ELECTRONIC CONTROL OF TRANSMITTANCE OF VISIBLE AND NEAR-INFRARED RADIATION
The present invention generally relates to optoelectronic compounds, including certain nitrobenzoyl compounds, for example 2-(4-nitrobenzoyl)oxazole. In certain embodiments, these compounds can be used as electrochromic media in devices requiring change of optical absorbance or transmittance as a function of applied voltage. Examples of such devices include electrochromic mirrors, windows, displays, or the like. One specific example is solar and thermal control by smart, dynamic windows for energy-efficient buildings. Other embodiments of the invention are generally directed to systems and devices using such compounds, methods of using such compounds, e.g., to control the absorbance or transmittance of light, kits involving such compounds, or the like.
1 . A method, comprising:
applying voltage to an electrochromic material comprising a compound as recited in claim 125 to cause the electrochromic material to exhibit a change in light transmittance.
2 - 42 . (canceled)
43 . An electrochromic device, comprising:
an electrochromic region comprising a compound as recited in claim 125 ; and
a voltage source able to apply voltage to the electrochromic region.
44 - 70 . (canceled)
71 . The electrochromic device of claim 43 , wherein the electrochromic region exhibits a change in light transmittance when a voltage is applied to the electrochromic region by the voltage source.
72 . The electrochromic device of claim 43 , wherein the electrochromic region exhibits a change in visible light transmittance.
73 . The electrochromic device of claim 43 , wherein the electrochromic region exhibits a change in infrared light transmittance.
74 . The electrochromic device of claim 43 , wherein the electrochromic region exhibits a decrease in light transmittance of at least 20% when a voltage is applied.
75 . The electrochromic device of claim 43 , wherein the electrochromic region exhibits a decrease in light transmittance of at least 40% when a voltage is applied.
76 . The electrochromic device of claim 43 , further comprising a working electrode and a counter electrode for applying the voltage to the substrate.
77 - 78 . (canceled)
79 . The electrochromic device of claim 76 , wherein the electrochromic region is adjacent to the working electrode.
80 . The electrochromic device of claim 76 , wherein the working electrode comprises the electrochromic region.
81 . The electrochromic device of claim 76 , further comprising an electrolyte positioned between the working electrode and the counter electrode, wherein the electrolyte comprises ions able to react with the compound to exhibit a change in light transmittance.
82 - 86 . (canceled)
87 . An electrochromic device, comprising:
a working electrode;
a counter electrode;
an electrochromic region comprising a compound as recited in claim 125 , positioned adjacent to the working electrode; and
an electrolyte comprising an organic salt and a solvent, positioned adjacent to the electrochromic region.
88 - 122 . (canceled)
123 . An electrochromic device, comprising:
a working electrode;
a counter electrode;
a voltage source electrically connecting the working electrode and the counter electrode;
an electrochromic region comprising a compound as recited in claim 125 ; and
an electrolyte comprising an organic salt and a solvent, positioned to cause ions from the organic salt to enter the electrochromic region when a voltage is applied by the voltage source.
124 . A method, comprising:
applying voltage to an electrochromic material comprising a compound as recited in claim 126 to cause the electrochromic material to exhibit a change in light transmittance.
125 . A compound selected from the group consisting of the following compounds, each identified by a first hash block of an InChIKey representation of the compound:
ALLWAOSHMBUSCG, ANXJCOOLVBUNGC, ATDIBDUBFUULMN, ATXBYXPOUBWGHS, BFCVRVKHVUSCDV, BFTZIIDFRHNXMH, BQUJHULPLWGXOR, BTKLFRTYJPEJJV, CFSIHLPYLRSZND, CISOONJPSVTMQY, CJWGKFBZERHWSU, CKBXXPLJRZKNBZ, CLUOWPXRGXTPAP, CLZNECLDGVRQDO, CSKUDVYHCDOHPO, CUIZUILBFZEWKW, CVVFXZOGKDDCLB, CWCIEEKNDVRBIB, DFTDWRPGBRJUGT, DGFFFXLJBKUUSY, DHZJXWFGYZAUGQ, DLYLCCAYBAXGIV, DNWHZADRGVNWLT, DOGFYCUNNPFFHS, DOHIUYSVWJFUEB, DPVHSBXNLONAGP, DTIZLTGKXWBLGU, DXSFEOPOTUNUMO, FBSXXYPHBYWBNJ, FDTISEJWMLFUTE, FFWNAHKRLGYITG, FMEVKSODUUEHQZ, FOYMFTCJUJZPMY, FQCGPBFYVGXFLE, FQTKKRXSWGNDRP, FRBHHVCOZRPDNM, FSLAMAAJAOBRFO, FTENHAOQXAWXRY, FUOCNALBJNFCDV, GEMFSLGMUJZKIM, GQCCGBNVDDIECM, GQZMJHCVCLKAFJ, GTHQONOMXXUAIQ, HCGUMPIRUBNLTL, HCYWBRAXICYAAY, HGHDROGAWZHXHU, HHVKBHNOTDWWCE, HIAPIDNDGAXANE, HIFFPLXLAOJWKW, HJHSQWYKEHATOI, HKOBUDAQQYMHFJ, HNPZSAZMXUGEHV, HOXHDFIFUUCBRO, HQOZVNBWYRGKHT, HRVNBUVDWWJGNH, HVSDMYGTBZEMAO, HWEYGIPITMKNKX, IFHLQKJXZQZPCK, IFNLHKUCDOEGDG, IFXIEZOJDXODRB, IGOQZFQHMOOVPJ, IKITXNGXHRYAPC, IKRRWMLPKPREBB, IPJVITGXJLPVQW, IWJTZHCKZQJTOZ, IWZBDCZQSPYOAC, JHBBZJIDQPQLFN, JJIUUGUVFIYHSA, JNJDRAIAVKACAP, JODSTBULQMGAAI, JWPFVFACMAVKFR, JXDSBZUFCHGVKF, JYZOMERLVYWRRR, KHPYGPOJAPXYPX, KIXAZOMAQCNPRU, KJIBUICULJHDBX, KKGCRDFFUMWKIF, KMQVXEMBOKKZNO, KONRIEMWPOQRRX, LBGIRCOKXRCQJR, LCXOVVPVKAXNLO, LFIDXGCBAQQTNX, LFQGCGXMMGBNCP, LSEPQTKAKRATOD, LSGHWUSRGHSPTB, LTQITSPOILMBLL, LXGAOSBSSDEKGU, LZDZNMZFMCDENN, MAQMWZXVVCMDAR, MEIUQXRWIPDZCF, MLIOHAJOVLXNTQ, MOFOPDUBGJCWOK, MYPUTLNIQSRWTG, NCAPCIGOEOKRTK, NCVLSXIFCXWBON, NDCQKBWZVUIVNF, NEEAVCLSDNCPGA, NNMBHXHRSTXKIP, NOHLKFAGVTZKAV, NTQGLAQKXZOTAU, NUVXYPUEUJUHRJ, NVJNEPNFGITCFK, NYJBAAADZNLEOO, OEJUOQYHZBDERD, OFAOINIMTBXHRC, OGHLZQNNCSTFHG, ONZWCAHSYZPUFE, OOHMNTJGGZZPPY, OQCPMYIDZIXNEB, PAACALUYKFODHE, PAODJXVDQFZRJH, PSQYJKBJVWKQQF, PTQHYVGEIKBKRK, PYCIVHJZSSEALF, QDISDVFPDXYPAE, QFNMQYZZYGZYQK, QJIVYHVZZOKKCT, QODAIMMRRLDBHV, QPQTWLWYLKNLKH, QPWZMHZYYNSIQC, QSLLQPDUKXABJK, QULQQZMXLMQWAM, QWYBFIMUTLGVLH, QZNYZBQRHMUISC, REAKBOKAGPKLOT, RKTWQWAQEUUXKS, RKWWEZSEONJEEZ, RNFWQXYXMKHHTI, RRJYHLUEVJBVIR, RRTSRPMGAQAXRY, RWFBBKNTRLCNOR, SRMXGFPDJXPYSX, STILHLHJNNOKQX, SVEJZQATPYNHRZ, SZRACDIPBYGTAF, TXOKBUVWTJPKCJ, UCURZIIQALXDJF, UQRPDKNXWCACOD, URAKZOZXVIQVNV, UXPKTORKSCQDRB, UYWIMHORAHKOHF, VCRZQQIVAZRHQL, VKYIKSLOFJYZKM, VNGXCTBWDSCQBH, VSFJUFJGUCMFGX, VTYTYZWERWWQAC, WBSQWAUDNFZVRO, WDIVEVPYHBKUKW, WGZBZTXFZCMZDI, WHHFABDZOJYRIY, WMESLTLNWRZXIX, WPQISOPBMPXZSO, WRPJEUMIIRURTI, WSAIJJSIPFTCBM, WWSXTJKNGBMBGX, XLUQSHGOGMNSIL, XOIQMYZUIYUZGH, XRASQPAHNHZDGF, XTWLNCAHPVTNTH, XUABSJAPHVAKHG, XZSSXGUYNGENFA, YDTSFOBAODKAON, YFDJFPAQXSGXTI, YKSLNRDPOBUZPH, YRZQMKPKHNMKLM, YUPOVDCLRSVNFD, ZAGDGEXATRGHGL, ZFPGIFZGPASVIJ, ZGLMYHSGIKBSOJ, ZIWQFPMIZMHGKL, ZNSOUJFLMUUPFZ, ZOJHEYOKFWFWJL, and ZSNAKPLZSNZBCX.
126 . A compound selected from the group consisting of the following compounds, each identified by a first hash block of an InChIKey representation of the compound:
ALLWAOSHMBUSCG, ATDIBDUBFUULMN, ATXBYXPOUBWGHS, BFCVRVKHVUSCDV, BQUJHULPLWGXOR, BTKLFRTYJPEJJV, CISOONJPSVTMQY, CUIZUILBFZEWKW, CVVFXZOGKDDCLB, DGFFFXLJBKUUSY, DHZJXWFGYZAUGQ, DLYLCCAYBAXGIV, DNWHZADRGVNWLT, DOHIUYSVWJFUEB, DPVHSBXNLONAGP, DXSFEOPOTUNUMO, FDTISEJWMLFUTE, FFWNAHKRLGYITG, FQCGPBFYVGXFLE, FRBHHVCOZRPDNM, FSLAMAAJAOBRFO, FTENHAOQXAWXRY, GEMFSLGMUJZKIM, GQCCGBNVDDIECM, GQZMJHCVCLKAFJ, GTHQONOMXXUAIQ, HCGUMPIRUBNLTL, HCYWBRAXICYAAY, HHVKBHNOTDWWCE, HIFFPLXLAOJWKW, HQOZVNBWYRGKHT, HWEYGIPITMKNKX, IFHLQKJXZQZPCK, IFXIEZOJDXODRB, IGOQZFQHMOOVPJ, IKITXNGXHRYAPC, IPJVITGXJLPVQW, IWJTZHCKZQJTOZ, IWZBDCZQSPYOAC, JJIUUGUVFIYHSA, JNJDRAIAVKACAP, JWPFVFACMAVKFR, JXDSBZUFCHGVKF, JYZOMERLVYWRRR, KHPYGPOJAPXYPX, KKGCRDFFUMWKIF, KONRIEMWPOQRRX, LBGIRCOKXRCQJR, LCXOVVPVKAXNLO, LFQGCGXMMGBNCP, LSGHWUSRGHSPTB, LTQITSPOILMBLL, MAQMWZXVVCMDAR, MEIUQXRWIPDZCF, NCVLSXIFCXWBON, NDCQKBWZVUIVNF, NOHLKFAGVTZKAV, NTQGLAQKXZOTAU, OFAOINIMTBXHRC, ONZWCAHSYZPUFE, OQCPMYIDZIXNEB, PAACALUYKFODHE, PSQYJKBJVWKQQF, PYCIVHJZSSEALF, QFNMQYZZYGZYQK, QPQTWLWYLKNLKH, QSLLQPDUKXABJK, QZNYZBQRHMUISC, REAKBOKAGPKLOT, RKTWQWAQEUUXKS, RKWWEZSEONJEEZ, RRJYHLUEVJBVIR, RRTSRPMGAQAXRY, SRMXGFPDJXPYSX, STILHLHJNNOKQX, SZRACDIPBYGTAF, UQRPDKNXWCACOD, URAKZOZXVIQVNV, UXPKTORKSCQDRB, UYWIMHORAHKOHF, VNGXCTBWDSCQBH, VSFJUFJGUCMFGX, WDIVEVPYHBKUKW, WGZBZTXFZCMZDI, WPQISOPBMPXZSO, WRPJEUMIIRURTI, WSAIJJSIPFTCBM, XLUQSHGOGMNSIL, XOIQMYZUIYUZGH, XTWLNCAHPVTNTH, XUABSJAPHVAKHG, XZSSXGUYNGENFA, YDTSFOBAODKAON, YFDJFPAQXSGXTI, YRZQMKPKHNMKLM, ZAGDGEXATRGHGL, ZGLMYHSGIKBSOJ, and ZSNAKPLZSNZBCX.
127 . An electrochromic device, comprising:
an electrochromic region comprising a compound as recited in claim 126 ; and
a voltage source able to apply voltage to the electrochromic region.
128 . An electrochromic device, comprising:
a working electrode;
a counter electrode;
an electrochromic region comprising a compound as recited in claim 126 , positioned adjacent to the working electrode; and
an electrolyte comprising an organic salt and a solvent, positioned adjacent to the electrochromic region.
129 . An electrochromic device, comprising:
a working electrode;
a counter electrode;
a voltage source electrically connecting the working electrode and the counter electrode;
an electrochromic region comprising a compound as recited in claim 126 ; and
an electrolyte comprising an organic salt and a solvent, positioned to cause ions from the organic salt to enter the electrochromic region when a voltage is applied by the voltage source.