IP Library › Granted Patent US 12,550,898
Granted Patent B2
US 12,550,898 · App. 17/795,630 · Granted Feb 17, 2026

Herbicide combinations comprising glufosinate and carfentrazone-ethyl

Inventors: Franck Dayan (Fort Collins, CO); Hudson Takano (Fort Collins, CO); Philip Westra (Fort Collins, CO); Steven Joseph Bowe (Research Triangle Park, NC); Rex A. Liebl (Research Triangle Park, NC); Douglas Findley (Research Triangle Park, NC); Ingo Meiners (Limburgerhof, DE)
Assignees: BASF SE; COLORADO STATE UNIVERSITY RESEARCH FOUNDATION
A01N43/653A01N57/20A01P13/00
View Patent ↗
Loading inventors, assignments & file history…
Monitor This Case
Get email alerts when status or documents change.
Order Certified Copies
Most orders are placed with the USPTO same day — all within 24 business hours.
Order via The Patent Place →
Pre-filled with this patent's details
Quick Facts
Patent No.
US 12,550,898
App. No.
17/795,630
Granted
Feb 17, 2026
Kind
B2
Abstract

The present invention relates to specific herbicide combinations comprising (i) L-glufosinate and/or salts thereof and (ii) carfentrazone-ethyl in specific ratios, and to compositions comprising said herbicide combinations in these ratios. The present invention further relates to a method of producing said specific herbicide combinations and compositions comprising said specific herbicide combinations. The present invention also relates to the use of said specific herbicide combinations and compositions comprising said specific herbicide combinations in the field of agriculture, for controlling harmful plants or undesired plant growth, as well as to corresponding methods.

Claims (42)

1 . A composition comprising

(i) glufosinate, L-glufosinate, or an agronomically acceptable salt thereof,

and

(ii) carfentrazone-ethyl,

wherein a ratio by weight of a total amount of component (i)

is at least 40 times more than a total amount of component (ii) in case of (i) being glufosinate, and

is at least 20 times more than the total amount of component (ii) in case of (i) being L-glufosinate;

wherein a total amount of component (i) is from 100 to 600 g/L, based on the total amount of the composition; and

wherein the total amount of component (ii) is

in the range of from 0.15 to 15 g/L, in case of (i) being glufosinate, and

in the range of from 0.2 to 30 g/L, in case of (i) being L-glufosinate,

in each case based on the total amount of the composition.

2 . The composition according to claim 1 , wherein a ratio by weight of the total amount of component (i) to the total amount of component (ii) is from 1000:1 to 50:1 in case of (i) being glufosinate.

3 . The composition according to claim 2 , wherein the ratio by weight of the total amount of component (i) to the total amount of component (ii) is at least from 500:1 to 60:1 in case of (i) being glufosinate.

4 . The composition according to claim 1 , wherein a ratio by weight of the total amount of component (i) to the total amount of component (ii) is at least from 500:1 to 25:1 in case of (i) being L-glufosinate.

5 . The composition according to claim 4 , wherein the ratio by weight of the total amount of component (i) to the total amount of component (ii) is at least from 250:1 to 30:1 in case of (i) being L-glufosinate.

6 . The composition according to claim 1 , wherein

the total amount of component (i) is in the range of from 150 to 500 g/L,

and

the total amount of component (ii) is in the range of from 0.2 to 10 g/L, in case of (i) being glufosinate, or

the total amount of component (ii) is in the range of from 0.4 to 20 g/L, in case of (i) being L-glufosinate,

in each case based on the total amount of the composition.

7 . The composition comprising the herbicide combination according to claim 1 , wherein the composition additionally comprises one or more further components selected from the group consisting of formulation auxiliaries and further agrochemically active compounds.

8 . The composition according to claim 1 , wherein the composition is in the form of a suspension concentrate (SC), oil dispersion (OD), or in form of microcapsules.

9 . A method for producing a composition as defined in claim 1 , comprising

(a) providing component (i),

(b) providing component (ii), and

(c) combining component (i) and component (ii),

such that the composition is obtained.

10 . A method for

controlling undesired plant growth,

and/or

controlling harmful plants,

comprising applying a composition as defined in claim 1 onto the undesired plants or the harmful plants, on parts of the undesired plants or the harmful plants, or on the area where the undesired plants or the harmful plants grow.

11 . The method according to claim 10 for treating or protecting row crops from undesired plants or the harmful plants, wherein

the total amount of component (i) is applied in the range of from 300 to 1000 g/ha, in case of (i) being glufosinate, or

the total amount of component (i) is applied in the range of from 150 to 500 g/ha, in case of (i) being L-glufosinate, and

the total amount of component (ii) is applied in the range of from 0.5 to 20 g/ha.

12 . The method according to claim 10 for treating or protecting specialty crops from undesired plants or the harmful plants, wherein

the total amount of component (i) is applied in the range of from 300 to 6000 g/ha, in case of (i) being glufosinate, or

the total amount of component (i) is applied in the range of from 150 to 3000 g/ha, in case of (i) being L-glufosinate, and

the total amount of component ii) is applied in the range of from 0.15 to 60 g/ha.

Assignments (3)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 27, 2022
From: BOWE, STEVEN JOSEPH; LIEBL, REX A.; FINDLEY, DOUGLAS; MEINERS, INGO
To: BASF CORPORATION
Reel/Frame 060640/0076 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 27, 2022
From: BASF CORPORATION
To: BASF SE
Reel/Frame 060640/0135 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 27, 2022
From: DAYAN, FRANCK; WESTRA, PHILIP; TAKANO, HUDSON
To: COLORADO STATE UNIVERSITY RESEARCH FOUNDATION
Reel/Frame 060980/0181 →
Priority Claims (1)
EP 20161389 · Mar 6, 2020 · regional
Continuity (2)
Provisional Application 62968304 · Jan 31, 2020
Related Publication 20230091043A1 · Mar 23, 2023
References Cited (32)
US 4168963A · Rupp et al. · 1979 [cited by applicant]
US 4265654A · Takematsu et al. · 1981 [cited by applicant]
US 5125958A · Poss · 1992 [cited by applicant]
US 5130246A · Schulz et al. · 1992 [cited by applicant]
US 5530142A · Zeiss · 1996 [cited by applicant]
US 5753470A · Then et al. · 1998 [cited by applicant]
US 6335186B1 · Bartsch et al. · 2002 [cited by applicant]
US 10260078B2 · Green et al. · 2019 [cited by applicant]
US 10555528B1 · Sada · 2020 [cited by applicant]
CN 103371175A · 2013 [cited by examiner]
EP 0127429A2 · 1984 [cited by applicant]
EP 0248357A2 · 1987 [cited by applicant]
EP 0249188A2 · 1987 [cited by applicant]
EP 0344683A2 · 1989 [cited by applicant]
EP 0367145A2 · 1990 [cited by applicant]
EP 0477902A2 · 1992 [cited by applicant]
JP H09244883A · 1997 [cited by applicant]
WO WO03024221A1 · 2003 [cited by applicant]
WO WO2006104120A1 · 2006 [cited by applicant]
WO WO2009141367A2 · 2009 [cited by applicant]
WO WO2011104213A2 · 2011 [cited by applicant]
WO WO2016113334A1 · 2016 [cited by applicant]
WO WO2019030098A1 · 2019 [cited by examiner]
WO WO2019142045A1 · 2019 [cited by examiner]
European Search Report for EP Patent Application No. 20161389.0, Issued on Aug. 6, 2020, 6 pages. [cited by applicant]
Hoerlein, Glufosinate (phosphinothricin), a natural amino acid with unexpected herbicidal properties, Rev Environ Contam Toxicol., vol. 138, pp. 73-145 (Jan. 1994). [cited by applicant]
International Application No. PCT/EP2021/051106, International Search Report and Written Opinion, mailed Apr. 16, 2021. [cited by applicant]
IP.com Prior Art Database Technical Disclosure, IP.com No. IPCOM000254869D, Aug. 9, 2008, 341 pages. [cited by applicant]
Lee et al., Evaluation of carfentrazone-ethyl alone and in combination with glyphosate or glufosinate for weed control in orchards, Korean J. Weed Sci., 17(3):256-61 (Jan. 1997). [cited by applicant]
Soloshonok, et al., “Asymmetric synthesis of phosphorus analogues of dicarboxylic ?-amino acids”, Journal of the Chemical Society, Perkin Transactions, vol. 1, Issue 12, 1992, pp. 1525-1529. [cited by applicant]
Theodoridis, et al., “Chapter 3 Protoporphyrinogen IX oxidase inhibitors”, Modern crop protection compounds, ed. Wolfgang Kramer, 2nd Edition, Dec. 14, 2011, pp. 163-195. [cited by applicant]
Zagar, et al., “Chapter: 3 Protoporphyrinogen IX oxidase inhibitors”, Modern Crop Protection Compounds, ed. Peter Jeschke, 3rd Edition, Jan. 25, 2019, pp. 173-211. [cited by applicant]