Semiconductor nanoparticle-based detection
View Patent ↗A detector includes a substrate including a matrix of aramid nanofibers, a distribution of nanoparticles across the matrix of aramid nanofibers, and a plurality of organic capping ligands. Each organic capping ligand of the plurality of organic capping ligands bonds a respective nanoparticle of the plurality of nanoparticles to a respective aramid nanofiber of the matrix of aramid nanofibers. The detector further includes first and second electrodes disposed along opposite sides of the substrate to capture charges generated by photons or particles incident upon the detector. Each nanoparticle of the plurality of nanoparticles has a semiconductor composition.
1 . A detector comprising:
a substrate comprising a matrix of aramid nanofibers;
a distribution of nanoparticles across the matrix of aramid nanofibers;
a plurality of organic capping ligands, each organic capping ligand of the plurality of organic capping ligands bonding a respective nanoparticle of the distribution of nanoparticles to a respective aramid nanofiber of the matrix of aramid nanofibers; and
first and second electrodes disposed along opposite sides of the substrate to capture charges generated by photons or particles incident upon the detector;
wherein each nanoparticle of the distribution of nanoparticles has a semiconductor composition.
2 . The detector of claim 1 , wherein:
each aramid nanofiber of the matrix of aramid nanofibers comprises a fiber backbone; and
the nanoparticles of the distribution of nanoparticles are aligned along the backbones of the matrix of aramid nanofibers.
3 . The detector of claim 1 , wherein the plurality of organic capping ligands establish hydrogen bonds with the matrix of aramid nanofibers.
4 . The detector of claim 1 , wherein each organic capping ligand of the plurality of organic capping ligands comprises 1-thioglycerol (TGOL).
5 . The detector of claim 1 , wherein each organic capping ligand of the plurality of organic capping ligands comprises Thioglycolic acid (TGA).
6 . The detector of claim 1 , wherein the semiconductor composition comprises cadmium telluride.
7 . The detector of claim 6 , wherein the cadmium telluride comprises cadmium and tellurium in a two-to-one ratio, respectively.
8 . The detector of claim 1 , wherein the semiconductor composition comprises lead telluride.
9 . A detector comprising:
a substrate comprising a matrix of aramid nanofibers;
a distribution of nanoparticles across the matrix of aramid nanofibers;
a plurality of organic capping ligands, each organic capping ligand of the plurality of organic capping ligands bonding a respective nanoparticle of the distribution of nanoparticles to a respective aramid nanofiber of the matrix of aramid nanofibers;
first and second electrodes disposed along opposite sides of the substrate to capture charges generated by photons or particles incident upon the detector; and
a plurality of metal nanoparticles distributed across the matrix of aramid nanofibers;
wherein each nanoparticle of the distribution of nanoparticles has a semiconductor composition.
10 . The detector of claim 9 , wherein each metal nanoparticle of the plurality of metal nanoparticles comprises silver.
11 . The detector of claim 1 , wherein:
the first electrode comprises a gold hole transport layer; and
the second electrode comprises an indium electron transport layer.
12 . The detector of claim 1 , wherein each nanoparticle of the distribution of nanoparticles is sized to establish a bandgap for detection of ionizing radiation.
13 . The detector of claim 1 , wherein at least some nanoparticles of the distribution of nanoparticles have a diameter less than about 10 nanometers.
14 . The detector of claim 1 , wherein the substrate and the first and second electrodes are disposed in respective layers of a planar structure.
15 . The detector of claim 14 , wherein the planar structure has a thickness falling in a range from about 30 micrometers to about 50 micrometers.
16 . A method of fabricating a detector, the method comprising:
preparing a film comprising a matrix of aramid nanofibers;
synthesizing, in a solution, a plurality of nanoparticles, each nanoparticle of the plurality of nanoparticles being synthesized such that an organic capping ligand is attached to the nanoparticle; and
infiltrating the film with the plurality of nanoparticles such that each nanoparticle of the plurality of nanoparticles is bonded to a respective aramid nanofiber of the matrix of aramid nanofibers via the organic capping ligand;
wherein each nanoparticle of the plurality of nanoparticles has a semiconductor composition.
17 . The method of claim 16 , wherein synthesizing the plurality of nanoparticles comprises implementing a vacuum filtration procedure in which the film is disposed as a filtration membrane.
18 . The method of claim 16 , further comprising:
synthesizing, in a further solution, a plurality of metal nanoparticles; and
infiltrating the film with the plurality of metal nanoparticles after infiltrating the film with the plurality of nanoparticles having the semiconductor composition.
19 . The method of claim 16 , further comprising depositing first and second electrodes along opposite sides of the film.
20 . The method of claim 16 , wherein synthesizing the plurality of nanoparticles comprises adding 1-thioglycerol (TGOL) to the solution to provide the organic capping ligand for each nanoparticle of the plurality of nanoparticles.