Articles of manufacture comprising nanocellulose elements
The present invention provides formulations comprising a suspension of nanocellulose (NC) elements and a drying/dispersal additive selected from the group consisting of temperature-responsive polymers, small molecule additives in volatile systems, and blocking agents and methods of preparing such formulations, and further provides NC-containing materials, composite materials and useful articles of manufacture made therefrom.
1. A method of producing a redispersible, dried nanocellulose (NC)-containing material with nanocellulose elements embedded therein, comprising:
drying a liquid formulation to form a redispersible, dried NC-containing material, wherein the liquid formulation comprises a suspension of nanocellulose elements (NCEs) in a liquid medium and a drying/dispersal additive, wherein the drying/dispersal additive is a temperature-responsive polymer and disrupts hydrogen bonding between the nanocellulose elements during the drying; and
wherein the method further comprises adding a pretreatment agent to the liquid formulation before the step of drying the liquid formulation, wherein the pretreatment agent is selected from the group consisting of ethylene diamine, o-phenylenediamine, diethylenetriamine, tetraethylenepentamine, 1,3-diaminopentane, ethanolamine, triethynolamine, and melamine, or wherein the pretreatment agent is a chelating agent; and
wherein the redispersibility of the dried NC-containing material is greater than that of a dried control material prepared by drying a control suspension of nanocellulose elements in a liquid medium, wherein the control suspension lacks the drying/dispersal additive.
2. The method of claim 1 , wherein the temperature-responsive polymer is a lower critical solution temperature (LCST) polymer or a short-chain oligomer derived from the LCST polymer.
3. The method of claim 2 , wherein the temperature-responsive polymer is a lower critical solution temperature (LCST) polymer.
4. The method of claim 3 , wherein the LCST polymer is selected from the group consisting of methyl cellulose, hydroxylethyl cellulose, hydroxypropyl cellulose, hydroxypropylmethyl cellulose, ethylhydroxyethyl cellulose, polyvinylcaprolactam, poly(methyl vinyl ether), poly(N-isopropylacrylamide), poly(N,N-diethylacrylamide), poly(ethylene oxide) and poly(propylene oxide) block copolymer, and elastin poly(pentapeptide).
5. The method of claim 1 , wherein the nanocellulose elements are derived from lignocellulosic materials.
6. The method of claim 5 , wherein the lignocellulosic materials comprise virgin biomass.
7. The method of claim 5 , wherein the lignocellulosic materials comprise waste materials.
8. The method of claim 1 , wherein the nanocellulose elements comprise crystalline cellulose.
9. The method of claim 1 , wherein the nanocellulose elements comprise cellulose nanofibers or cellulose microfibers.
10. The method of claim 1 , wherein the nanocellulose elements consist essentially of cellulose nanofibers.
11. The method of claim 1 , wherein the chelating agent is EDTA.
12. The method of claim 1 , wherein the pretreatment agent is added before or simultaneously with addition of the drying/dispersal additive.
13. The method of claim 1 , wherein the pretreatment agent is a chelating agent is added before or simultaneously with addition of the drying/dispersal additive.