Coated phosphor particle, light emitting device including a coated phosphor particle, and method of making a coated phosphor particle
A light emitting device comprises a light emitting diode (LED) chip having a dominant wavelength in a range from about 390 nm to about 560 nm, an encapsulant in optical communication with the LED chip, and coated phosphor particles dispersed in the encapsulant. Each of the coated phosphor particles comprises (a) a luminescent particle having a first refractive index at the dominant wavelength, and (b) an optical coating on the luminescent particle, where the optical coating has a second refractive index at the dominant wavelength. The second refractive index is between the first refractive index and a refractive index of the encapsulant at the dominant wavelength.
1 . A coated phosphor particle comprising:
a luminescent particle having a first refractive index at a predetermined wavelength, the predetermined wavelength being a dominant wavelength of a light emitting diode (LED) chip, the dominant wavelength being in a range from about 390 nm to about 560 nm;
an optical coating on the luminescent particle, the optical coating having a second refractive index at the predetermined wavelength;
wherein the second refractive index is between the first refractive index and a refractive index of an encapsulant at the predetermined wavelength,
wherein the optical coating is one of a plurality of optical coatings on the luminescent particle, each of the optical coatings having a second refractive index between the first refractive index and the refractive index of the encapsulant, the second refractive index decreasing through a thickness of the optical coatings in a direction away from the luminescent particle, each optical coating of the plurality comprising a successively lower second refractive index in the direction away from the luminescent particle.
2 . The coated phosphor particle of claim 1 , wherein the predetermined wavelength is a dominant wavelength of a light emitting diode (LED) chip.
3 . The coated phosphor particle of claim 2 , wherein the dominant wavelength is in a range from about 390 nm to about 560 nm.
4 . The coated phosphor particle of claim 1 , wherein the encapsulant comprises silicone.
5 . The coated phosphor particle of claim 1 , wherein the luminescent particle includes a host lattice comprising yttrium aluminum garnet (YAG), lutetium aluminum garnet (LuAG), or CaAlSiN 3 .
6 . The coated phosphor particle of claim 1 ,
wherein the refractive index of the encapsulant is in a range from 1.4 to less than 1.6,
wherein the first refractive index is in a range from greater than 1.8 to 1.9, and
wherein the second refractive index is in a range from 1.6 to 1.8.
7 . The coated phosphor particle of claim 1 , wherein the optical coating comprises a glass.
8 . The coated phosphor particle of claim 1 , wherein the optical coating comprises one or more oxides selected from the group consisting of: M 2 O, where M is Li, Na, K, Rb, Cs, and/or Fr; NO, where N is Be, Mg, Ca, Sr, Ba, and/or Ra; L 2 O 3 , where L is La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb and/or Lu; B 2 O 3 , SiO 2 , Al 2 O 3 , BaO, TiO 2 , ZnO, ZrO 2 , CeO 2 , EuO, PbO; and YbO.
9 . The coated phosphor particle of claim 1 , wherein the second refractive index varies through a thickness of the optical coating, the second refractive index comprising a gradient.
10 . The coated phosphor particle of claim 1 , wherein the optical coating is one of a plurality of optical coatings on the luminescent particle,
wherein each of the optical coatings has a second refractive index between the first refractive index and the refractive index of the encapsulant, and
wherein some or all of the optical coatings have different second refractive indexes.
11 . The coated phosphor particle of claim 10 , wherein the plurality of optical coatings includes at least two and up to 15 of the optical coatings.