Glass substrate multilayer structure, a method for manufacturing the same, and a display panel including the same
Provided are a glass substrate multilayer structure including a glass substrate; a polyimide-based shatter-proof layer formed on one surface of the glass substrate; and a hard coating layer formed on the polyimide-based shatter-proof layer. The polyimide-based shatter-proof layer has a thickness of 5 to 50 μm, the hard coating layer has a thickness of 5 to 20 μm, and the glass substrate multilayer structure has a retardation in a thickness direction (R th ) of 200 nm or less. A method for manufacturing the glass substrate multilayer structure, and a display panel including the glass substrate multilayer structure are also provided.
1. A glass substrate multilayer structure comprising:
a glass substrate;
a polyimide-based shatter-proof layer formed on one surface of the glass substrate; and
a hard coating layer formed on the polyimide-based shatter-proof layer,
wherein the polyimide-based shatter-proof layer has a thickness of 5 to 50 μm, the hard coating layer has a thickness of 5 to 20 μm, and the glass substrate multilayer structure has a retardation in a thickness direction (Rth) of 200 nm or less,
wherein the polyimide-based shatter-proof layer comprises a polyfunctional (meth)acrylic crosslinked polymer.
2. The glass substrate multilayer structure of claim 1 , wherein the polyimide-based shatter-proof layer comprises a polyimide polymer comprising a unit derived from an aromatic diamine and an aromatic dianhydride.
3. The glass substrate multilayer structure of claim 1 , wherein the hard coating layer comprises a unit derived from a condensate of alkoxysilane having an epoxy group.
4. The glass substrate multilayer structure of claim 3 , wherein the condensate of alkoxysilane having an epoxy group is a silsesquioxane resin having an epoxy group.
5. The glass substrate multilayer structure of claim 3 , wherein the hard coating layer further comprises a unit derived from a crosslinking agent having a polyfunctional epoxy group.
6. The glass substrate multilayer structure of claim 1 , wherein the glass substrate has a thickness of 100 to 1000 μm.
7. The glass substrate multilayer structure of claim 1 , wherein the glass substrate multilayer structure has a flame retardant grade of V-0 as evaluated in accordance with a UL-94 VB flame retardant specification.
8. The glass substrate multilayer structure of claim 1 , wherein a surface of the hard coating layer of the glass substrate multilayer structure has a surface hardness in accordance with ASTM D3363 of 4H or more.
9. A method for manufacturing a glass substrate multilayer structure, the method comprising the steps of:
applying a shatter-proof layer forming composition on one surface of a glass substrate and curing the composition to form a polyimide-based shatter-proof layer; and
applying a hard coating layer forming composition on the polyimide-based shatter-proof layer and curing the composition to form a hard coating layer,
wherein the polyimide-based shatter-proof layer has a thickness of 5 to 50 μm, the hard coating layer has a thickness of 5 to 20 μm, and the glass substrate multilayer structure has a retardation in a thickness direction (Rth) of 200 nm or less thereof,
wherein the shatter-proof layer forming composition comprises a compound having a polyfunctional (meth)acryl group.
10. The method for manufacturing a glass substrate multilayer structure of claim 9 , wherein the shatter-proof layer forming composition comprises a polyimide polymer comprising a unit derived from an aromatic diamine and an aromatic dianhydride.
11. The method for manufacturing a glass substrate multilayer structure of claim 9 , wherein the hard coating layer forming composition comprises a condensate of alkoxysilane having an epoxy group.
12. The method for manufacturing a glass substrate multilayer structure of claim 11 , wherein the condensate of alkoxysilane having an epoxy group is a silsesquioxane resin having an epoxy group.
13. The method for manufacturing a glass substrate multilayer structure of claim 11 , wherein the hard coating layer forming composition further comprises a crosslinking agent having a polyfunctional epoxy group.
14. The method for manufacturing a glass substrate multilayer structure of claim 9 , wherein the glass substrate multilayer structure has a flame retardant grade of V-0 as evaluated in accordance with a UL-94 VB flame retardant specification.
15. The method for manufacturing a glass substrate multilayer structure of claim 9 , wherein a surface of the hard coating layer of the glass substrate multilayer structure has a surface hardness in accordance with ASTM D3363 of 4H or more.
16. A display panel comprising the glass substrate multilayer structure according to claim 1 .