Alkaline cation enrichment and water electrolysis to provide CO
Provided herein are methods of removing carbon dioxide from an aqueous stream or gaseous stream by: contacting the gaseous stream comprising carbon dioxide, when present, with an aqueous solution comprising ions capable of forming an insoluble carbonate salt; contacting the aqueous solution comprising carbon dioxide with an electroactive mesh that induces its alkalinization thereby forcing the precipitation of a carbonate solid from the solution and thereby the removal of dissolved inorganic carbon by electrolysis; and removing the precipitated carbonate solids from the solution, or the surface of the mesh where they may deposit. Also provided herein are flow-through electrolytic reactors comprising an intake device in fluid connection with a rotating cylinder comprising an electroactive mesh, and a scraping device and/or liquid-spray based device for separating a solid from the mesh surface.
1. A method of removing carbon dioxide from a gaseous fluid, the method comprising:
contacting the gaseous fluid with an aqueous solution comprising divalent cations capable of forming an insoluble divalent cation carbonate and/or hydroxide solid(s); and
performing water electrolysis on the aqueous solution with an electroactive surface, thereby inducing alkalinization of the aqueous solution and precipitation of the insoluble divalent cation carbonate and/or hydroxide solid(s) from the aqueous solution; and
performing a re-alkalinization of the aqueous solution by dissolution of mafic rocks, ultramafic rocks, or industrial solids;
wherein the divalent cations comprise magnesium ions, calcium ions, or both; and
wherein contacting the gaseous fluid with the aqueous solution comprises continuously equilibrating the aqueous solution with the gaseous fluid.
2. The method of claim 1 , wherein the method produces stoichiometric amounts of the insoluble divalent cation carbonate and/or hydroxide solids from the aqueous solution.
3. The method of claim 1 , wherein the gaseous fluid comprises between 0.04 to 100 vol. % CO 2 .
4. The method of claim 1 , wherein the gaseous fluid is atmospheric air.
5. The method of claim 1 , wherein the gaseous fluid is flue gas emitted from a natural gas-fired power plant, a coal-fired power plant, an iron mill, a steel mill, a cement plant, an ethanol plant, or a chemical manufacturing plant.
6. The method of claim 1 , wherein the aqueous solution contains an amount of dissolved carbon dioxide that is in equilibrium with the gaseous fluid.
7. The method of claim 1 , wherein the aqueous solution is in thermal equilibrium with the gaseous fluid.
8. The method of claim 1 , wherein the method produces calcium and magnesium carbonate and hydroxide solids in a molar ratio of Ca:Mg of about 10:55.
9. The method of claim 1 , wherein the method produces about 55 mmol magnesium bicarbonate and about 10 mmol calcium carbonate per kg water.
10. The method of claim 1 , wherein the divalent cations capable of forming the insoluble divalent cation carbonate and/or hydroxide solid(s) further comprise cations of Ba, Sr, Fe, Zn, Pb, Cd, Mn, Ni, Co, Cu, Al, or any combination thereof.
11. The method of claim 1 , wherein the aqueous solution has a concentration of NaCl of about 1,000 ppm or more.
12. The method of claim 1 , wherein the aqueous solution comprises seawater.
13. The method of claim 1 , wherein the method utilizes an end-to-end energy intensity of about 2.5 MWh or less per tonne of carbon dioxide mineralized.
14. The method of claim 1 , wherein the aqueous solution is bubbled with atmospheric air.
15. The method of claim 1 , wherein the electroactive surface produces an increased alkaline condition, in situ, in the aqueous solution within about 2 to 20000 μm of the electroactive surface.
16. The method of claim 15 , wherein the alkaline condition is at a pH of 8 or greater.
17. The method of claim 1 , wherein the electroactive surface comprises a metallic, nonmetallic, or carbon-based material.
18. The method of claim 17 , wherein the electroactive surface contains stainless steel, titanium oxide, carbon nanotubes, polymers, graphite, or any combination thereof.
19. The method of claim 1 , wherein the electroactive surface comprises pores having a diameter in the range of about 0.1 μm to about 10000 μm.
20. The method of claim 1 , wherein the electroactive surface comprises an electroactive mesh, and inducing the precipitation of the carbonate and/or hydroxide solid(s) includes rotating a cylinder the electroactive mesh in the solution, while applying suction to draw the solution onto the outer surface of the mesh.
21. The method of claim 1 , wherein the aqueous solution is a brine solution.
22. The method of claim 1 , wherein the aqueous solution is an alkaline earth metal cation-containing solution.
23. The method of claim 1 , wherein inducing precipitation of the carbonate and/or hydroxide solid(s) further comprises inducing precipitation of at least one carbonate or hydroxide of Ba, Sr, Fe, Zn, Pb, Cd, Mn, Ni, Co, Cu, or Al.
24. The method of claim 1 , wherein the aqueous solution contains dissolved carbon species comprising H 2 CO 3 , HCO 3 − , CO 3 2− , or any combination thereof.
25. The method of claim 1 , wherein the aqueous solution has a concentration of NaCl of about 30,000 ppm or more.
26. A flow-through electrolytic reactor comprising an intake device in fluid connection with a rotating cylindrical electrode or a planar electrode, and a scraping device and/or liquid-spray based device for separating a precipitated solid from a surface or solution, wherein the rotating cylindrical electrode or the planar electrode is capable of inducing removal of dissolved inorganic carbon by precipitation of a carbonate and/or hydroxide solid from an aqueous solution comprising carbon dioxide and ions capable of forming an insoluble carbonate and/or hydroxide solid, and
wherein the plurality of rotating cylindrical electrodes or planar electrodes are arranged in a series of planar cells in parallel or cylindrical cells in parallel, within the same, or distinct reaction modules, in series, or in parallel.
27. The flow-through electrolytic reactor of claim 26 , further comprising an aqueous solution comprising carbon dioxide, Ca ions, and Mg ions.
28. The flow-through electrolytic reactor of claim 26 , wherein the rotating cylindrical electrode or the planar electrode contains a metallic or carbon-based mesh.
29. The flow-through electrolytic reactor of claim 28 , wherein the rotating cylindrical electrode or the planar electrode contains stainless steel, titanium oxide, carbon nanotubes, polymers, graphite, or any combination thereof.
30. The flow-through electrolytic reactor of claim 26 , wherein the reactor comprises a plurality of rotating cylindrical electrodes or planar electrodes.
31. The flow-through electrolytic reactor of claim 26 , wherein the reactor is in fluid communication with a desalination device.