Transition metal/zeolite SCR catalysts
A method of converting nitrogen oxides in a gas to nitrogen by contacting the nitrogen oxides with a nitrogenous reducing agent in the presence of a zeolite catalyst containing at least one transition metal, wherein the zeolite is a small pore zeolite containing a maximum ring size of eight tetrahedral atoms, wherein the at least one transition metal is selected from the group consisting of Cr, Mn, Fe, Co, Ce, Ni, Cu, Zn, Ga, Mo, Ru, Rh, Pd, Ag, In, Sn, Re, Jr and Pt.
1. A catalyst composition for treating exhaust gas comprising:
a. a small pore first aluminosilicate molecular sieve having a silica-to-alumina ratio of about 8 to about 150, having a first framework selected from AEI, CHA, and AFX, and containing from 0.1 to 10 wt % of Cu, based on the total weight of the molecular sieve, and
b. a second small pore aluminosilicate molecular sieve having a silica-to-alumina ratio of about 8 to about 150, having a second framework selected from AEI, CHA, and AFX, and containing from 0.1 to 10 wt % of Fe, based on the total weight of the molecular sieve,
wherein the catalyst is effective to promote the reaction of NH3 with NOx to form nitrogen and water, selectively.
2. Catalyst composition of claim 1 , wherein the first and second frameworks are the same.
3. The catalyst composition of claim 2 , wherein the first and second frameworks are CHA.
4. The catalyst composition of claim 2 , wherein the first and second frameworks are AEI.
5. The catalyst composition of claim 2 , wherein the first and second frameworks are AFX.
6. The catalyst composition of claim 2 , wherein said catalyst is a washcoat coated on a substrate selected from a metal flow-through substrate, a ceramic flow-through substrate, a wall-flow filter, a sintered metal filter, and a partial filter.
7. The catalyst composition of claim 2 wherein the first small pore aluminosilicate molecular sieve and the second small pore aluminosilicate molecular sieve are present as a mixture.
8. The catalyst composition of claim 1 , wherein the first framework is AEI and the second framework is CHA.
9. The catalyst composition of claim 1 , wherein the first framework is CHA and the second framework is AEI.
10. The catalyst composition of claim 1 , wherein the first framework is AEI and the second framework is AFX.
11. The catalyst composition of claim 1 , wherein the first framework is AFX and the second framework is AEI.
12. The catalyst composition of claim 1 , wherein said catalyst is a washcoat coated on a substrate selected from a metal flow-through substrate, a ceramic flow-through substrate, a wall-flow filter, a sintered metal filter, and a partial filter.
13. The catalyst composition of claim 1 wherein the first small pore aluminosilicate molecular sieve and the second aluminosilicate molecular sieve are present as a mixture.