Granted Patent
B2
US 12,719,073 · App. 17/924,473 · Granted Aug 25, 2026
Redox relay flow batteries and methods of making the same
View Patent ↗
Loading inventors, assignments & file history…
Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST
Recorded Nov 10, 2022
From: SEVOV, CHRISTO; WONG, CURT
To: OHIO STATE INNOVATION FOUNDATION
Reel/Frame 061718/0937 →
Continuity (2)
Provisional Application
63024598
· May 14, 2020
References Cited (134)
US 20140030623A1
· Chiang
· 2014
[cited by examiner]
US 20140239906A1
· Anderson
· 2014
[cited by examiner]
CN 108933271A
· 2018
[cited by applicant]
EP 0197465A2
· 1986
[cited by examiner]
JP 6397847B2
· 2018
[cited by applicant]
WO 2012083233A1
· 2012
[cited by applicant]
Aminabhavi, T. M.; Balundgi, R. H.; Cassidy, P. E. A Review on Biodegradable Plastics. Polym. Plast. Technol. Eng. 1990, 29 (3), 235-262. https://doi.org/10.1080/03602559008049843.
[cited by applicant]
Asua, J. M. Emulsion Polymerization: From Fundamental Mechanisms to Process Developments. J. Polym. Sci. Part A Polym. Chem. 2004, 42 (5), 1025-1041. https://doi.org/10.1002/pola.11096.
[cited by applicant]
Beh, E. S.; De Porcellinis, D.; Gracia, R. L.; Xia, K. T .; Gordon, R. G.; Aziz, M. J. A Neutral PH Aqueous Organic-Organometallic Redox Flow Battery with Extremely High Capacity Retention. ACS Energy Lett. 2017, 2 (3),…
[cited by applicant]
Bozorg, M.; Hankiewicz, B.; Abetz, V. Solubility Behaviour of Random and Gradient Copolymers of Di- and Oligo(Ethylene Oxide) Methacrylate in Water: Effect of Various Additives. Soft Matter 2020, 16 (4), 1066-1081. http…
[cited by applicant]
Bugnon, L.; Morton, C. J. H.; Novak, P.; Vetter, J.; Nesvadba, P. Synthesis of Poly(4-Methacryloyloxy-TEMPO) via Group-Transfer Polymerization and Its Evaluation in Organic Radical Battery. Chem. Mater. 2007, 19, 2910-2…
[cited by applicant]
Burgess, M.; Chénard, E.; Hernández-Burgos, K.; Nagarjuna, G.; Assary, R. S.; Hui, J.; Moore, J. S.; Rodríguez-López, J. Impact of Backbone Tether Length and Structure on the Electrochemical Performance of Viologen Redo…
[cited by applicant]
Burgess, M.; Hernández-Burgos, K.; Schuh, J. K.; Davila, J.; Montoto, E. C.; Ewoldt, R. H.; Rodríguez-López, J. Modulation of the Electrochemical Reactivity of Solubilized Redox Active Polymers via Polyelectrolyte Dynam…
[cited by applicant]
Burgess, M.; Hernández-Burgos, K.; Simpson, B. H.; Lichtenstein, T.; Avetian, S.; Nagarjuna, G.; Cheng, K. J.; Moore, J. S.; Rodríguez-López, J. Scanning Electrochemical Microscopy and Hydrodynamic Voltammetry Investiga…
[cited by applicant]
Cabrera, P. J.; Yang, X.; Suttil, J. A.; Brooner, R. E. M.; Thompson, L. T.; Sanford, M. S. Evaluation of Tris-Bipyridine Chromium Complexes for Flow Battery Applications: Impact of Bipyridine Ligand Structure on Solubi…
[cited by applicant]
Cabrera, P. J.; Yang, X.; Suttil, J. A.; Hawthorne, K. L.; Brooner, R. E. M.; Sanford, M. S.; Thompson, L. T. Complexes Containing Redox Noninnocent Ligands for Symmetric, Multielectron Transfer Nonaqueous Redox Flow Ba…
[cited by applicant]
Carino, E. V; Diesendruck, C. E.; Moore, J. S.; Curtiss, L. A.; Assary, R. S.; Brushett, F. R. BF 3-Promoted Electrochemical Properties of Quinoxaline in Propylene Carbonate. RSC Adv. 2015, 5 (24), 18822-18831. https://…
[cited by applicant]
Moeller, K. D. (2018). Using Physical Organic Chemistry to Shape the Course of Electrochemical Reactions. Chemical Reviews, 118(9), 4817-4833. doi:10.1021/acs.chemrev.7b00656 https://doi.org/10.1021/acs.chemrev.7b00656.
[cited by applicant]
Chen, H.; Tu, H.; Hu, C.; Liu, Y.; Dong, D.; Sun, Y.; Dai, Y.; Wang, S.; Qian, H.; Lin, Z.; et al. Cationic Covalent Organic Framework Nanosheets for Fast Li-Ion Conduction. J. Am. Chem. Soc. 2018, No. step II, jacs.7b1…
[cited by applicant]
Chen, Y.; Zhou, M.; Xia, Y.; Wang, X.; Liu, Y.; Yao, Y.; Zhang, H.; Li, Y.; Lu, S.; Qin, W.; Wu, X.; Wang, Q. A Stable and High-Capacity Redox Targeting-Based Electrolyte for Aqueous Flow Batteries. Joule 2019, 3 (9), 2…
[cited by applicant]
Cheng, Y.; Wang, X.; Huang, S.; Samarakoon, W.; Xi, S.; Ji, Y.; Zhang, H.; Zhang, F.; Du, Y.; Feng, Z.; Adams, S.; Wang, Q. Redox Targeting-Based Vanadium Redox-Flow Battery. ACS Energy Lett. 2019, 4, 3028-3035. https:/…
[cited by applicant]
Darling, R. M.; Gallagher, K. G.; Kowalski, J. A.; Ha, S.; Brushett, F. R. Pathways to Low-Cost Electrochemical Energy Storage: A Comparison of Aqueous and Nonaqueous Flow Batteries. Energy Environ. Sci. 2014, 7 (11), 3…
[cited by applicant]
DeBruler, C.; Hu, B.; Moss, J.; Luo, J.; Liu, T. L. A Sulfonate-Functionalized Viologen Enabling Neutral Cation Exchange, Aqueous Organic Redox Flow Batteries toward Renewable Energy Storage. ACS Energy Lett. 2018, No. …
[cited by applicant]
Derible, A.; Diebold, C.; Dentzer, J.; Gadiou, R.; Becht, J. M.; Le Drian, C. A Palladium Catalyst Supported on Carbon-Coated Cobalt Nanoparticles-Preparation of Palladium-Free Biaryls by Suzuki-Miyaura Reactions in Eth…
[cited by applicant]
Dmello, R.; Milshtein, J. D.; Brushett, F. R.; Smith, K. C. Cost-Driven Materials Selection Criteria for Redox Flow Battery Electrolytes. J. Power Sources 2016, 330, 261-272. https://doi.org/10.1016/j.jpowsour.2016.08.1…
[cited by applicant]
Doris, S. E.; Ward, A. L.; Baskin, A.; Frischmann, P. D.; Gavvalapalli, N.; Chénard, E.; Sevov, C. S.; Prendergast, D.; Moore, J. S.; Helms, B. A. Macromolecular Design Strategies for Preventing Active-Material Crossove…
[cited by applicant]
Duan, W.; Huang, J.; Kowalski, J. A.; Shkrob, I. A.; Vijayakumar, M.; Walter, E.; Pan, B.; Yang, Z.; Milshtein, J. D.; Li, B.; et al. “wine-Dark Sea” in an Organic Flow Battery: Storing Negative Charge in 2,1,3-Benzothi…
[cited by applicant]
Duan, W.; Huang, J.; Kowalski, J. A.; Shkrob, I. A.; Vijayakumar, M.; Walter, E.; Pan, B.; Yang, Z.; Milshtein, J. D.; Li, B.; Liao, C.; Zhang, Z.; Wang, W.; Liu, J.; Moore, J. S.; Brushett, F. R.; Zhang, L.; Wei, X. “w…
[cited by applicant]
Dunn, B.; Kamath, H.; Tarascon, J. M. Electrical Energy Storage for the Grid: A Battery of Choices. Science. American Association for the Advancement of Science Nov. 18, 2011, pp. 928-935. https://doi.org/10.1126/scienc…
[cited by applicant]
Elsenbaumer, R. L.; Jen, K. Y.; Oboodi, R. Processible and Environmentally Stable Conducting Polymers. Synth. Met. 1986, 15 (2-3), 169-174. https://doi.org/10.1016/0379-6779(86)90020-2.
[cited by applicant]
Energy Information Administration, U. Annual Energy Outlook 2019 with Projections to 2050; 2019.
[cited by applicant]
Friedrich, J. M.; Ponce-de-León, C.; Reade, G. W.; Walsh, F. C. Reticulated Vitreous Carbon as an Electrode Material. J. Electroanal. Chem. 2004, 561, 203-217. https://doi.org/10.1016/j.jelechem.2003.07.019.
[cited by applicant]
Gaultois, M. W.; Sparks, T. D.; H Borg, C. K.; Seshadri, R.; Bonificio, W. D.; Clarke, D. R. Data-Driven Review of Thermoelectric Materials: Performance and Resource Considerations. Chem. Mater. 2013, 25, 2911-2920. htt…
[cited by applicant]
Gietter, A. A. S.; Pupillo, R. C.; Yap, G. P. A.; Beebe, T. P.; Rosenthal, J.; Watson, D. A. On-Surface Cross-Coupling Methods for the Construction of Modified Electrode Assemblies with Tailored Morphologies. Chem. Sci.…
[cited by applicant]
Gossage, Z. T.; Schorr, N. B.; Hernández-Burgos, K.; Hui, J.; Simpson, B. H.; Montoto, E. C.; Rodríguez-López, J. Interrogating Charge Storage on Redox Active Colloids via Combined Raman Spectroscopy and Scanning Electr…
[cited by applicant]
Greene, A. F.; Danielson, M. K.; Delawder, A. O.; Liles, K. P.; Li, X.; Natraj, A.; Wellen, A.; Barnes, J. C. Redox-Responsive Artificial Molecular Muscles: Reversible Radical-Based Self-Assembly for Actuating Hydrogels…
[cited by applicant]
Gür, T. M. Review of Electrical Energy Storage Technologies, Materials and Systems: Challenges and Prospects for Large-Scale Grid Storage. Energy Environ. Sci 2018, 11, 2696. https://doi.org/10.1039/c8ee01419a.
[cited by applicant]
Haegel, N. M.; Margolis, R.; Buonassisi, T.; Feldman, D.; Froitzheim, A.; Garabedian, R.; Green, M.; Glunz, S.; Henning, H.-M.; Holder, B.; et al. Terawatt-Scale Photovoltaics: Trajectories and Challenges. Science (80-.…
[cited by applicant]
Hearne, S. J.; Iacopi, F.; Faunce, T. A.; Su, D.; Prest, J. On-Grid Batteries for Large-Scale Energy Storage: Challenges and Opportunities for Policy and Technology. MRS Energy Sustain. 2018. https://doi.org/10.1557/mre…
[cited by applicant]
Hendriks, K. H.; Robinson, S. G.; Braten, M. N.; Sevov, C. S.; Helms, B. A.; Sigman, M. S.; Minteer, S. D.; Sanford, M. S. High-Performance Oligomeric Catholytes for Effective Macromolecular Separation in Nonaqueous Red…
[cited by applicant]
Hendriks, K. H.; Robinson, S. G.; Braten, M. N.; Sevov, C. S.; Helms, B. A.; Sigman, M. S.; Minteer, S. D.; Sanford, M. S. High-Performance Oligomeric Catholytes for Effective Macromolecular Separation in Nonaqueous Red…
[cited by applicant]
Hendriks, K. H.; Sevov, C. S.; Cook, M. E.; Sanford, M. S. Multielectron Cycling of a Low-Potential Anolyte in Alkali Metal Electrolytes for Nonaqueous Redox Flow Batteries. ACS Energy Lett. 2017, 2 (10), 2430-2435. htt…
[cited by applicant]
Hensel, J. K.; Carpenter, A. P.; Ciszewski, R. K.; Schabes, B. K.; Kittredge, C. T.; Moore, F. G.; Richmond, G. L. Molecular Characterization of Water and Surfactant AOT at Nanoemulsion Surfaces. Proc. Natl. Acad. Sci. …
[cited by applicant]
Hu, B.; Luo, J.; Hu, M.; Yuan, B.; Liu, T. L. A PH-Neutral, Metal-Free Aqueous Organic Redox Flow Battery Employing an Ammonium Anthraquinone Anolyte. Angew. Chemie Int. Ed. 2019, 58 (46), 16629-16636. https://doi.org/1…
[cited by applicant]
Hu, B.; Tang, Y.; Luo, J.; Grove, G.; Guo, Y.; Liu, T. L. Improved Radical Stability of Viologen Anolytes in Aqueous Organic Redox Flow Batteries. Chem. Commun. 2018, 54 (50), 6871-6874. https://doi.org/10.1039/C8CC0233…
[cited by applicant]
Huang, J.; Su, L.; Kowalski, J. A.; Barton, J. L.; Ferrandon, M.; Burrell, A. K.; Brushett, F. R.; Zhang, L. A Subtractive Approach to Molecular Engineering of Dimethoxybenzene-Based Redox Materials for Non-Aqueous Flow…
[cited by applicant]
Huang, J.; Yang, Z.; Murugesan, V.; Walter, E.; Hollas, A.; Pan, B.; Assary, R. S.; Shkrob, I. A.; Wei, X.; Zhang, Z. Spatially Constrained Organic Diquat Anolyte for Stable Aqueous Flow Batteries. ACS Energy Lett. 2018…
[cited by applicant]
Huang, Q.; Yang, J.; Ng, C. B.; Jia, C.; Wang, Q. A Redox Flow Lithium Battery Based on the Redox Targeting Reactions between LiFePO4 and Iodide. Energy Environ. Sci. 2016, 9 (3), 917-921. https://doi.org/10.1039/C5EE03…
[cited by applicant]
Hyun-woo, N. Frequent Fire Raising Concerns over Safety of Solar Energy. The Korea Times. Dec. 18, 2018.
[cited by applicant]
Ibe, T.; Frings, R. B.; Lachowicz, A.; Kyo, S.; Nishide, H. Nitroxide Polymer Networks Formed by Michael Addition: On Site-Cured Electrode-Active Organic Coatingw. Chem. Commun. 2010, 46, 3475-3477. https://doi.org/10.1…
[cited by applicant]
Iyer, V. A.; Schuh, J. K.; Montoto, E. C.; Pavan Nemani, V.; Qian, S.; Nagarjuna, G.; Rodríguez-López, J.; Ewoldt, R. H.; Smith, K. C. Assessing the Impact of Electrolyte Conductivity and Viscosity on the Reactor Cost a…
[cited by applicant]
Jadoun, S.; Riaz, U. A Review on the Chemical and Electrochemical Copolymerization of Conducting Monomers: Recent Advancements and Future Prospects. Polym. Plast. Technol. Eng. 2020, 59 (5), 484-504. https://doi.org/10.…
[cited by applicant]
Jalkh, J.; Leroux, Y. R.; Vacher, A.; Lorcy, D.; Hapiot, P.; Lagrost, C. Tetrathiafulvalene-Tetracyanoquinodimethane Charge-Transfer Complexes Wired to Carbon Surfaces: Tuning of the Degree of Charge Transfer. J. Phys. …
[cited by applicant]
Janoschka, T.; Hager, M. D.; Schubert, U. S. Powering up the Future: Radical Polymers for Battery Applications. Adv. Mater. 2012, 24 (48), 6397-6409. https://doi.org/10.1002/adma.201203119.
[cited by applicant]
Janoschka, T.; Martin, N.; Hager, M. D.; Schubert, U. S. An Aqueous Redox-Flow Battery with High Capacity and Power: The TEMPTMA/MV System. Angew. Chemie Int. Ed. 2016, 55 (46), 14427-14430. https://doi.org/10.1002/anie…
[cited by applicant]
Janoschka, T.; Martin, N.; Martin, U.; Friebe, C.; Morgenstern, S.; Hiller, H.; Hager, M. D.; Schubert, U. S. An Aqueous, Polymer-Based Redox-Flow Battery Using Non-Corrosive, Safe, and Low-Cost Materials. Nature 2015, …
[cited by applicant]
Janoschka, T.; Morgenstern, S.; Hiller, H.; Friebe, C.; Wolkersdörfer, K.; Häupler, B.; Hager, M. D.; Schubert, U. S. Synthesis and Characterization of TEMPO- and Viologen-Polymers for Water-Based Redox-Flow Batteries. …
[cited by applicant]
Ji, Y.; Goulet, M.; Pollack, D. A.; Kwabi, D. G.; Jin, S.; Porcellinis, D.; Kerr, E. F.; Gordon, R. G.; Aziz, M. J. A Phosphonate-Functionalized Quinone Redox Flow Battery at Near-Neutral PH with Record Capacity Retenti…
[cited by applicant]
Jia, C.; Pan, F.; Zhu, Y. G.; Huang, Q.; Lu, L.; Wang, Q. High-Energy Density Nonaqueous All Redox Flow Lithium Battery Enabled with a Polymeric Membrane. Sci. Adv. 2015, 1 (10), 1-7. https://doi.org/10.1126/sciadv.1500…
[cited by applicant]
Jin, S.; Fell, E. M.; Vina-Lopez, L.; Jing, Y.; Michalak, P. W.; Gordon, R. G.; Aziz, M. J. Near Neutral PH Redox Flow Battery with Low Permeability and Long-Lifetime Phosphonated Viologen Active Species. Adv. Energy Ma…
[cited by applicant]
Jing, Y.; Wu, M.; Wong, A. A.; Fell, E. M.; Jin, S.; Pollack, D. A.; Kerr, E. F.; Gordon, R. G.; Aziz, M. J. In Situ Electrosynthesis of Anthraquinone Electrolytes in Aqueous Flow Batteries. Green Chem. 2020, 22 (18), 6…
[cited by applicant]
Johnson, B. M.; Francke, R.; Little, R. D.; Berben, L. A. High Turnover in Electro-Oxidation of Alcohols and Ethers with a Glassy Carbon-Supported Phenanthroimidazole Mediator. Chem. Sci. 2017, 8 (9), 6493-6498. https:/…
[cited by applicant]
Li, W.; Kerr, E.; Goulet, M.; Fu, H.; Zhao, Y.; Yang, Y.; Veyssal, A.; He, J.; Gordon, R. G.; Aziz, M. J.; Jin, S. A Long Lifetime Aqueous Organic Solar Flow Battery. Adv. Energy Mater. 2019, 9 (31), 1900918. https://do…
[cited by applicant]
Li, Y.; Xu, Z.; Liu, Y.; Jin, S.; Fell, E. M.; Wang, B.; Gordon, R. G.; Aziz, M. J.; Yang, Z.; Xu, T. Functioning Water-Insoluble Ferrocenes for Aqueous Organic Flow Battery via Host-Guest Inclusion. ChemSusChem 2021, 1…
[cited by applicant]
Liles, K. P.; Greene, A. F.; Danielson, M. K.; Colley, N. D.; Wellen, A.; Fisher, J. M.; Barnes, J. C. Photoredox-Based Actuation of an Artificial Molecular Muscle. Macromol. Rapid Commun. 2018, 39 (17), 1700781. https:…
[cited by applicant]
Lin, K.; Chen, Q.; Gerhardt, M. R.; Tong, L.; Kim, S. B.; Eisenach, L.; Valle, A. W.; Hardee, D.; Gordon, R. G.; Aziz, M. J.; Marshak, M. P. Alkaline Quinone Flow Battery. Science (80-. ). 2015, 349 (6255), 1529-1532. h…
[cited by applicant]
Lin, K.; Gómez-Bombarelli, R.; Beh, E. S.; Tong, L.; Chen, Q.; Valle, A.; Aspuru-Guzik, A.; Aziz, M. J.; Gordon, R. G. A Redox-Flow Battery with an Alloxazine-Based Organic Electrolyte. Nat. Energy 2016, 1 (9), 16102. h…
[cited by applicant]
Liu, T.; Wei, X.; Nie, Z.; Sprenkle, V.; Wang, W. A Total Organic Aqueous Redox Flow Battery Employing a Low Cost and Sustainable Methyl Viologen Anolyte and 4-HO-TEMPO Catholyte. Adv. Energy Mater. 2016, 6 (3), 1-8. ht…
[cited by applicant]
Liu, T.; Zhang, Y.; Jiang, Z.; Zeng, X.; Ji, J.; Li, Z.; Gao, X.; Sun, M.; Lin, Z.; Ling, M.; et al. Exploring Competitive Features of Stationary Sodium Ion Batteries for Electrochemical Energy Storage. Energy Environ. …
[cited by applicant]
Liu, W.; Liu, Y.; Zhang, H.; Xie, C.; Shi, L.; Zhou, Y.-G.; Li, X. A Highly Stable Neutral Viologen/Bromine Aqueous Flow Battery with High Energy and Power Density. Chem. Commun. 2019, 55 (33), 4801-4804. https://doi.or…
[cited by applicant]
Ma, T.; Pan, Z.; Miao, L.; Chen, C.; Han, M.; Shang, Z.; Chen, J. Porphyrin-Based Symmetric Redox-Flow Batteries towards Cold-Climate Energy Storage. Angew. Chemie—Int. Ed. 2018, 130 (12), 3212-3216. https://doi.org/10.…
[cited by applicant]
Maharjan, M.; Wai, N.; Veksha, A.; Giannis, A.; Lim, T. M.; Lisak, G. Sal Wood Sawdust Derived Highly Mesoporous Carbon as Prospective Electrode Material for Vanadium Redox Flow Batteries. J. Electroanal. Chem. 2019, 83…
[cited by applicant]
McCulloch, W. D.; Yu, M.; Wu, Y. PH-Tuning a Solar Redox Flow Battery for Integrated Energy Conversion and Storage. ACS Energy Lett. 2016, 1 (3), 578-582. https://doi.org/10.1021/acsenergylett.6b00296.
[cited by applicant]
Milshtein, J. D.; Barton, J. L.; Darling, R. M.; Brushett, F. R. 4-Acetamido-2,2,6,6-Tetramethylpiperidine-1-Oxyl as a Model Organic Redox Active Compound for Nonaqueous Flow Batteries. J. Power Sources 2016, 327, 151-1…
[cited by applicant]
Moeller, K. D. Using Physical Organic Chemistry to Shape the Course of Electrochemical Reactions.
[cited by applicant]
Montoto, E. C.; Cao, Y.; Kenneth Hernándezhernández-Burgos; Sevov, C. S.; Braten, M. N.; Helms, B. A.; Moore, J. S.; Rodríguez-Lópezlópez, J. Effect of the Backbone Tether on the Electrochemical Properties of Soluble Cy…
[cited by applicant]
Montoto, E. C.; Nagarjuna, G.; Hui, J.; Burgess, M.; Sekerak, N. M.; Hernández-Burgos, K.; Wei, T.-S.; Kneer, M.; Grolman, J.; Cheng, K. J.; Lewis, J. A.; Moore, J. S.; Rodríguez-López, J. Redox Active Colloids as Discr…
[cited by applicant]
Montoto, E. C.; Nagarjuna, G.; Moore, J. S.; Rodríguez-López, J. Redox Active Polymers for Non-Aqueous Redox Flow Batteries: Validation of the Size-Exclusion Approach. J. Electrochem. Soc. 2017, 164 (7), A1688-A1694. ht…
[cited by applicant]
Muench, S.; Wild, A.; Friebe, C.; Ha, B.; Janoschka, T.; Schubert, U. S. Polymer-Based Organic Batteries. Chem. Rev. 2016, No. 116, 9438-9484. https://doi.org/10.1021/acs.chemrev.6b00070.
[cited by applicant]
Nagarjuna, G.; Hui, J.; Cheng, K. J.; Lichtenstein, T.; Shen, M.; Moore, J. S.; Rodríguez-López, J. Impact of Redox-Active Polymer Molecular Weight on the Electrochemical Properties and Transport Across Porous Separator…
[cited by applicant]
Ortiz-Medina, J.; Wang, Z.; Cruz-Silva, R.; Morelos-Gomez, A.; Wang, F.; Yao, X.; Terrones, M.; Endo, M. Defect Engineering and Surface Functionalization of Nanocarbons for Metal-Free Catalysis. Adv. Mater. 2019, 180571…
[cited by applicant]
Pan, F.; Yang, J.; Huang, Q.; Wang, X.; Huang, H.; Wang, Q. Redox Targeting of Anatase TiO 2 for Redox Flow Lithium-Ion Batteries. Adv. Energy Mater. 2014, 4 (15), 1400567. https://doi.org/10.1002/aenm.201400567.
[cited by applicant]
Perry, M. L.; Weber, A. Z. Advanced Redox-Flow Batteries: A Perspective. J. Electrochem. Soc. 2016, 163 (1), A5064-A5067. https://doi.org/10.1149/2.0101601jes.
[cited by applicant]
Perticarari, S.; Sayed-Ahmad-Baraza, Y.; Ewels, C.; Moreau, P.; Guyomard, D.; Poizot, P.; Odobel, F.; Gaubicher, J. Dual Anion-Cation Reversible Insertion in a Bipyridinium-Diamide Triad as the Negative Electrode for Aq…
[cited by applicant]
Phal, S.; Shatri, B.; Berisha, A.; Geladi, P.; Lindholm-Sethson, B.; Tesfalidet, S. Covalently Electrografted Carboxyphenyl Layers onto Gold Surface Serving as a Platform for the Construction of an Immunosensor for Dete…
[cited by applicant]
Pinson, J.; Podvorica, F. Attachment of Organic Layers to Conductive or Semiconductive Surfaces by Reduction of Diazonium Salts. Chem. Soc. Rev. 2005, 34 (5), 429-439. https://doi.org/10.1039/b406228k.
[cited by applicant]
Ponce de León, C.; Frías-Ferrer, A.; González-García, J.; Szánto, D. A.; Walsh, F. C. Redox Flow Cells for Energy Conversion. J. Power Sources 2006, 160 (1), 716-732. https://doi.org/10.1016/j.jpowsour.2006.02.095.
[cited by applicant]
Roe, S.; Menictas, C.; Skyllas-Kazacos, M. A High Energy Density Vanadium Redox Flow Battery with 3 M Vanadium Electrolyte. J. Electrochem. Soc. 2015, 163 (1), A5023-A5028. https://doi.org/10.1149/2.0041601jes.
[cited by applicant]
Ruckenstein, E.; Li, Z. F. Surface Modification and Functionalization through the Self-Assembled Monolayer and Graft Polymerization. Adv. Colloid Interface Sci. 2005, 113 (1), 43-63. https://doi.org/10.1016/J.CIS.2004.0…
[cited by applicant]
Schon, T. B.; McAllister, B. T.; Li, P.-F.; Seferos, D. S. The Rise of Organic Electrode Materials for Energy Storage. Chem. Soc. Rev. 2016, 45 (22), 6345-6404. https://doi.org/10.1039/C6CS00173D.
[cited by applicant]
Sevov, C. S.; Brooner, R. E. M.; Chénard, E.; Assary, R. S.; Moore, J. S.; Rodríguez-López, J.; Sanford, M. S. Evolutionary Design of Low Molecular Weight Organic Anolyte Materials for Applications in Nonaqueous Redox F…
[cited by applicant]
Sevov, C. S.; Fisher, S. L.; Thompson, L. T.; Sanford, M. S. Mechanism-Based Development of a Low-Potential, Soluble, and Cyclable Multielectron Anolyte for Nonaqueous Redox Flow Batteries. J. Am. Chem. Soc. 2016, 138 (…
[cited by applicant]
Sevov, C. S.; Hendriks, K. H.; Sanford, M. S. Low-Potential Pyridinium Anolyte for Aqueous Redox Flow Batteries. J. Phys. Chem. C 2017, 121 (39), 24376-24380. https://doi.org/10.1021/acs.jpcc.7b06247.
[cited by applicant]
Sevov, C. S.; Hickey, D. P.; Cook, M. E.; Robinson, S. G.; Barnett, S.; Minteer, S. D.; Sigman, M. S.; Sanford, M. S. Physical Organic Approach to Persistent, Cyclable, Low-Potential Electrolytes for Flow Battery Applic…
[cited by applicant]
Sevov, C. S.; Samaroo, S. K.; Sanford, M. S. Cyclopropenium Salts as Cyclable, High-Potential Catholytes in Nonaqueous Media. Adv. Energy Mater. 2017, 7 (5), 1602027. https://doi.org/10.1002/aenm.201602027.
[cited by applicant]
Soloveichik, G. L. Flow Batteries: Current Status and Trends. Chem. Rev. 2015, 115 (20), 11533-11558. https://doi.org/10.1021/cr500720t.
[cited by applicant]
Song, Y.; Zhao, S.; Chen, Y.; Cai, J.; Li, J.; Yang, Q.; Sun, J.; Liu, Z. Enhanced Sulfur Redox and Polysulfide Regulation via Porous VN-Modified Separator for Li—S Batteries. ACS Appl. Mater. Interfaces 2019, 11, 5687-…
[cited by applicant]
Song, Z.; Zhou, H. Towards Sustainable and Versatile Energy Storage Devices: An Overview of Organic Electrode Materials. Energy Environ. Sci. 2013, 6 (8), 2280. https://doi.org/10.1039/c3ee40709h.
[cited by applicant]
Suga, T.; Konishi, H.; Nishide, H. Photocrosslinked Nitroxide Polymer Cathode-Active Materials for Application in an Organic-Based Paper Battery. Chem. Commun. 2007, No. 17, 1730. https://doi.org/10.1039/b618710b.
[cited by applicant]
Sun, Z.; Li, Z.; Gao, L.; Zhao, X.; Han, D.; Gan, S.; Guo, S.; Niu, L. Grafting Benzenediazonium Tetrafluoroborate onto LiNi x Co y Mn z O 2 Materials Achieves Subzero-Temperature High-Capacity Lithium-Ion Storage via a…
[cited by applicant]
Truesdell, B. L.; Hamby, T. B.; Sevov, C. S. General C(Sp 2 )-C(Sp 3 ) Cross-Electrophile Coupling Reactions Enabled by Overcharge Protection of Homogeneous Electrocatalysts. J Am Chem Soc 2020, 142, 5884-5893. https://…
[cited by applicant]
Wahlquist, C. South Australia's Tesla Battery on Track to Make Back a Third of Cost in a Year. The Guardian. Sep. 27, 2018.
[cited by applicant]
Wang, C.; Li, X.; Yu, B.; Wang, Y.; Yang, Z.; Wang, H.; Lin, H.; Ma, J.; Li, G.; Jin, Z. Molecular Design of Fused-Ring Phenazine Derivatives for Long-Cycling Alkaline Redox Flow Batteries. ACS Energy Lett. 2020, 5, 411…
[cited by applicant]
Weber, A. Z.; Mench, M. M.; Meyers, J. P.; Ross, P. N.; Gostick, J. T.; Liu, Q. Redox Flow Batteries: A Review. J. Appl. Electrochem. 2011, 41 (10), 1137-1164. https://doi.org/10.1007/s10800-011-0348-2.
[cited by applicant]
Wei, X.; Pan, W.; Duan, W.; Hollas, A.; Yang, Z.; Li, B.; Nie, Z.; Liu, J.; Reed, D.; Wang, W.; Sprenkle, V. Materials and Systems for Organic Redox Flow Batteries: Status and Challenges. ACS Energy Lett. 2017, 2 (9), 2…
[cited by applicant]
Wei, X.; Xu, W.; Vijayakumar, M.; Cosimbescu, L.; Liu, T.; Sprenkle, V.; Wang, W. TEMPO-Based Catholyte for High-Energy Density Nonaqueous Redox Flow Batteries. Adv. Mater. 2014, 26 (45), 7649-7653. https://doi.org/10.1…
[cited by applicant]
Winsberg, J.; Hagemann, T.; Janoschka, T.; Hager, M. D.; Schubert, U. S. Redox-Flow Batteries: From Metals to Organic Redox-Active Materials. Angew. Chemie—Int. Ed. 2017, 56 (3), 686-711. https://doi.org/10.1002/anie.20…
[cited by applicant]
Winsberg, J.; Hagemann, T.; Muench, S.; Friebe, C.; Häupler, B.; Janoschka, T.; Morgenstern, S.; Hager, M. D.; Schubert, U. S. Poly(Boron-Dipyrromethene)—A Redox-Active Polymer Class for Polymer Redox-Flow Batteries. Ch…
[cited by applicant]
Wu, M.; Jing, Y.; Wong, A. A.; Fell, E. M.; Jin, S.; Tang, Z.; Gordon, R. G.; Aziz, M. J. Extremely Stable Anthraquinone Negolytes Synthesized from Common Precursors. Chem 2020, 6 (6), 1432-1442. https://doi.org/10.1016…
[cited by applicant]
Xiao, P.; Xu, Y. Recent Progress in Two-Dimensional Polymers for Energy Storage and Conversion: Design, Synthesis, and Applications. J. Mater. Chem. A 2018, 6 (44), 21676-21695. https://doi.org/10.1039/C8TA02820F.
[cited by applicant]
Yan, R.; Wang, Q. Redox-Targeting-Based Flow Batteries for Large-Scale Energy Storage. Adv. Mater. 2018, 30 (47), 1802406. https://doi.org/10.1002/adma.201802406.
[cited by applicant]
Yang, B.; Hoober-Burkhardt, L.; Wang, F.; Surya Prakash, G. K.; Narayanan, S. R. An Inexpensive Aqueous Flow Battery for Large-Scale Electrical Energy Storage Based on Water-Soluble Organic Redox Couples. J. Electrochem…
[cited by applicant]
Yang, Z.; Liu, J.; Baskaran, S.; Imhoff, C. H.; Holladay, J. D. Enabling Renewable Energy—and the Future Grid—with Advanced Electricity Storage. JOM 2010, 62 (9), 14-23. https://doi.org/10.1007/s11837-010-0129-0.
[cited by applicant]
Yang, Z.; Tong, L.; Tabor, D. P.; Beh, E. S.; Goulet, M.-A.; De Porcellinis, D.; Aspuru-Guzik, A.; Gordon, R. G.; Aziz, M. J. Alkaline Benzoquinone Aqueous Flow Battery for Large-Scale Storage of Electrical Energy. Adv.…
[cited by applicant]
Yang, Z.; Zhang, J.; Kintner-Meyer, M. C. W.; Lu, X.; Choi, D.; Lemmon, J. P.; Liu, J. Electrochemical Energy Storage for Green Grid. Chem. Rev. 2011, 111 (5), 3577-3613. https://doi.org/10.1021/cr100290v.
[cited by applicant]
Yoo, S. J.; Li, L.-J.; Zeng, C.-C.; Little, R. D. Polymeric Ionic Liquid and Carbon Black Composite as a Reusable Supporting Electrolyte: Modification of the Electrode Surface. Angew. Chemie Int. Ed. 2015, 54 (12), 3744…
[cited by applicant]
Yu, J.; Fan, L.; Yan, R.; Zhou, M.; Wang, Q. A Redox Targeting-Based Aqueous Redox Flow Lithium Battery. ACS Energy Lett. 2018, 3, 2314-2320. https://doi.org/10.1021/acsenergylett.8b01420.
[cited by applicant]
Yu, J.; Wang, X.; Zhou, M.; Wang, Q. A Redox Targeting-Based Material Recycling Strategy for Spent Lithium Ion Batteries. Energy Environ. Sci. 2019, 12 (9), 2672-2677. https://doi.org/10.1039/C9EE01478K.
[cited by applicant]
Zanzola, E.; Dennison, C. R.; Battistel, A.; Peljo, P.; Vrubel, H.; Amstutz, V.; Girault, H. H. Redox Solid Energy Boosters for Flow Batteries: Polyaniline as a Case Study. Electrochim. Acta 2017, 235, 664-671. https://…
[cited by applicant]
Zhang, J.; Corman, R. E.; Schuh, J. K.; Ewoldt, R. H.; Shkrob, I. A.; Zhang, L. Solution Properties and Practical Limits of Concentrated Electrolytes for Nonaqueous Redox Flow Batteries. J. Phys. Chem. C 2018, 122 (15),…
[cited by applicant]
Zhang, J.; Huang, J.; Robertson, L. A.; Assary, R. S.; Shkrob, I. A.; Zhang, L. Elucidating Factors Controlling Long-Term Stability of Radical Anions for Negative Charge Storage in Nonaqueous Redox Flow Batteries. J. Ph…
[cited by applicant]
Zhang, J.; Huang, J.; Robertson, L. A.; Shkrob, I. A.; Zhang, L. Comparing Calendar and Cycle Life Stability of Redox Active Organic Molecules for Nonaqueous Redox Flow Batteries. J. Power Sources 2018, 397, 214-222. ht…
[cited by applicant]
Zhang, J.; Shkrob, I. A.; Assary, R. S.; Tung, S. O.; Silcox, B.; Curtiss, L. A.; Thompson, L.; Zhang, L. Toward Improved Catholyte Materials for Redox Flow Batteries: What Controls Chemical Stability of Persistent Radi…
[cited by applicant]
Zhou, M.; Chen, Y.; Zhang, Q.; Xi, S.; Yu, J.; Du, Y.; Hu, Y.-S.; Wang, Q. Na 3 V 2 (PO 4 ) 3 as the Sole Solid Energy Storage Material for Redox Flow Sodium-Ion Battery. Adv. Energy Mater. 2019, 9 (30), 1901188. https:…
[cited by applicant]
Zhou, M.; Huang, Q.; Pham Truong, T. N.; Ghilane, J.; Zhu, Y. G.; Jia, C.; Yan, R.; Fan, L.; Randriamahazaka, H.; Wang, Q. Nernstian-Potential-Driven Redox-Targeting Reactions of Battery Materials. Chem 2017, 3 (6), 103…
[cited by applicant]
Zhu, Y. G.; Du, Y.; Jia, C.; Zhou, M.; Fan, L.; Wang, X.; Wang, Q. Unleashing the Power and Energy of LiFePO4-Based Redox Flow Lithium Battery with a Bifunctional Redox Mediator. J. Am. Chem. Soc. 2017, 139 (18), 6286-6…
[cited by applicant]
International Searching Authority (ISA/US). International Search Report and Written Opinion. PCT Application No. PCT/US2021/032160. Issued on Oct. 7, 2021. 12 pages.
[cited by applicant]
Wong et al. All-organic storage solids and redox shuttles for redox-targeting flow batteries. ACS Energy Letters, vol. 6, No. 4, Mar. 12, 2021. <URL: https://pubs.acs.org/doi/abs/10.1021/acsenergylett.1c00143>.
[cited by applicant]
European Patent Office. Extended European Search Report for European Application No. 21803125.0, dated Jun. 16, 2025, 9 pages.
[cited by applicant]