Two-component polyurethane composition
A two-component polyurethane composition comprising a polyisocyanate and an emulsion polymer having greater than 2.2% of hydroxy groups in the emulsion polymer and comprising structural units of a polymerizable surfactant, a first hydroxy-functional monomer, an acid monomer and/or a salt thereof, an additional monoethylenically unsaturated nonionic monomer, and optionally a second hydroxy-functional alkyl (meth)acrylate; the two-component polyurethane composition providing improved alcohol resistance without compromising both acid and alkali resistance.
1. A two-component polyurethane composition comprising an emulsion polymer and a polyisocyanate, wherein the emulsion polymer having a weight average molecular weight of 180,000 g/mol or less comprises, by weight based on the weight of the emulsion polymer,
(a) 0.3% or more of structural units of a polymerizable surfactant,
(b) greater than 25% of structural units of a first hydroxy-functional monomer of the following formula,
where R 11 is hydrogen or —CH 3 ; R 12 , R 13 , and R 14 are each independently an alkyl group; provided that R 12 , R 13 , and R 14 together contain from 3 to 20 carbon atoms; and B is
(c) from zero to 40% of structural units of a second hydroxy-functional alkyl (meth)acrylate;
(d) structural units of an acid monomer, a salt thereof, or mixtures thereof; and
(e) structural units of an additional monoethylenically unsaturated nonionic monomer;
wherein the emulsion polymer comprises greater than 2.2% of hydroxy groups, by weight based on the weight of the emulsion polymer.
2. The polyurethane composition of claim 1 , wherein the polymerizable surfactant is selected from the group consisting of polymerizable phosphoric acid surfactants, polymerizable phosphate surfactants, polymerizable phosphonic acid surfactants, polymerizable phosphonate surfactants, or mixtures thereof.
3. The polyurethane composition of claim 1 , wherein the emulsion polymer comprises from 0.5% to 1.5% of structural units of the polymerizable surfactant.
4. The polyurethane composition of claim 1 , wherein the acid monomer and the salt thereof are selected from the group consisting of a carboxylic acid monomer, a phosphorous acid monomer, salts thereof, or mixtures thereof.
5. The polyurethane composition of claim 1 , wherein the emulsion polymer comprises from 28% to 75% of structural units of the first hydroxy-functional monomer, by weight based on the weight of the emulsion polymer.
6. The polyurethane composition of claim 1 , wherein the second hydroxy-functional alkyl (meth)acrylate is selected from the group consisting of 2-hydroxyethyl acrylate, 2-hydroxyethyl methacrylate, 2-hydroxypropyl acrylate, 2-hydroxypropyl methacrylate, 3-hydroxypropyl acrylate, 3-hydroxypropyl methacrylate, or mixtures thereof.
7. The polyurethane composition of claim 1 , wherein the emulsion polymer has a weight average molecular weight of from 8,000 to 100,000 g/mol.
8. The polyurethane composition of claim 1 , wherein the equivalent ratio of the total number of isocyanate group equivalents in the polyisocyanate, to the total number of hydroxyl group equivalents in the emulsion polymer is in the range of from 0.7:1 to 4:1.
9. A process of preparing the two-component polyurethane composition of claim 1 , comprising: admixing the emulsion polymer with a polyisocyanate.