IP Library Granted Patent US 12,435,209
Granted Patent B2
US 12,435,209 · App. 17/769,033 · Granted Oct 7, 2025

Liquid additive composition

Inventor: Inga Maurer (Denver, NC)
Assignee: Avient Switzerland GmbH
C08K13/02C08J3/22C08J5/18C08L23/06C08L27/16C08J2323/06C08J2423/20C08J2427/16C08K3/36C08K5/13C08K5/524C08K2201/014C08L2201/08C08L2203/16C08L2205/025C08L2205/035C08L2207/066C08L2310/00
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Quick Facts
Patent No.
US 12,435,209
App. No.
17/769,033
Granted
Oct 7, 2025
Kind
B2
Abstract

A liquid additive composition containing a fluoropolymer; an organophosphite antioxidant; a sterically hindered phenol antioxidant; and one or more hydrocarbon polymer dispersants provided improved processing and product appearance in film applications, extrusion blow molding and as a masterbatch enhancer.

Claims (34)

1. A liquid additive composition, comprising:

a fluoropolymer;

an organophosphite antioxidant;

a sterically hindered phenol antioxidant;

two different polymerized C4-olefin dispersants;

a polymeric dispersant that is not a polymerized C4-olefin;

a micronized polyethylene or polyethylene-containing wax; and

silica.

2. The liquid additive composition according to claim 1 , wherein the fluoropolymer is present in an amount of 10 to 25 wt %.

3. The liquid additive composition according to claim 1 , wherein the organophosphite antioxidant is present in an amount of 15 to 35 wt %.

4. The liquid additive composition according to claim 1 , wherein the sterically hindered phenol antioxidant is present in an amount of 0.5 to 10 wt %.

5. The liquid additive composition according to claim 1 , wherein the two different polymerized C4-olefin dispersants are present in an amount of 30 to 75 wt %.

6. The liquid additive composition according to claim 1 , wherein the fluoropolymer is a polyvinylidene fluoride.

7. The liquid additive composition according to claim 1 , further comprising an additional antioxidant.

8. A liquid additive composition, consisting of:

a fluoropolymer;

an organophosphite antioxidant;

a sterically hindered phenol antioxidant;

two different polymerized C4-olefin dispersants;

a polymeric dispersant that is not a polymerized C4-olefin;

a micronized polyethylene or polyethylene-containing wax; and

silica.

9. An article comprising the liquid additive composition according to claim 1 .

10. A film comprising the liquid additive composition according to claim 1 .

11. An extruded blow molded article comprising the liquid additive composition according to claim 1 .

12. A masterbatch comprising the liquid additive composition according to claim 1 .

13. A process for improving the surface appearance of a film, comprising adding to the film or a precursor to the film the liquid additive composition according to claim 1 .

14. A method of preparing a film that includes a step of adding the liquid additive composition according to claim 1 .

15. The liquid additive composition according to claim 1 , wherein the polymeric dispersant that is not a polymerized C4-olefin is present in an amount of 0.1 to 5 wt %.

16. The liquid additive composition according to claim 8 , wherein the fluoropolymer is present in an amount of 10 to 25 wt %.

17. The liquid additive composition according to claim 8 , wherein the organophosphite antioxidant is present in an amount of 15 to 35 wt %.

18. The liquid additive composition according to claim 8 , wherein the sterically hindered phenol antioxidant is present in an amount of 0.5 to 10 wt %.

19. The liquid additive composition according to claim 8 , wherein the two different polymerized C4-olefin dispersants are present in an amount of 30 to 75 wt %.

20. The liquid additive composition according to claim 8 , wherein the fluoropolymer is a polyvinylidene fluoride.

Assignments (1)
CHANGE OF NAME Recorded Dec 18, 2023
From: CLARIANT PLASTICS & COATINGS LTD
To: AVIENT SWITZERLAND GMBH
Reel/Frame 065894/0267 →
Continuity (2)
Provisional Application 62916440 · Oct 17, 2019
Related Publication 20240101790A1 · Mar 28, 2024
References Cited (6)
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US 5015693A · Duchesne et al. · 1991 [cited by applicant]
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US 6294604B1 · Focquet et al. · 2001 [cited by applicant]
International Search Report and Written Opinion dated Jan. 28, 2021, issued in corresponding International Patent Application No. PCT/EP2020/079110. [cited by applicant]