Aluminum alloy compositions, articles therefrom, and methods of producing articles therefrom
Systems of weldable wires, powder, and materials comprising an aluminum-magnesium-scandium alloy, and methods for additive manufacturing the alloy are described. The alloy can be additive manufactured in industrial scale. With post treatment, the additive manufactured alloys can have desired properties for aerospace applications.
1. An aluminum-magnesium-scandium alloy having a composition comprising:
Sc greater than or equal to 0.23 and less than or equal to 0.37 weight percent (wt%);
Zr greater than or equal to 0.11 and less than or equal to 0.19 wt%;
Mg greater than or equal to 4.1 and less than or equal to 5.6 wt%;
Mn greater than or equal to 0.2 and less than or equal to 1.0 wt%;
Ti greater than or equal to 0.05 and less than or equal to 0.15 wt%;
each of Si, Fe, Cu, and Zn less than or equal to 0.1 wt%;
with a balance of the composition being Al,
wherein the composition comprises at least one primary particle or domain of Al3(Sc, Zr) having at least one dimension of less than or equal to 20 μm.
2. The alloy of claim 1 , further comprising less than or equal to 0.1 wt % of at least one of Cd, Hg, Ag, B and Li.
3. The alloy of claim 1 , further comprising less than or equal to 0.002 wt % B.
4. The alloy of claim 1 , further comprising less than or equal to 0.0003 wt % Be.
5. The alloy of claim 1 , further comprising less than or equal to 0.05 wt % Si.
6. The alloy of claim 1 , wherein a ratio of Zr to Sc is less than or equal to 0.51, when determined according to the formula:
(Zr wt %/Sc wt %).
7. The alloy of claim 1 , further comprising less than or equal to 0.2 wt % Cr.
8. The alloy of claim 7 , wherein a ratio of Cu to Cr is less than or equal to 0.3, when determined according to the formula: (Cu wt %/Cr wt %).
9. The alloy of claim 2 , wherein a ratio of the combination of Zr and Ti present to Sc is less than or equal to 0.3, when determined according to the formula: ((Zr wt %+Tiw t %)/Sc wt %).
10. The alloy of claim 2 , further comprising at least one trace element less than or equal to 0.05 wt%, and a total amount of trace element less than or equal to 0.15 wt%.
11. The alloy of claim 10 , wherein the at least one trace element is selected from the group consisting of: an element from the lanthanide group, yttrium (Y), niobium (Nb), vanadium (V), hydrogen (H), oxygen (O), nitrogen (N), and any combination thereof.
12. A wire comprising an aluminum-magnesium-scandium alloy having a composition comprising:
Sc greater than or equal to 0.23 and less than or equal to 0.37 wt%;
Zr greater than or equal to 0.11 and less than or equal to 0.19 wt%;
Mg greater than or equal to 4.1 and less than or equal to 5.6 wt%;
Mn greater than or equal to 0.2 and less than or equal to 1.0 wt%;
Ti greater than or equal to 0.05 and less than or equal to 0.15 wt%;
each of Si, Fe, Cu, and Zn less than or equal to 0.1 wt%;
with a balance of the composition being Al;
wherein the composition further comprises less than or equal to 0.0003 wt % Be.
13. The wire of claim 12 , wherein the composition further comprises less than or equal to 0.2 wt % Cr.
14. The wire of claim 12 , wherein the composition further comprises less than or equal to 0.1 wt % of at least one of Cd, Hg, Ag, B, and Li.
15. The wire of claim 12 , wherein the composition further comprises less than or equal to 0.002 wt % B.
16. The wire of claim 12 , wherein the composition further comprises less than or equal to 0.05 wt % Si.
17. The wire of claim 12 , wherein a ratio of Zr to Sc is less than or equal to 0.51, when determined according to the formula: (Zr wt %/Sc wt %).
18. The wire of claim 13 , wherein a ratio of Cu to Cr is less than or equal to 0.3, when determined according to the formula: (Cu wt %/Cr wt %).
19. The wire of claim 12 , wherein a ratio of the combination of Zr and Ti present to Sc is less than or equal to 0.3, when determined according to the formula:
((Zr wt %+Ti wt %)/Sc wt %).
20. The wire of claim 12 , wherein the composition further comprises at least one trace element less than or equal to 0.05 wt%, and a total amount of trace element less than or equal to 0.15 wt%.
21. The wire of claim 20 , wherein the at least one trace element is selected from the group consisting of: an element from the lanthanide group, yttrium (Y), niobium (Nb), vanadium (V), hydrogen (H), oxygen (O), nitrogen (N), and any combination thereof.
22. The wire of claim 12 , wherein the composition comprises at least one primary particle or domain of Al3(Sc, Zr) having at least one dimension of less than or equal to 20 μm.
23. The wire of claim 12 , wherein the wire has an average diameter of less than or equal to 2 mm.
24. The wire of claim 12 , wherein the wire has a spooling cast from 25 to 50 cm and a spooling helix of less than or equal to 0.1 of the spooling cast.
25. The wire of claim 12 , wherein an article formed from the wire has a thickness greater than or equal to 0.05 inch.
26. The wire of claim 25 , wherein at least a portion of the article has a height at least 1000 times greater than a thickness of the same portion of the article.