Radiation-sensitive resin composition and method for forming pattern
A radiation-sensitive resin composition includes: an onium salt compound represented by formula (1′); a resin including a structural unit having an acid-dissociable group; and a solvent. E A is a substituted or unsubstituted (α+β)-valent organic group having 1 to 40 carbon atoms; Z + is a monovalent radiation-sensitive onium cation; and α and β are each independently 1 or 2.
1. A radiation-sensitive resin composition comprising:
an onium salt compound represented by formula (1′);
a resin comprising a structural unit having an acid-dissociable group;
a radiation-sensitive acid generator capable of generating an acid upon exposure, the acid having a pKa smaller than a pKa of an acid generated by the onium salt compound upon exposure; and
a solvent:
wherein E A is a substituted or unsubstituted (α+β)-valent organic group having 1 to 40 carbon atoms,
Z + is a monovalent radiation-sensitive onium cation, and
α and β are each independently 1 or 2,
wherein the acid generated by the onium salt compound does not substantially dissociate the acid-dissociable group of the resin.
2. The radiation-sensitive resin composition according to claim 1 , wherein in the formula (1′), α and β are the same number.
3. The radiation-sensitive resin composition according to claim 1 , wherein the onium salt compound represented by the formula (1′) is an onium salt compound represented by formula (1) below:
wherein E 1 is a substituted or unsubstituted divalent organic group having 1 to 40 carbon atoms, and Z + is as defined in the formula (1′).
4. The radiation-sensitive resin composition according to claim 3 , wherein E 1 is a substituted or unsubstituted divalent chain hydrocarbon group having 1 to 20 carbon atoms, a substituted or unsubstituted divalent alicyclic hydrocarbon group having 3 to 20 carbon atoms, or a substituted or unsubstituted divalent aromatic hydrocarbon group having 6 to 20 carbon atoms.
5. The radiation-sensitive resin composition according to claim 3 , wherein E 1 is a substituted or unsubstituted divalent aromatic hydrocarbon group having 6 to 20 carbon atoms.
6. The radiation-sensitive resin composition according to claim 3 , wherein part or all of hydrogen atoms on carbon atoms in the substituted or unsubstituted divalent organic group represented by E 1 are substituted with a halogen atom or a halogenated alkyl group.
7. The radiation-sensitive resin composition according to claim 3 , wherein the minimum number of atoms on a path connecting the carbon atom of the carbonyl group bonded to E 1 and the sulfur atom of the sulfanyl group bonded to E 1 is from 1 to 6.
8. The radiation-sensitive resin composition according to claim 3 , wherein the minimum number of atoms on a path connecting the carbon atom of the carbonyl group bonded to E 1 and the sulfur atom of the sulfanyl group bonded to E 1 is 1 or 2.
9. The radiation-sensitive resin composition according to claim 1 , wherein the radiation-sensitive onium cation is a radiation-sensitive sulfonium cation or a radiation-sensitive iodonium cation.
10. The radiation-sensitive resin composition according to claim 1 , wherein a content of the onium salt compound is 0.01 parts by mass or more and 30 parts by mass or less with respect to 100 parts by mass of the resin.
11. A method for forming a pattern, the method comprising:
directly or indirectly applying the radiation-sensitive resin composition according to claim 1 onto a substrate to form a resist film;
exposing the resist film; and
developing the exposed resist film with a developer.
12. The radiation-sensitive resin composition according to claim 1 , wherein a content of the onium salt compound is 0.1 parts by mass or more and 20 parts by mass or less with respect to 100 parts by mass of the resin.
13. The radiation-sensitive resin composition according to claim 1 , wherein a content of the onium salt compound is 0.2 parts by mass or more and 15 parts by mass or less with respect to 100 parts by mass of the resin.
14. The radiation-sensitive resin composition according to claim 1 , wherein the radiation-sensitive acid generator generates a sulfonic acid upon exposure.
15. The radiation-sensitive resin composition according to claim 1 , wherein a content of the radiation-sensitive acid generator is 0.1 parts by mass or more and 40 parts by mass or less with respect to 100 parts by mass of the resin.
16. The radiation-sensitive resin composition according to claim 1 , wherein a content of the radiation-sensitive acid generator is 1 parts by mass or more and 30 parts by mass or less with respect to 100 parts by mass of the resin.
17. The radiation-sensitive resin composition according to claim 1 , wherein a content of the radiation-sensitive acid generator is 5 parts by mass or more and 20 parts by mass or less with respect to 100 parts by mass of the resin.