Hydrogen storage and release material and method of producing same
The present invention provides a hydrogen storage and release material including a two-dimensional hydrogen boride-containing sheet including a two-dimensional network containing n(H x B y ) (n≥4, 0.001≤x/y≤0.999) having a molar ratio of boron to hydrogen from 1:0.999 to 1:0.001, the molar ratio being determined by thermal desorption spectroscopy, and mass measurement before and after a temperature rise, wherein the hydrogen storage and release material has: peaks derived from B1s of boron at 187.5±1.0 eV and 191.2±1.0 eV to 193±1.0 eV in X-ray photoelectron spectroscopy, and a peak derived from a B—H stretching vibration at from 2400 cm −1 to 2600 cm −1 and also a peak derived from a B—H—B stretching vibration at from 1200 cm −1 to 1800 cm −1 in infrared spectroscopy.
1. A material for reversible hydrogen storage and release, the material comprising:
a two-dimensional hydrogen boride-containing sheet including a two-dimensional network containing n(H x B y ) (n≥4, 0.001≤x/y≤0.999) having a molar ratio of boron to hydrogen of from 1:0.999 to 1:0.001, the molar ratio being determined by thermal desorption spectroscopy, and mass measurement before and after temperature rise,
wherein the material for reversible hydrogen storage and release:
has peaks derived from B1s of boron at 187.5±1.0 eV and 191.2±1.0 eV to 193±1.0 eV in X-ray photoelectron spectroscopy, and
has a peak derived from a B-H stretching vibration at from 2400 cm −1 to 2600 cm −1 and also has a peak derived from a B-H-B stretching vibration at from 1200 cm −1 to 1800 cm −1 in infrared spectroscopy,
wherein
the material for reversible hydrogen storage and release reversibly stores and releases hydrogen,
the material for reversible hydrogen storage and release releases hydrogen by being heated to from 120° C. to 450° C., and
the material for reversible hydrogen storage and release that has released hydrogen, stores hydrogen by bringing the material into contact with water, and
wherein the two-dimensional hydrogen boride-containing sheet has a mesh-shaped planar structure in which:
boron atoms are arranged in a cyclic hexagon,
a plurality of the hexagons formed by the boron atoms are connected to each other, and
hydrogen atoms are randomly bonded to the boron atoms forming the plurality of the hexagons, without having specific periodic regularity and without aggregating.
2. The material for reversible hydrogen storage and release of claim 1 , wherein the two-dimensional hydrogen boride-containing sheet has a length of 100 nm or more in at least one direction.
3. A method of producing the material for reversible hydrogen storage and release of claim 1 , the method comprising:
mixing, in a polar organic solvent, magnesium diboride having a MgB 2 structure and an ion exchange resin to which an ion that is ion-exchangeable with a magnesium ion constituting the magnesium diboride is coordinated, to form a hydrogen storage and release material precursor; and
heat-treating the hydrogen storage and release material precursor at from 120° C. to 450° C.
4. The method of producing the material for reversible hydrogen storage and release of claim 3 , wherein the hydrogen storage and release material precursor:
includes the two-dimensional network containing (HB) n (n≥4) having a molar ratio of boron to hydrogen at 1:1, the molar ratio being determined by thermal desorption spectroscopy, and mass measurement before and after temperature rise, and
has a spectrum showing a peak derived from B1s of negatively charged boron at 188 eV±1.0 eV in X-ray photoelectron spectroscopy, and showing a peak derived from an sp 2 structure of boron at 191 eV±1.0 eV in electron energy loss spectroscopy.
5. The method of producing the material for reversible hydrogen storage and release of claim 3 , wherein the ion exchange resin has a sulfo group.
6. The method of producing the material for reversible hydrogen storage and release of claim 3 , wherein the polar organic solvent is acetonitrile.
7. A reversible hydrogen storage and release method, comprising:
heating a hydrogen storage and release material to from 120° C. to 450° C. to release hydrogen and bringing the hydrogen storage and release material that has released hydrogen into contact with water to store hydrogen,
wherein the hydrogen storage and release material:
comprises a two-dimensional hydrogen boride-containing sheet including a two-dimensional network containing n(H x B y ) (n≥4, 0.001≤x/y≤0.999) having a molar ratio of boron to hydrogen from 1:0.999 to 1:0.001, the molar ratio being determined by thermal desorption spectroscopy, and mass measurement before and after temperature rise,
has peaks derived from B1s of boron at 187.5±1.0 eV and 191.2±1.0 eV to 193±1.0 eV in X-ray photoelectron spectroscopy, and
has a peak derived from a B-H stretching vibration at from 2400 cm −1 to 2600 cm −1 and also has a peak derived from a B-H-B stretching vibration at from 1200 cm −1 to 1800 cm −1 in infrared spectroscopy.