Device and spectrometer for quantitatively detecting carbon 14 isotope by dual-wavelength method
View Patent ↗A device and a spectrometer for quantitatively detecting carbon 14 isotope by a dual-wavelength method. Two mid-infrared lasers with different wavelengths are locked in an optical cavity of a sample chamber, to ensure the two lasers are collinear. The cavity length of the optical cavity is adjusted by a cavity length adjusting unit, to tune the mode frequency of the optical cavity, and then tune the frequencies of the two mid-infrared lasers, so that the frequencies of the two mid-infrared lasers match with different energy levels of the target isotope molecule simultaneously. After the frequencies of the mid-infrared lasers match with the energy levels of the target isotope molecule simultaneously, the target isotope molecule is excited by two mid-infrared lasers simultaneously, and the optical cavity output signal of the second mid-infrared laser passing through the optical cavity is detected.
1. A device for quantitatively detecting carbon 14 isotope by a dual-wavelength method, wherein the device comprises: a first laser source, a second laser source, a first laser modulator and demodulator, a second laser modulator and demodulator, a sample chamber and a signal detector;
the first laser source is configured to output a continuous first mid-infrared laser; the second laser source is configured to output a continuous second mid-infrared laser; the wavelengths of the first mid-infrared laser and the second mid-infrared laser are different;
the first laser modulator and demodulator is configured to lock the first mid-infrared laser in the optical cavity of the sample chamber; the second laser modulator and demodulator is configured to lock the second mid-infrared laser in the optical cavity of the sample chamber;
the sample chamber at least comprises a cavity length adjusting unit;
the cavity length adjusting unit is configured to adjust the cavity length of the optical cavity, to tune the mode frequency of the optical cavity, and then tune the frequencies of the first mid-infrared laser and the second mid-infrared laser, so that the frequency of the first mid-infrared laser and the frequency of the second mid-infrared laser match with different energy levels of a target isotope molecule simultaneously;
the signal detector is configured to detect an optical cavity output signal of the second mid-infrared laser passing through the optical cavity after the laser frequencies and the energy levels of the target isotope molecule are matched simultaneously;
wherein the target isotope molecule is CO 2 containing carbon 14 isotope,
and the optical cavity output signal is a cavity enhanced absorption spectroscopy signal, a cavity ring-down spectroscopy signal, or noise-immune cavity enhanced optical heterodyne molecular spectroscopy signal.
2. The device according to claim 1 , wherein the tuning bandwidth of the first mid-infrared laser is greater than 1 MHz;
the tuning bandwidth of the second mid-infrared laser is greater than 1 MHz.
3. The device according to claim 1 , wherein the first laser modulator and demodulator is configured to lock the first mid-infrared laser in the optical cavity of the sample chamber, comprising:
the first laser modulator and demodulator is configured to modulate and demodulate the frequency and phase of the first mid-infrared laser, and generate an error signal;
the first laser modulator and demodulator is further configured to generate a negative feedback signal according to the error signal to control the frequency of the first mid-infrared laser, so that the first mid-infrared laser is locked in the optical cavity of the sample chamber;
the second laser modulator and demodulator is configured to lock the second mid-infrared laser in the optical cavity of the sample chamber, comprising:
the second laser modulator and demodulator is configured to modulate and demodulate the frequency and phase of the second mid-infrared laser, and generate an error signal;
the second laser modulator and demodulator is further configured to generate a negative feedback signal according to the error signal to control the frequency of the second mid-infrared laser, so that the second mid-infrared laser is locked in the optical cavity of the sample chamber.
4. The device according to claim 1 , wherein the first mid-infrared laser and the second mid-infrared laser are collinear in the sample chamber.
5. The device according to claim 1 , wherein the optical cavity is a high-finesse optical cavity, and the fineness is greater than 10,000.
6. The device according to claim 1 , wherein the cavity length adjusting unit is a piezoelectric ceramic unit.
7. The device according to claim 1 , wherein the sample chamber further comprises a temperature controller;
the temperature controller is configured to adjust the temperature of the optical cavity;
after adjustment, the fluctuation range of the temperature of the optical cavity is less than 100 mK.
8. The device according to claim 1 , further comprising a timing controller;
wherein the timing controllor is configured to control the working states of the cavity length adjusting unit and the detector.
9. A spectrometer, wherein the spectrometer comprises the device according to claim 1 .