MOISTURE CURABLE POLYACRYLATE COMPOSITIONS AND USES THEREOF

1 . A moisture curable polyacrylate polymer prepared from:

i. 20 to 70% by weight of a first acrylic or methacrylic acid derivative having a structure of CH 2 ═CR 1 COOR 2 , where R 1 is H or CH 3 and R 2 is a C4-24 linear, branched or cyclic alkyl chain, or combination thereof,

ii. 20 to 70% by weight of a second acrylic or methacrylic acid derivative having a structure of CH 2 ═CR 1 COXR 3 , where R 1 is H or CH 3 ; X is O, NR 3 , S; R 3 is H, C1-2 alkyl chain or a combination thereof, and

iii. 0.1 to 10% by weight of a silane functional acrylic or methacrylic acid derivative having a structure of CH 2 ═CR 1 COOR 4 SiR 5 3-nm Y n , where R 1 is H or CH 3 ; R 4 is a C1-24 linear, branched or cyclic alkylene or arylene chain; R 5 is a C1-24 linear, branched or cyclic alkyl chain; Y is C1-3 alkoxy, aryloxy, acetoxy, oximino, enoxy, amino, ester, amide, lactate ester, lactate amide, H, OH, halogen, or combination thereof; n=1, 2, or 3.

2 . The moisture curable polyacrylate polymer of claim 1 , wherein

(i) the first acrylic or methacrylic acid derivative is n-butyl acrylate, n-butyl methacrylate, n-pentyl acrylate, n-hexyl acrylate, n-heptyl acrylate, and n-octyl acrylate, n-nonyl acrylate, lauryl methacrylate, cyclohexyl acrylate, and branched (meth)acrylic isomers, such as i-butyl acrylate, i-butyl methacrylate, t-butyl methacrylate, 2-ethylhexyl acrylate, stearyl methacrylate, isooctyl acrylate; or combination thereof.

3 . The moisture curable polyacrylate composition of claim 1 , wherein

(ii) the second acrylic or methacrylic acid derivative is methyl acrylate, ethyl acrylate, methoxyethyl acrylate, ethyl methacrylate, methyl methacrylate, or combination thereof.

4 . The moisture curable polyacrylate composition of claim 1 , wherein

(iii) the silane functional acrylic or methacrylic acid derivative is trimethoxysilylpropyl (meth)acrylate, triethoxysilylpropyl (meth)acrylate, trimethoxysilylethyl (meth)acrylate, methyldimethoxysilylpropyl (meth)acrylate, (meth)acryloxypropylSi(OCHCH 3 CON(CH 3 ) 2 ) 3 , (meth)acryloxypropylSi(OCHCH 3 COOCH 2 CH 3 ), or combination thereof.

5 . The moisture curable polyacrylate polymer of claim 1 , wherein

i. the first acrylic or methacrylic acid derivative n-butyl acrylate and/or 2-ethylhexyl acrylate and

ii. the second acrylic or methacrylic acid derivative methyl acrylate, ethyl acrylate, and/or methoxyethyl acrylate.

6 . A moisture curable composition comprising:

1. about 10 to 90% by weight of a moisture curable polyacrylate polymer prepared from:

i. 20 to 70% by weight of a first acrylic or methacrylic acid derivative having a structure of CH 2 ═CR 1 COOR 2 , where R 1 is H or CH 3 and R 2 is a C4-24 linear, branched or cyclic alkyl chain, or combination thereof,

ii. 20 to 70% by weight of a second acrylic or methacrylic acid derivative having a structure of CH 2 ═CR 1 COXR 3 , where R 1 is H or CH 3 ; X is O, NR 3 , S; R 3 is H, C1-2 alkyl chain or a combination thereof, and

iii. 0.1 to 10% by weight of a silane functional acrylic or methacrylic acid derivative having a structure of CH 2 ═CR 1 COOR 4 SiR 5 3-n Y n , where R 1 is H or CH 3 ; R 4 is a C1-24 linear, branched or cyclic alkylene or arylene chain; R 5 is a C1-24 linear, branched or cyclic alkyl chain; Y is C1-3 alkoxy, aryloxy, acetoxy, oximino, enoxy, amino, ester, amide, lactate ester, lactate amide, H, OH, halogen, or combination thereof; n=1, 2, or 3;

2) about 5 to about 90% of a finely divided inorganic filler or a mixer of fillers;

3) about 0.001 to about 0.5% by weight of a moisture or acid scavenger, or combination thereof;

4) about 0.001 to about 5% by weight of a moisture curing catalyst; and

5) optionally, up to about 10% by weight of a crosslinker, adhesion promotor, plasticizer, acid scavenger, pigment, inhibitor, and/or odor mask.

7 . The moisture curable composition of claim 6 , wherein said filler is selected from the group consisting of fumed silica, clay, metal salts of carbonates, sulfates, phosphates, carbon black, metal oxides, quartz, zirconium silicate, gypsum, silicon nitride, boron nitride, zeolite, glass, and combinations thereof.

8 . The moisture curable composition of claim 6 , wherein said filler is selected from the group consisting of a combination of fumed silica, calcium carbonates and magnesium oxide.

9 . The moisture curable composition of claim 6 , wherein said filler selected from the group consisting of silicone resins, organic fillers, plastic powder, and combinations thereof.

10 . The moisture curable polyacrylate composition of claim 6 wherein the moisture scavenger is vinyltrimethoxysilane, vinylmethyldimethoxysilane, hexamethyldisilazane, methyltriethoxysilane, methyltrimethoxysilane, or combination thereof.

11 . The moisture curable polyacrylate composition of claim 6 wherein the acid scavenger is hexamethyldisilazane, ethylene oxide, sodium bicarbonate, sodium carbonate, calcium carbonate, magnesium oxide, or combination thereof.

12 . The moisture curable silane modified polyacrylate composition of claim 6 wherein the moisture curing catalyst is an organometallic compound of tin, titanium, zinc, zirconium, lead, iron cobalt, antimony, manganese and bismuth, or amines, amidines, guanidines, or combination thereof.

13 . The moisture curable composition of claim 6 , wherein the adhesion promotor is a moisture reactive silane.

14 . The moisture curable composition of claim 13 , wherein said moisture reactive silane is selected from the group consisting of alkoxy silanes, acetoxy silanes, enoxy silanes, oximino silanes, amino silanes, lactate ester silanes, lactate amido silanes and combinations thereof.

15 . The moisture curable composition of claim 14 , wherein said moisture reactive silane comprises vinyltrioximinosilane, vinyltrialkoxysilane and combinations thereof.

16 . The composition of claim 6 , wherein said adhesion promoter is selected from the group consisting of tris(3-(trimethoxysilyl) propyl) isocyanurate, γ-ureidopropyltrimethoxy silane, γ-aminopropyltrimethoxy silane, and combinations thereof.

17 . A cured composition of the moisture curable composition of claim 6 .

18 . The cured composition of claim 17 which is an automotive gasket.

19 . A method of preparing a moisture curable polyacrylate polymer comprising:

1) polymerizing with a reaction temperature of about 50 to about 120° C. for about 4 to 24 hours of:

a. 40 to 90% by weight of a mixture of:

i. 20 to 70% by weight of a first acrylic or methacrylic acid derivative having a structure of CH 2 ═CR 1 COOR 2 , where R 1 is H or CH 3 and R 2 is a C4-24 linear, branched or cyclic alkyl chain, or combination thereof,

ii. 20 to 70% by weight of a second acrylic or methacrylic acid derivative having a structure of CH 2 ═CR 1 COXR 3 , where R 1 is H or CH 3 ; X is O, NR 3 , S; R 3 is H, C1-2 alkyl chain or a combination thereof, and

iii. 0.1 to 10% by weight of a silane functional acrylic or methacrylic acid derivative having a structure of CH 2 ═CR 1 COOR 4 SiR 5 3-n Y n , where R 1 is H or CH 3 ; R 4 is a C1-24 linear, branched or cyclic alkylene or arylene chain; R 5 is a C1-24 linear, branched or cyclic alkyl chain; Y is C1-3 alkoxy, aryloxy, acetoxy, oximino, enoxy, amino, ester, amide, lactate ester, lactate amide, H, OH, halogen, or combination thereof; n=1, 2, or 3,

b. 10-60% by weight of an alcohol of the formula HOR 6 , where R 6 is C 1-4 linear or branched alkyl chain,

c. 0-60% by weight of an ester of the formula R 7 COOR 8 , where R 7 and R 8 is independently C 1-4 alkyl chain,

d. 0.01 to 5% of an azo or peroxide radical initiator,

2) removing the solvents and any volatile at the temperature from about 50 to about 120° C. under a vacuum from about 10 to 30 psi, and wherein the resultant polyacrylate polymer has a weight average molecular weight (Mw) of about 1,000 g/mol to about 100,000 g/mol and a PDI from about 1.5 to 10.