IP Library Granted Patent US 12,384,136
Granted Patent B2
US 12,384,136 · App. 17/874,774 · Granted Aug 12, 2025

Composite material for passive radiative cooling

Inventor: Alex Heltzel (Austin, TX)
Assignee: PC KRAUSE AND ASSOCIATES, INC.
B32B15/08B32B27/20B32B2264/1021B32B2264/303B32B2307/30B32B2307/40B32B2307/416B32B2311/08B32B2311/24B32B2419/00Y10T428/31504
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Quick Facts
Patent No.
US 12,384,136
App. No.
17/874,774
Granted
Aug 12, 2025
Kind
B2
Abstract

A composite material for passive radiative cooling is provided. In some embodiments, the composite material includes a base layer, and at least one emissive layer located adjacent to a surface of the base layer. In some embodiments, the at least one emissive layer is affixed to the surface of the base layer via a binding agent. In some embodiments, the surface of the base layer comprises a reflective substrate comprising an adhesive layer. In some embodiments, the at least one emissive layer is affixed to the base layer via the adhesive layer of the base layer.

Claims (25)

1. A composite material for passive radiative cooling comprising:

a reflective substrate comprising aluminum; and

at least one thermally-emissive layer comprising a plurality of spherical silica microparticles located adjacent to a surface of the reflective substrate, wherein the at least one thermally-emissive layer is affixed to the surface of the reflective substrate via a polymer binding agent,

wherein at least some light impinging on the thermally-emissive layer reaches the reflective substrate,

wherein an ideal material exhibits an emissivity=1 in the frequency range of 8 micrometers to 13 micrometers, and is purely reflective at all other frequencies,

wherein the composite material provides positive radiative cooling power when exposed to direct sunlight at an ambient temperature of 300 Kelvin, when an equilibrium temperature of the composite material is above 280 Kelvin,

wherein the composite material provides radiative cooling power in excess of the ideal material when exposed to direct sunlight at an ambient temperature of 300 Kelvin, when the equilibrium temperature of the composite material is between 320 and 330 Kelvin, and

wherein each of the plurality of microparticles includes a diameter greater than or equal to 5 μm and less than or equal to 30 μm.

2. The composite material of claim 1 , wherein the binding agent is transparent.

3. The composite material of claim 1 , wherein the binding agent includes a thickness less than or equal to approximately 50 μm.

4. The composite material of claim 1 , wherein the reflective substrate further comprises silver.

5. The composite material of claim 4 , wherein the binding agent is transparent.

6. The composite material of claim 4 , wherein the binding agent includes a thickness less than or equal to approximately 50 μm.

7. A composite material for passive radiative cooling comprising:

a reflective substrate comprising aluminum; and

at least one thermally-emissive layer comprising a plurality of spherical silica microparticles located adjacent to a surface of the reflective substrate, wherein the at least one thermally-emissive layer is affixed to the surface of the reflective substrate via a polymer binding agent,

wherein at least some light impinging on the thermally-emissive layer reaches the reflective substrate,

wherein an ideal material exhibits an emissivity=1 in the frequency range of 8 micrometers to 13 micrometers, and is purely reflective at all other frequencies,

wherein the composite material provides radiative cooling power in excess of the ideal material when the composite material is exposed to a nighttime sky at an ambient temperature of 280 Kelvin, when an equilibrium temperature of the composite material is above 255 Kelvin, and

wherein each of the plurality of microparticles includes a diameter greater than or equal to 5 μm and less than or equal to 30 μm.

8. The composite material of claim 7 , wherein the binding agent is transparent.

9. The composite material of claim 7 , wherein the binding agent includes a thickness less than or equal to approximately 50 μm.

10. The composite material of claim 7 , wherein the reflective substrate further comprises silver.

11. The composite material of claim 10 , wherein the binding agent is transparent.

12. The composite material of claim 10 , wherein the binding agent includes a thickness less than or equal to approximately 50 μm.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 24, 2023
From: HELTZEL, ALEX
To: PC KRAUSE AND ASSOCIATES, INC.
Reel/Frame 062792/0079 →
Continuity (3)
Continuation 15172304 · Jun 3, 2016
Provisional Application 62170369 · Jun 3, 2015
Related Publication 20220355577A1 · Nov 10, 2022
References Cited (36)
US 3043112A · Head · 1962 [cited by applicant]
US 5234985A · Koo · 1993 [cited by applicant]
US 7503971B2 · Butler · 2009 [cited by applicant]
US 20010044489A1 · Hugo · 2001 [cited by applicant]
US 20040009319A1 · Zanchetta · 2004 [cited by applicant]
US 20040185276A1 · Hara · 2004 [cited by applicant]
US 20050064094A1 · Wojtysiak · 2005 [cited by applicant]
US 20070110961A1 · Fensel · 2007 [cited by applicant]
US 20080318031A1 · Smith · 2008 [cited by applicant]
US 20120107625A1 · Smith · 2012 [cited by examiner]
US 20130288042A1 · Haines · 2013 [cited by applicant]
US 20140131023A1 · Raman · 2014 [cited by applicant]
US 20140233120A1 · Kreling · 2014 [cited by applicant]
US 20150131146A1 · Fan · 2015 [cited by applicant]
US 20150146287A1 · Kuhlmann · 2015 [cited by applicant]
US 20160356561A1 · Heltzel · 2016 [cited by applicant]
US 20170248381A1 · Yang · 2017 [cited by applicant]
US 20180246261A1 · Templin · 2018 [cited by applicant]
US 20190338415A1 · Wrench · 2019 [cited by applicant]
JP 2011163715A · 2011 [cited by applicant]
JP 60086173A · 2015 [cited by applicant]
KR 101524728B1 · 2015 [cited by applicant]
International (PCT) Search Report and Written Opinion for International (PCT) Patent App. No. PCT/US23/80503 dated Mar. 13, 2024, 10 pages. [cited by applicant]
Dictionary definition of “abrasive”, Merriam-Webster, printed from the web: Oct. 3, 2018, url: https://www.merriamwebster.com/dictionary/abrasive. [cited by applicant]
Zhu, Linxiao, Raman, Aaswath, and Fan, Shanhui, Color-preserving Daytime Radiative Cooling, Applied Physics Letters, 103, 223902, 2013, AIP Publishing, 6 pages. [cited by applicant]
Rephaeli, Eden, Raman, Aaswath, and Fan, Shanhui, Ultrabroadband Photonic Structures to Acheive High-Performance Daytime Radiative Cooling, NANO Letters 2013, 13, pp. 1457-1461, American Chemical Society, 5 pages. [cited by applicant]
Raman, Aaswath P., Anoma, Marc Abou, Zhu, Linxiao, Rephaeli, Eden, and Fan, Shanhui, Passive Radiative Cooling Below Ambient Air Temperature Under Direct Sunlight, Nature, v. 515, Letter, Nov. 27, 2014, 11 pages. [cited by applicant]
Granqvist, C. G., Hjortsberg, A., Radiative Cooling to Low Temperatures: General Considerations and Application to Selectively Emitting SiO Films, Journal of Applied Physics, v. 52, No. 6, Jun. 1981, AIP Publishing, 17 … [cited by applicant]
ASTM G173-03 Reference Spectra, Feb. 2022, https://www.nrel.gov/grid/solar-resource/spectra-am1.5.html, retrieved on Mar. 2, 2022, 3 pages. [cited by applicant]
Optotherm Support-Emissivity in the Infrared, 2018, https://www.optotherm.com/emiss-table.htm, retrieved on Mar. 2, 2022, 6 pages. [cited by applicant]
Transmetra, Table of Emissivity of Various Surfaces, Feb. 2022, https://www.transmetra.ch/images/transmetra_pdf/publikationen_literatur/pyrometrie-thermografie/emissivity_table.pdf, retrieved on Mar. 2, 2022, 10 pages. [cited by applicant]
Howell, J.R., Menguc, M.P., Daun, K., Siegel, R., Thermal Radiation Heat Transfer, 5th Ed., CRC Press, 2010, pp. 21, 22, 60, and 61. [cited by applicant]
Johnson et al., “Optical Constants of the Noble Metals” Physical Review B, vol. 6, No. 12, Dec. 15, 1972, 10 pages. [cited by applicant]
Hecht, E., Optics, 4th Ed., Pearson, 2002, p. 139. [cited by applicant]
Howell, J.R., Menguc, M.P., Daun, K., Siegel, R., Thermal Radiation Heat Transfer, 7th Ed., CRC Press, 2020, p. 381. [cited by applicant]
Palik, E.D., Handbook of Optical Constants of Solids, Academic Press, 1985, pp. 350-357. [cited by applicant]