Dual component LLDPE copolymers with improved impact and tear resistance, and methods of their preparation
Disclosed are ethylene polymer compositions containing a homogeneously-branched first ethylene polymer component and 15-35 wt. % of a homogeneously-branched second ethylene polymer component of higher density than the first ethylene polymer component. The ethylene polymer composition can be characterized by a density from 0.912 to 0.925 g/cm 3 , a ratio of Mw/Mn from 2 to 5, a melt index less than 2 g/10 min, and a CY-a parameter at 190° C. from 0.35 to 0.7. These polymer compositions have the excellent dart impact strength and optical properties of a metallocene-catalyzed LLDPE, but with improved machine direction tear resistance, and can be used in blown film and other end-use applications. Further, methods for improving film Elmendorf tear strength also are described.
1. An ethylene polymer composition comprising:
(i) a homogeneously-branched first ethylene polymer component; and
(ii) a homogeneously-branched second ethylene polymer component having a second component density in a range from about 0.935 to about 0.972 g/cm 3 and a second component melt index in a range from about 0.5 to about 40 g/10 min;
wherein the amount of the second ethylene polymer component is in a range from about 15 to about 35 wt. %, based on the total weight of the first ethylene polymer component and the second ethylene polymer component; and
wherein the composition is characterized by:
a density in a range from about 0.912 to about 0.925 g/cm 3 ;
a ratio of Mw/Mn in a range from about 2 to about 5;
a melt index in a range from about 0.3 to about 2 g/10 min;
a CY-a parameter in a range from about 0.35 to about 0.7; and
an ATREF curve containing at least two peaks, with a first peak at a temperature in a range from about 60 to about 72° C., and a second peak at a temperature in a range from about 92 to about 104° C.
2. The composition of claim 1 , wherein:
the second component density is from about 0.94 to about 0.96 g/cm 3 ; and
the second component melt index is from about 0.5 to about 8 g/10 min.
3. The composition of claim 2 , wherein the composition comprises an ethylene homopolymer, an ethylene/α-olefin copolymer, or a combination thereof.
4. The composition of claim 3 , wherein the amount of the second ethylene polymer component is from about 15 to about 30 wt. %, based on the total weight of the first ethylene polymer component and the second ethylene polymer component.
5. The composition of claim 3 , wherein the composition is a single reactor product.
6. The composition of claim 3 , wherein the composition is a post-reactor blend.
7. The composition of claim 3 , wherein the composition contains no measurable amount of hafnium or titanium.
8. The composition of claim 3 , wherein the composition is further characterized by:
a Mw in a range from about 100 to about 200 kg/mol; and
a ratio of Mz/Mw in a range from about 1.7 to about 2.2.
9. An article of manufacture comprising the composition of claim 8 .
10. A film comprising the composition of claim 8 , wherein the film has:
a MD Elmendorf tear strength in a range from about 100 to about 500 g/mil;
a haze of less than or equal to about 10%; and
a dart impact strength of greater than or equal to about 250 g/mil.
11. The film of claim 10 , wherein the dart impact strength is greater than or equal to about 500 g/mil.
12. The composition of claim 1 , wherein the composition comprises an ethylene homopolymer, an ethylene/1-butene copolymer, an ethylene/1-hexene copolymer, an ethylene/1-octene copolymer, or any combination thereof.
13. The composition of claim 12 , wherein:
the CY-a parameter is from about 0.4 to about 0.6; and
the amount of the second ethylene polymer component is from about 15 to about 28 wt. %, based on the total weight of the first ethylene polymer component and the second ethylene polymer component.
14. The composition of claim 12 , wherein the composition is further characterized by:
a ratio of HLMI/MI in a range from about 12 to about 25; and
a ratio of Mz/Mw in a range from about 1.7 to about 2.5.
15. The composition of claim 12 , wherein:
the second peak is at a temperature from about 94 to about 102° C.; and
a difference between the temperatures (ΔT) of the first peak and the second peak is in a range from about 26 to about 39° C.
16. The composition of claim 12 , wherein the composition, the first ethylene polymer component, and the second ethylene polymer component, independently, contain less than 10 long chain branches (LCB) per million total carbon atoms.
17. A film comprising the composition of claim 12 , wherein the film has:
a MD Elmendorf tear strength in a range from about 100 to about 500 g/mil;
a haze of less than or equal to about 10%; and
a dart impact strength of greater than or equal to about 250 g/mil.
18. An ethylene polymer composition comprising:
(i) a homogeneously-branched first ethylene polymer component having a first component density in a range from about 0.905 to about 0.918 g/cm 3 ; and
(ii) a homogeneously-branched second ethylene polymer component having a second component density in a range from about 0.935 to about 0.972 g/cm 3 and a second component melt index in a range from about 0.5 to about 40 g/10 min;
wherein the amount of the second ethylene polymer component is in a range from about 15 to about 35 wt. %, based on the total weight of the first ethylene polymer component and the second ethylene polymer component; and
wherein the composition is characterized by:
a density in a range from about 0.912 to about 0.925 g/cm 3 ;
a ratio of Mw/Mn in a range from about 2 to about 5;
a melt index in a range from about 0.3 to about 2 g/10 min;
a CY-a parameter in a range from about 0.35 to about 0.7; and
an ATREF curve containing at least two peaks, with a first peak at a temperature in a range from about 60 to about 72° C., and a second peak at a temperature in a range from about 92 to about 104° C.
19. The composition of claim 18 , wherein first component density is from about 0.91 to about 0.918 g/cm 3 .
20. The composition of claim 18 , wherein the composition contain less than 5 long chain branches (LCB) per million total carbon atoms.
21. The composition of claim 18 , wherein first component is further characterized by a first component melt index in a range from about 0.5 to about 1.8 g/10 min.
22. A film comprising the composition of claim 18 , wherein the film has:
a MD Elmendorf tear strength in a range from about 100 to about 500 g/mil;
a haze of less than or equal to about 10%; and
a dart impact strength of greater than or equal to about 250 g/mil.
23. The composition of claim 1 , wherein the ratio of Mw/Mn is in a range from about 2 to 3.
24. The film of claim 10 , wherein the ratio of Mw/Mn is in a range from about 2 to 3.
25. The composition of claim 18 , wherein the ratio of Mw/Mn is in a range from about 2 to 3.
26. The film of claim 22 , wherein the ratio of Mw/Mn is in a range from about 2 to 3.