Short-wave infrared materials, detectors, and methods
View Patent ↗Aspects of the present disclosure generally relate to short-wave infrared (SWIR) materials, SWIR detectors, and methods of use. In an aspect, a SWIR detector is provided and includes a conductive layer disposed over a first portion of a substrate, the conductive layer having a trench therein, and a hole transport layer disposed over at least a second portion of the substrate and within the trench of the conductive layer. The SWIR detector further includes a light conversion layer disposed over at least a portion of the hole transport layer, the light conversion layer comprising a composition having the formula A a B b M c X d , wherein: A is an organic group or ion thereof; B is an organic group, an inorganic group, or ion thereof; M is a metal or ion thereof; X is a halogen or ion thereof; and a, b, c, and d are numbers expressing amounts of A, B, M, and X.
1. A short-wave infrared detector, comprising:
a conductive layer disposed over a first portion of a substrate, the conductive layer having a trench therein;
a hole transport layer disposed over at least a second portion of the substrate, at least a portion of the hole transport layer positioned within the trench of the conductive layer;
a light conversion layer disposed over at least a portion of the hole transport layer, the light conversion layer comprising a composition of formula (I):
A a B b M c X d (I),
wherein:
A of formula (I) is an organic group or ion thereof;
B of formula (I) is an organic group, an inorganic group, or ion thereof, A and B being the same or different;
M of formula (I) is a metal or ion thereof;
X of formula (I) is a halogen or ion thereof; and
a, b, c, and d of formula (I) are numbers expressing amounts of A, B, M, and X.
2. The short-wave infrared detector of claim 1 , wherein a of formula (I) is a non-zero number, b of formula (I) is 1−a, and d of formula (I) is 3.
3. The short-wave infrared detector of claim 2 , wherein a of formula (I) is from about 0.2 to about 0.9.
4. The short-wave infrared detector of claim 2 , wherein a of formula (I) is from about 0.2 to about 0.25, or from about 0.25 to about 0.3, or from about 0.3 to about 0.4, or from about 0.4 to about 0.5, or from about 0.5 to about 0.6, or from about 0.6 to about 0.7, or from about 0.7 to about 0.8, or from about 0.8 to about 0.9.
5. The short-wave infrared detector of claim 1 , wherein M of formula (I) is Pb, Sn, Ge, or ion thereof.
6. The short-wave infrared detector of claim 1 , wherein A of formula (I) is selected from the group consisting of methylamine, dimethylamine, trimethylamine, ethylamine, diethylamine, triethylamine, trisopropylamine, aziridine, diaziridine, formamidine, amidine, guanidine, methylammonium, dimethylammonium, trimethylammonium, ethylammonium, diethylammonium, triethylammonium, triisopropylammonium, aziridinium, diaziridinium, formamidinium, amidinium, guanidinium, and combinations thereof.
7. The short-wave infrared detector of claim 1 , wherein B of formula (I) is selected from the group consisting of ammonia, hydrazine, ammonium, hydroxylammonium, hydrazinium, and combinations thereof.
8. The short-wave infrared detector of claim 1 , wherein the short-wave infrared detector is configured to operate at a temperature of about 10° C. or higher.
9. The short-wave infrared detector of claim 1 , wherein:
A of formula (I) is methylammonium or formamidinium; and
B of formula (I) is methylammonium, formamidinium, hydrazinium, or hydroxylammonium.
10. The short-wave infrared detector of claim 1 , wherein the light conversion layer has a thickness of about 200 nm to about 800 nm.
11. The short-wave infrared detector of claim 1 , wherein:
the conductive layer comprises a conductive oxide; and
the hole transport layer comprises polyacetylene, polyaniline, polypyrrole, polythiophene, derivatives thereof, or combinations thereof.
12. The short-wave infrared detector of claim 1 , wherein:
the conductive layer comprises indium tin oxide (ITO), fluorine doped tin oxide (FTO), aluminum doped zinc oxide, indium zinc oxide (IZO), indium-doped cadmium oxide, barium stannate, strontium vanadate, calcium vanadate, or combinations thereof; and
the hole transport layer comprises poly(3,4-ethylenedioxythiophene) (PEDOT), poly(3,4-ethylenedioxythiophene) polystyrene sulfonate (PEDOT:PSS), poly(4,4-dioctylcyclopentadithiophene), or combinations thereof.
13. A short-wave infrared detection system, comprising:
at least one processor;
an illumination source configured to illuminate a sampled location of an object or a scene; and
a detector configured to detect light from the sampled location, the detector comprising:
a conductive layer having a trech therein;
a hole transport layer, at least a portion of the hole transport layer positioned within the trench of the conductive layer; and
a light conversion layer disposed over the hole transport layer, the light conversion layer comprising a composition of formula (I):
A a B b M c X d (I),
wherein:
A of formula (I) is an organic group or ion thereof;
B of formula (I) is an organic group, an inorganic group, or ion thereof, B and A being the same or different;
M of formula (I) is a metal or ion thereof;
X of formula (I) is a halogen or ion thereof; and
a, b, c, and d of formula (I) are numbers expressing amounts of A, B, M, and X.
14. The short-wave infrared detection system of claim 13 , wherein the at least one processor is configured to create an absorption image of the object or the scene.
15. The short-wave infrared detection system of claim 13 , wherein:
the hole transport layer comprises polyacetylene, polyaniline, polypyrrole, polythiophene, derivatives thereof, or combinations thereof; and
the conductive layer comprises a conductive oxide.
16. The short-wave infrared detection system of claim 13 , wherein:
M of formula (I) is Pb, Sn, Ge, or ion thereof;
A of formula (I) is selected from the group consisting of methylamine, dimethylamine, trimethylamine, ethylamine, diethylamine, triethylamine, trisopropylamine, aziridine, diaziridine, formamidine, amidine, guanidine, methylammonium, dimethylammonium, trimethylammonium, ethylammonium, diethylammonium, triethylammonium, triisopropylammonium, aziridinium, diaziridinium, formamidinium, amidinium, guanidinium, and combinations thereof; or
combinations thereof.
17. A method, comprising:
directing a light beam comprising short-wave infrared light from an illumination source towards an object and illuminating a sampled location on the object; and
detecting, by a detector, light absorbed or reflected by the sampled location on the object, the detector comprising:
a conductive layer having a trench therein;
a hole transport layer, at least a portion of the hole transport layer positioned within the trench of the conductive layer; and
a light conversion layer disposed over the hole transport layer, the light conversion layer having a thickness from about 200 nm to about 800 nm, the light conversion layer comprising a composition of formula (I):
A a B b M c X d (I),
wherein:
A of formula (I) is an organic group or ion thereof;
B of formula (I) is an organic group, an inorganic group, or ion thereof, B and A being the same or different;
M of formula (I) is a metal or ion thereof;
X of formula (I) is a halogen or ion thereof; and
a, b, c, and d of formula (I) are numbers expressing amounts of A, B, M, and D.
18. The method of claim 17 , further comprising creating an image based on the detected light.
19. The short-wave infrared detection system of claim 13 , wherein:
the conductive layer comprises indium tin oxide (ITO), fluorine doped tin oxide (FTO), aluminum doped zinc oxide, indium zinc oxide (IZO), indium-doped cadmium oxide, barium stannate, strontium vanadate, calcium vanadate, or combinations thereof; and
the hole transport layer comprises poly (3,4-ethylenedioxythiophene) (PEDOT), poly (3,4-ethylenedioxythiophene) polystyrene sulfonate (PEDOT: PSS), poly (4,4-dioctylcyclopentadithiophene), or combinations thereof.
20. The method of claim 17 , wherein:
the conductive layer comprises indium tin oxide (ITO), fluorine doped tin oxide (FTO), aluminum doped zinc oxide, indium zinc oxide (IZO), indium-doped cadmium oxide, barium stannate, strontium vanadate, calcium vanadate, or combinations thereof; and
the hole transport layer comprises poly (3,4-ethylenedioxythiophene) (PEDOT), poly (3,4-ethylenedioxythiophene) polystyrene sulfonate (PEDOT: PSS), poly (4,4-dioctylcyclopentadithiophene), or combinations thereof.