IP Library › Granted Patent US 12,187,981
Granted Patent B2
US 12,187,981 · App. 17/897,039 · Granted Jan 7, 2025

Dissolvable toilet brush formulations with desiccant and dye system to indicate cleaning

Inventor: Daniel Thomas Piorkowski (Fairfield, CT)
Assignee: HENKEL AG & CO. KGAA
C11D1/143C11D3/08C11D3/10C11D3/2086C11D3/40C11D17/0056C11D2111/14
View Patent ↗
Loading inventors, assignments & file history…
Monitor This Case
Get email alerts when status or documents change.
Order Certified Copies
Most orders are placed with the USPTO same day — all within 24 business hours.
Order via The Patent Place →
Pre-filled with this patent's details
Quick Facts
Patent No.
US 12,187,981
App. No.
17/897,039
Granted
Jan 7, 2025
Kind
B2
Abstract

A dissolvable unit dose toilet cleaning composition for use with a wand. The unit dose contains surfactant, an organic acid, an organic acid buffering agent, and a dye system including a desiccant, a water-soluble dye, and optionally a colorant. The composition is compressed into a tablet or puck wherein at least 30% dissolves in 10 minutes when submerged in toilet water. Upon exposing a surface of the unit dose composition to water in the toilet, the water-soluble dye colors the water in the toilet. Pressing the wetted surface of the unit dose composition to a surface of the toilet, the water-soluble dye colors the surface of the toilet.

Claims (52)

1. A dissolvable solid unit dose toilet cleaning composition comprising:

an anionic surfactant;

a carbonate or bicarbonate salt;

an organic acid;

a dye system comprising a desiccant and a water-soluble dye; and

virgin soap pellets comprising at least one monovalent salt of a monocarboxylic fatty acid in an amount of from 5 wt % to 50 wt %, based on the total weight of the unit dose toilet cleaning composition,

wherein at least 30% of the total weight of the unit dose toilet cleaning composition dissolves when submerged in water for 10 minutes.

2. The unit dose toilet cleaning composition of claim 1 , wherein the desiccant is in an amount of from about 0.2% to about 3.0% by weight, based on the total weight of the unit dose toilet cleaning composition.

3. The unit dose toilet cleaning composition of claim 1 , wherein the water-soluble dye is in an amount of from about 0.005% to about 0.1% by weight, based on the total weight of the unit dose toilet cleaning composition.

4. The unit dose toilet cleaning composition of claim 1 , wherein the dye system further comprises a colorant.

5. The unit dose toilet cleaning composition of claim 4 , wherein the colorant is a lake pigment.

6. The unit dose toilet cleaning composition of claim 4 , wherein the colorant is in an amount of from 0.0001% to about 0.1% by weight, based on the total weight of the unit dose toilet cleaning composition.

7. The unit dose toilet cleaning composition of claim 1 , wherein the unit dose toilet cleaning composition is a compressed solid, defines an indentation in at least one of its surfaces, and the indentation is adapted to receive and engage a wand.

8. A unit dose toilet cleaning composition comprising:

an anionic surfactant;

a carbonate or bicarbonate salt;

an organic acid;

about 0.2% to about 3.0% calcium silicate;

a water-soluble dye; and

virgin soap pellets comprising at least one monovalent salt of a monocarboxylic fatty acid in an amount of from 5 wt % to 50 wt %, based on the total weight of the unit dose toilet cleaning composition.

9. The unit dose toilet cleaning composition of claim 8 , wherein the calcium silicate is in an amount of from about 0.5% to about 1.0% by weight, based on the total weight of the unit dose toilet cleaning composition.

10. The unit dose toilet cleaning composition of claim 8 , wherein the water-soluble dye comprises a colorant.

11. The unit dose toilet cleaning composition of claim 8 , wherein the anionic surfactant is an alpha olefin sulphonate.

12. A method of visually indicating application of a toilet cleaning composition to a toilet, the method comprising:

providing a unit dose toilet cleaning composition comprising:

an anionic surfactant;

a carbonate or bicarbonate salt;

an organic acid;

a dye system comprising a desiccant and a water-soluble dye; and

virgin soap pellets comprising at least one monovalent salt of a monocarboxylic fatty acid in an amount of from 5 wt % to 50 wt %, based on the total weight of the unit dose toilet cleaning composition,

wherein at least 30% of the total weight of the unit dose toilet cleaning composition dissolves within 10 minutes when submerged in toilet water; and

exposing a surface of the unit dose toilet cleaning composition to water in the toilet, wherein the water-soluble dye colors the water in the toilet.

13. The method of claim 12 , further comprising pressing the wetted surface of the unit dose toilet cleaning composition to a surface of the toilet, wherein the water-soluble dye colors the surface of the toilet.

14. The method of claim 12 , wherein the step of exposing comprises submerging the unit dose toilet cleaning composition in the water in the toilet.

15. The method of claim 12 , wherein the desiccant is in an amount of from about 0.2% to about 3.0% by weight, based on the total weight of the unit dose toilet cleaning composition.

16. The method of claim 12 , wherein the unit dose toilet cleaning composition is free from color of the water-soluble dye upon storage at room temperature.

17. The unit dose toilet cleaning composition of claim 1 , wherein the virgin soap pellets further comprises at least one of:

a water soluble polyhydric organic solvent;

a sugar alcohol;

an organic salt;

an inorganic salt;

a chelating agent; or

a stabilizer.

18. The unit dose toilet cleaning composition of claim 1 , wherein the virgin soap pellets comprise fatty acids in an amount of from about 0.5% to 5% by weight, based on the total weight of the virgin soap pellets.

19. The unit dose toilet cleaning composition of claim 8 , wherein the virgin soap pellets further comprise at least one of:

a water soluble polyhydric organic solvent;

a sugar alcohol;

an organic salt;

an inorganic salt;

a chelating agent; or

a stabilizer.

20. The unit dose toilet cleaning composition of claim 8 , wherein the virgin soap pellets comprise fatty acids in an amount of from about 0.5% to 5% by weight, based on the total weight of the virgin soap pellets.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 27, 2022
From: PIORKOWSKI, DANIEL THOMAS
To: HENKEL AG & CO. KGAA
Reel/Frame 061228/0175 →
Continuity (1)
Related Publication 20240067898A1 · Feb 29, 2024
References Cited (46)
US 2755497A · Greacen, Jr. · 1956 [cited by applicant]
US 4031673A · Hagelberg · 1977 [cited by applicant]
US 4167422A · Bellanca · 1979 [cited by examiner]
US 4493124A · Agapiou · 1985 [cited by applicant]
US 4642836A · Bokmiller · 1987 [cited by applicant]
US 4852201A · Wundrock et al. · 1989 [cited by applicant]
US 5471697A · Daconta · 1995 [cited by applicant]
US 5630243A · Federico et al. · 1997 [cited by applicant]
US 5888002A · Fenstersheib · 1999 [cited by applicant]
US 6094771A · Egolf et al. · 2000 [cited by applicant]
US 6124251A · Rader et al. · 2000 [cited by applicant]
US 6463620B2 · Busha · 2002 [cited by applicant]
US 6863830B1 · Purdy et al. · 2005 [cited by applicant]
US 6939841B2 · Requejo · 2005 [cited by applicant]
US 7065825B2 · Minkler et al. · 2006 [cited by applicant]
US 7127768B2 · Blum et al. · 2006 [cited by applicant]
US 7146676B2 · Kubes et al. · 2006 [cited by applicant]
US 7159265B2 · Soller et al. · 2007 [cited by applicant]
US 7232364B2 · Hibbard · 2007 [cited by applicant]
US 7275276B2 · Jaszenovics et al. · 2007 [cited by applicant]
US 7530138B1 · Platt · 2009 [cited by applicant]
US 7563756B2 · Brady · 2009 [cited by applicant]
US 7650663B2 · Michaels et al. · 2010 [cited by applicant]
US 7827648B2 · Soller et al. · 2010 [cited by applicant]
US 9408521B2 · Molinet et al. · 2016 [cited by applicant]
US 20020061831A1 · Kaziska et al. · 2002 [cited by applicant]
US 20030040459A1 · Araya · 2003 [cited by examiner]
US 20070079460A1 · Tapp et al. · 2007 [cited by applicant]
US 20100125957A1 · Hong · 2010 [cited by examiner]
US 20120246854A1 · Uchiyama et al. · 2012 [cited by applicant]
US 20130104304A1 · Wilson et al. · 2013 [cited by applicant]
US 20160106274A1 · Eun · 2016 [cited by applicant]
US 20180296043A1 · Meier et al. · 2018 [cited by applicant]
US 20210052117A1 · O'Brien · 2021 [cited by examiner]
DE 102008028138A1 · 2009 [cited by applicant]
EP 1553864A2 · 2005 [cited by applicant]
EP 2569487A1 · 2013 [cited by applicant]
ES 2622227T3 · 2017 [cited by applicant]
GB 738299A · 1955 [cited by applicant]
GB 2242130A · 1991 [cited by applicant]
GB 2329325A · 1999 [cited by applicant]
WO 0149818A1 · 2001 [cited by applicant]
WO WO2005061689A1 · 2005 [cited by examiner]
WO 2007107750A1 · 2007 [cited by applicant]
WO 2014039356A1 · 2014 [cited by applicant]
Co-pending U.S. Appl. No. 17/301,837, inventors Larracuente, A., et al., filed on Apr. 15, 2021 (Not yet Published). [cited by applicant]
Cited By (2)
US 1,076,291 US 1,133,565