series resistance Rs from the measured real part of the impedance;

(c) performing at least one further measurement in order to determine the real part and an imaginary part, and/or an absolute value and a phase of the impedance of the cell at at least one further frequency that is lower than the first frequency;

(d) subtracting at least the series resistance Rs from a result of the at least one further measurement; and

(e) ascertaining the ohmic resistance R 1 and the capacitance C 1 from the result.

2. The method according to claim 1 , wherein the first measurement is also performed to determine the imaginary part of the impedance of the cell at the first frequency.

3. The method according to claim 1 , wherein the equivalent circuit diagram further comprises a series inductance L, and step (d) further comprises subtracting an impedance contribution of the inductance iωL, wherein ω=2πf and f is a frequency at which a respective measurement was performed.

4. The method according to claim 3 , wherein, in step (a), the imaginary part is also measured and the inductance is calculated from the imaginary part.

5. The method according to claim 3 , wherein frequencies f 1 , f 2 , f 3 and f 4 are used for the measurements in steps (a) and (c):

f 1 is a frequency at which a Nyquist plot of the impedance of the equivalent circuit diagram has a zero crossing;

f 2 is a frequency of 300 Hz or more, and is at least 5 times f 1 ,

f 3 is a frequency at which the Nyquist plot of the impedance of the equivalent circuit diagram has an extreme value; and

f 4 is a frequency in a range from 10 to 50 Hz; and

wherein f 2 , as a highest frequency, corresponds to the first frequency in step (a).

6. The method according to claim 5 , wherein f 1 and f 3 are calculated from initial parameters or parameters of the equivalent circuit diagram estimated by a previous run of the method.

7. The method according to claim 1 , wherein the equivalent circuit diagram comprises at least one further RC element having parameters R 2 and C 2 .

8. A model-based method for monitoring a lithium ion cell and forecasting future power characteristics, the method comprising:

providing the equivalent circuit diagram for representing the impedance of the lithium ion cell;

ascertaining the parameters of the equivalent circuit diagram, including Rs, R 1 and C 1 , using the method according claim 1 ;

ascertaining a temperature and a state of charge; and

ascertaining a state of health and forecasting the future power characteristics of the cell based on the parameters of the equivalent circuit diagram by incorporating the temperature and the state of charge.

9. A battery system, comprising:

a plurality of lithium ion cells;

a signal generator for generating a current or voltage signal as an excitation signal, wherein the system is not intended for use with an external excitation signal;

a voltage or current measurement apparatus for each cell, wherein the voltage or current measurement apparatus is configured to measure a response signal in response to the excitation signal;

a battery management system comprising a controller, wherein an equivalent circuit diagram for representing the impedance of the lithium ion cell is provided in a memory of the controller, and wherein, the equivalent circuit diagram comprises the at least one RC element with the ohmic resistance R 1 , the capacitance C 1 , and the series resistance Rs, and

the battery management system is configured to monitor the lithium ion cells using the method according to claim 8 .