Method for producing thermoelectric conversion element
When a size is increased for mass production, an area of a pressurized surface is increased. This raised a problem in that insufficient load or the like causes a pressure during pressure sintering and a relative density of a thermoelectric conversion element to be likely to become insufficient. As a solution, there is provided a method for producing a thermoelectric conversion element, including: a step of mixing a skutterudite-type thermoelectric conversion material powder containing Sb and a sintering agent containing a compound including Mn and Sb, to obtain a mixture; and a step of sintering the mixture.
1. A method for producing a thermoelectric conversion element, comprising:
a step of mixing a skutterudite-type thermoelectric conversion material powder containing Sb and a sintering assistant containing a compound including Mn and Sb, to obtain a mixture; and
a step of sintering the mixture.
2. The method for producing the thermoelectric conversion element according to claim 1 , wherein the compound including Mn and Sb has a peak of a crystal structure of at least one of Mn1.1Sb and Mn2Sb observed by XRD.
3. The method for producing the thermoelectric conversion element according to claim 1 , wherein in the mixture, the sintering assistant is 10 mass % or less relative to a total amount of the thermoelectric conversion material powder and the sintering assistant.
4. The method for producing the thermoelectric conversion element according claim 1 , wherein the thermoelectric conversion material powder contains Yb and Co.
5. The method for producing the thermoelectric conversion element according to claim 1 , wherein the thermoelectric conversion material powder contains Ce and Fe.
6. The method for producing the thermoelectric conversion element according to claim 2 , wherein in the mixture, the sintering assistant is 10 mass % or less relative to a total amount of the powder thermoelectric conversion material powder and the sintering assistant.
7. The method for producing the thermoelectric conversion element according to claim 2 , wherein the thermoelectric conversion material powder contains Yb and Co.
8. The method for producing the thermoelectric conversion element according to claim 3 , wherein the thermoelectric conversion material powder contains Yb and Co.
9. The method for producing the thermoelectric conversion element according to claim 6 , wherein the thermoelectric conversion material powder contains Yb and Co.
10. The method for producing the thermoelectric conversion element according to claim 2 , wherein the thermoelectric conversion material powder contains Ce and Fe.
11. The method for producing the thermoelectric conversion element according to claim 3 , wherein the thermoelectric conversion material powder contains Ce and Fe.
12. The method for producing the thermoelectric conversion element according to claim 6 , wherein the thermoelectric conversion material powder contains Ce and Fe.