R-T-B-based permanent magnet and method for producing same, motor, and automobile
An R-T-B-based permanent magnet which contains R that represents at least one rare earth element essentially including Tb or Dy, T that represents Fe or at least one iron-group element essentially including Fe and Co, and B that represents boron, and further contains Cu. The total content of R is 28.35 to 29.95% by mass, inclusive, the content of Cu is 0.05 to 0.40% by mass, inclusive, and the content of B is 0.93 to 1.00% by mass, inclusive. The distribution of the concentration of Tb or Dy decreases from the outside of the R-T-B-based permanent magnet toward the inside of the R-T-B-based permanent magnet.
1 . An R-T-B based permanent magnet in which R represents one or more rare earth elements which essentially includes Tb or Dy, T represents one or more iron group elements which essentially includes Fe or a combination of Fe and Co, and B represents boron; wherein
the R-T-B based permanent magnet further includes Cu,
a total content of R is within a range of 28.35 mass % or more and 29.95 mass % or less,
a content of Cu is within a range of 0.05 mass % or more and 0.40 mass % or less,
a content of B is within a range of 0.93 mass % or more and 1.00 mass % or less,
a content of Ga is within a range of 0 mass % or more and 0.05 mass % or less,
a concentration distribution of Tb or Dy decreases from a surface area towards an inside of the R-T-B based permanent magnet,
a residual magnetic flux density is 1485 mT or more, the residual magnetic flux density being measured after a grain boundary diffusion process, and
a coercivity is 1800 kA/m or more.
2 . The R-T-B based permanent magnet according to claim 1 , wherein R represents one or more rare earth elements which essentially includes Tb.
3 . The R-T-B based permanent magnet according to claim 1 comprising C in a content of less than 750 ppm.
4 . The R-T-B based permanent magnet according to claim 1 comprising N in a content of less than 500 ppm.
5 . The R-T-B based permanent magnet according to claim 1 comprising O in a content of less than 650 ppm.
6 . The R-T-B based permanent magnet according to claim 1 , wherein one or more light rare earth elements are included as R, and a concentration distribution of the one or more light rare earth elements decreases from the surface area towards the inside of the R-T-B based permanent magnet.
7 . The R-T-B based permanent magnet according to claim 1 , wherein a concentration distribution of Cu decreases from the surface area towards the inside of the R-T-B based permanent magnet.
8 . The R-T-B based permanent magnet according to claim 1 , wherein the R-T-B based permanent magnet further includes Al, and a concentration distribution of Al decreases from the surface area towards the inside of the R-T-B based permanent magnet.
9 . The R-T-B based permanent magnet according to claim 1 , wherein the R-T-B based permanent magnet further includes Co, and a concentration distribution of Co decreases from the surface area towards the inside of the R-T-B based permanent magnet.
10 . The R-T-B based permanent magnet according to claim 1 , wherein the R-T-B based permanent magnet further includes Ga, and a concentration distribution of Ga decreases from the surface area towards the inside of the R-T-B based permanent magnet.
11 . A motor comprising the R-T-B based permanent magnet according to claim 1 .
12 . An automobile comprising the motor according to claim 11 .
13 . A method for producing the R-T-B based permanent magnet of claim 1 comprising:
storing hydrogen to a raw material alloy, and
dehydrogenating the raw material alloy storing hydrogen; in which
the raw material alloy storing hydrogen is dehydrogenated under a dehydrogenating temperature within a range of 50° C. or higher and 200° C. or lower for a dehydrogenating time of 5 minutes or longer and 600 minutes or shorter.
14 . The method for producing the R-T-B based permanent magnet according to claim 13 , wherein 2100 ppm or more and 3100 ppm or less of H is included in a coarse magnetic powder obtained by dehydrogenation the raw material alloy storing hydrogen.