Apparatus for reducing greenhouse gas emission in vessel and vessel including the same

1. An apparatus for reducing greenhouse gas emission in a vessel, the apparatus comprising:

a seawater supply unit that supplies seawater;

an ammonia water producing unit that reacts fresh water with NH 3 to produce and supply ammonia water;

an absorption tower comprising a CO 2 removing unit that cools exhaust gas discharged from a vessel engine by reacting the exhaust gas with the seawater supplied from the seawater supply unit, and removes CO 2 by reacting the cooled exhaust gas with the ammonia water supplied from the ammonia water producing unit to convert CO 2 into NH 4 HCO 3 (aq); and

an ammonia recycling unit that recycles NH 3 by reacting NH 4 HCO 3 (aq) discharged from the absorption tower with Ca(OH) 2 or Mg(OH) 2 , and returns the recycled NH 3 back to the ammonia water producing unit.

2. The apparatus according to claim 1 , wherein the absorption tower further comprises a NO X absorbing unit that absorbs and removes NO X of the exhaust gas discharged from the vessel engine,

the CO 2 removing unit cools the exhaust gas, from which the NO X is removed, by reacting the exhaust gas with the seawater supplied from the seawater supply unit, and removes CO 2 by reacting the cooled exhaust gas with the ammonia water supplied from the ammonia water producing unit to convert CO 2 into NH 4 HCO 3 (aq), and

the ammonia recycling unit recycles NH 3 and returns the recycled NH 3 back to the ammonia water producing unit and the NO X absorbing unit.

3. The apparatus according to claim 2 , wherein the NO X absorbing unit directly receives NH 3 from the ammonia recycling unit through a blower or a compressor and sprays the received NH 3 to a first NH 3 spray nozzle, or when NH 3 is insufficient, the NO X absorbing unit receives urea water of a urea water storage tank through a urea water supply pump and sprays the received urea water to a second NH 3 spray nozzle so as to compensate for the lack of NH 3 .

4. The apparatus according to claim 1 , wherein the absorption tower further comprises a SO X absorbing unit that dissolves and removes SO X while cooling the exhaust gas discharged from the vessel engine by reacting the exhaust gas with the seawater supplied from the seawater supply unit, and

the CO 2 removing unit removes CO 2 by reacting the exhaust gas, from which the SO X is removed, with the ammonia water supplied from the ammonia water producing unit to convert CO 2 into NH 4 HCO 3 (aq).

5. The apparatus according to claim 1 , wherein, in the absorption tower, a NO X absorbing unit that absorbs and removes NO X from the exhaust gas discharged from the vessel engine, a SO X absorbing unit that dissolves and removes SO X while cooling the exhaust gas, from which the NO X has been removed, through reaction with the seawater supplied from the seawater supply unit, and the CO 2 removing unit that removes CO 2 by reacting the exhaust gas, from which the SO X has been removed, with the ammonia water supplied from the ammonia water producing unit to convert CO 2 into NH 4 HCO 3 (aq) are stacked, and

the ammonia recycling unit recycles NH 3 and returns the recycled NH 3 back to the ammonia water producing unit and the NO X absorbing unit.

6. The apparatus according to claim 5 , wherein the absorption tower further comprises an exhaust gas economizer (EGE) that is formed between the NO X absorbing unit and the SO X absorbing unit and performs heat exchange between waste heat of the vessel engine and boiler water.

7. The apparatus according to claim 5 , wherein the NO X absorbing unit directly receives NH 3 from the ammonia recycling unit through a blower or a compressor and sprays the received NH 3 to a first NH 3 spray nozzle, or

when NH 3 is insufficient, the NO X absorbing unit receives urea water of a urea water storage tank through a urea water supply pump and sprays the received urea water to a second NH 3 spray nozzle so as to compensate for the lack of NH 3 .

8. The apparatus according to claim 1 , wherein the ammonia water producing unit comprises:

a fresh water tank that stores fresh water;

a fresh water pump that pumps and supplies the fresh water from the fresh water tank;

an ammonia water production tower comprising a tower tank, a NH 3 spray nozzle that is formed at a lower end of the tower tank and sprays NH 3 upward, a fresh water spray nozzle that is formed at an upper end of the tower tank and sprays the fresh water from the fresh water pump downward, a first packing material that is formed between the NH 3 spray nozzle and the fresh water spray nozzle and contacts the fresh water with NH 3 to dissolve NH 3 and generate ammonia water, and a cooling jacket that cools heat generated by the tower tank due to a dissolution reaction; and

an ammonia water pump that supplies ammonia water from an ammonia water storage tank, which stores ammonia water drained to a lower end of the ammonia water production tower, to an upper end of the CO 2 removing unit.

9. The apparatus according to claim 8 , wherein the ammonia water production tower comprises a mist removal plate that is formed at the upper end of the tower tank in a curved multi-plate shape and returns mist scattered from the fresh water toward the first packing material.

10. The apparatus according to claim 8 , further comprising a NH 3 supply pipe through which NH 3 exhausted to the upper end of the ammonia water production tower is supplied to an lower end of the CO 2 removing unit.

11. The apparatus according to claim 8 , wherein the first packing material comprises multi-stage distilling column packings designed to increase a contact area per unit volume.

12. The apparatus according to claim 11 , wherein a solution redistributor is formed between the multi-stage distilling column packings.

13. The apparatus according to claim 8 , wherein a diameter and a height of the tower tank are designed so that a flow velocity of the fresh water and a flow velocity of the NH 3 are ½ of a flooding velocity.

14. The apparatus according to claim 8 , wherein the loss and lack of NH 3 are compensated for by supplying NH 3 from the ammonia recycling unit through the NH 3 spray nozzle of the ammonia water producing unit or supplying NH 3 from a separate NH 3 storage tank when the loss and lack of NH 3 occur.

15. The apparatus according to claim 8 , wherein the CO 2 removing unit comprises:

an ammonia water spray nozzle that is connected to the ammonia water pump and sprays ammonia water downward;

a second packing material that contacts CO 2 with the ammonia water and converts CO 2 into NH 4 HCO 3 (aq);

a cooling jacket that is formed in multi-stages for each section of an absorption apparatus filled with the second packing material and cools heat generated by a CO 2 removal reaction;

a water spray that collects NH 3 discharged to the outside without reacting with CO 2 ;

a mist removal plate that is formed in a curved multi-plate shape and returns the ammonia water toward the second packing material;

a partition wall that is formed so that the ammonia water does not flow backward; and

an umbrella-shaped blocking plate that covers an exhaust gas inlet hole of the partition wall.

16. The apparatus according to claim 8 , wherein the ammonia recycling unit comprises:

a Ca(OH) 2 storage tank that stores Ca(OH) 2 ;

a mixing tank in which NH 4 HCO 3 (aq) discharged from the absorption tower is stirred with Ca(OH) 2 by an agitator to generate CaCO 3 (s) and H 2 O and NH 3 (g) is recycled;

a filter that suctions a solution and precipitate from the mixing tank and separates CaCO 3 (s);

a high-pressure pump that transfers the solution and precipitate to the filter at high pressure; and

a CaCO 3 (s) storage tank that stores a slurry or CaCO 3 (s) of a solid state.

17. The apparatus according to claim 16 , wherein ammonia water or fresh water separated by the filter is supplied to the ammonia water producing unit, or excess ammonia water or excess fresh water additionally generated by the mixing tank compared to a total circulating fresh water is stored in the fresh water tank.

18. The apparatus according to claim 8 , wherein the ammonia recycling unit comprises:

a Mg(OH) 2 storage tank that stores Mg(OH) 2 ;

a mixing tank in which NH 4 HCO 3 (aq) discharged from the absorption tower is stirred with Mg(OH) 2 by an agitator to generate MgCO 3 (s) and H 2 O and NH 3 (g) is recycled;

a filter that suctions a solution and precipitate from the mixing tank and separates MgCO 3 (s);

a high-pressure pump that transfers the solution and precipitate to the filter at high pressure; and

a MgCO 3 (s) storage tank that stores a slurry or MgCO 3 (s) of a solid state.

19. The apparatus according to claim 18 , wherein ammonia water or fresh water separated by the filter is supplied to the ammonia water producing unit, or excess ammonia water or excess fresh water additionally generated by the mixing tank compared to a total circulating fresh water is stored in the fresh water tank.

20. The apparatus according to claim 1 , further comprising a discharge unit comprising:

a cleaning water tank that stores cleaning water discharged from the absorption tower;

a water treatment device comprising a filtering unit that controls turbidity to satisfy an outboard discharge condition of the cleaning water transferred to the cleaning water tank by a transfer pump, and a neutralizing agent injecting unit that controls pH; and

a sludge storage tank that separates and stores solid emissions.