IP Library Granted Patent US 11,923,105
Granted Patent B2
US 11,923,105 · App. 17/887,844 · Granted Mar 5, 2024

Methods and systems for fabricating high quality superconducting tapes

Inventors: Goran Majkic (Houston, TX); Venkat Selvamanickam (Houston, TX)
Assignee: University of Houston System
H01B12/06C23C16/0209C23C16/408C23C16/448C23C16/545H01B13/00H01B13/0026H01B13/008H10N60/0464
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Quick Facts
Patent No.
US 11,923,105
App. No.
17/887,844
Granted
Mar 5, 2024
Kind
B2
Abstract

An MOCVD system fabricates high quality superconductor tapes with variable thicknesses. The MOCVD system can include a gas flow chamber between two parallel channels in a housing. A substrate tape is heated and then passed through the MOCVD housing such that the gas flow is perpendicular to the tape's surface. Precursors are injected into the gas flow for deposition on the substrate tape. In this way, superconductor tapes can be fabricated with variable thicknesses, uniform precursor deposition, and high critical current densities.

Claims (21)

1. A method of fabricating a superconductor tape by metal organic chemical vapor deposition using a precursor to film conversion, the method comprising:

heating a superconductor substrate tape via ohmic heating; and

laminarly flowing the precursor in a gas phase such that the precursor thermally decomposes upon contact with the heated superconductor substrate tape thereby forming a superconductor film;

wherein the precursor to film conversion efficiency is greater than approximately 20% of theoretical value.

2. The method of claim 1 , wherein the superconductor tape is a REBCO film.

3. The method of claim 2 , wherein the REBCO film comprises the formula REB a2 Cu 3 O 7 .

4. The method of claim 1 , wherein the superconductor tape is substantially uniform.

5. The method of claim 1 , wherein the superconductor tape comprises no observable misoriented grain growth.

6. The method of claim 1 , wherein the precursor to film conversion efficiency is a result of a conversion of precursor to film performed within a gap in a range from less than 1 mm to approximately ¼ inch.

7. The method of claim 6 , wherein the gap is defined by an upper surface and a lower surface parallel to the upper surface.

8. The method of claim 1 , wherein the superconductor tape comprises a film thickness greater than approximately 2 μm and a critical current density greater than approximately 4 MA/cm 2 at 77 K in a zero applied magnetic field.

9. The method of claim 8 , wherein the superconductor tape further comprises non c-axis grain orientation less than approximately 10%.

10. A method of fabricating a superconductor tape by metal organic chemical vapor deposition, the method comprising:

heating a superconductor substrate tape via ohmic heating; and

laminarly flowing a precursor in a gas phase such that the precursor thermally decomposes upon contact with the heated superconductor substrate tape thereby forming a superconductor film,

wherein the superconductor tape comprises a film thickness greater than approximately 2 μm and a critical current density greater than approximately 4 MA/cm 2 at 77 K in a zero applied magnetic field.

11. The method of claim 10 , wherein the superconductor tape further comprises non c-axis grain orientation less than approximately 10%.

12. The method of claim 10 , wherein the superconductor tape is a REBCO film.

13. The method of claim 12 , wherein the REBCO film comprises the formula REB a2 Cu 3 O 7 .

14. The method of claim 10 , wherein the superconductor tape is substantially uniform.

15. The method of claim 10 , wherein the superconductor tape comprises no observable misoriented grain growth.

Assignments (3)
CONFIRMATORY LICENSE Recorded Apr 11, 2024
From: UNIVERSITY OF HOUSTON
To: US DEPARTMENT OF ENERGY
Reel/Frame 067095/0121 →
CONFIRMATORY LICENSE Recorded Apr 11, 2024
From: UNIVERSITY OF HOUSTON
To: US DEPARTMENT OF ENERGY
Reel/Frame 067095/0132 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 15, 2022
From: MAJKIC, GORAN; SELVAMANICKAM, VENKAT
To: UNIVERSITY OF HOUSTON SYSTEM
Reel/Frame 060808/0310 →
Continuity (6)
Continuation 16930529 · Jul 16, 2020
Continuation 16727326 · Dec 26, 2019
Continuation 15139127 · Apr 26, 2016
Division 14208818 · Mar 13, 2014
Provisional Application 61801478 · Mar 15, 2013
Related Publication 20220392669A1 · Dec 8, 2022