High throughput methane pyrolysis reactor for low-cost hydrogen production
An apparatus to decompose a hydrocarbon reactant into a gaseous product and a solid product includes a reactor volume, a reservoir of liquid material, a plurality of nozzles connected to the reservoir of liquid material, the plurality of nozzles configured to distribute the liquid material into the reactor volume from the reservoir as a liquid mist, a gas inlet connected to a hydrocarbon gas source to receive hydrocarbon gas reactant, a distributor connected to the inlet to distribute the hydrocarbon gas reactant into the reactor volume, a heat source located adjacent the reactor volume configured to heat the reactor volume, a separator to separate the solid product from the liquid material, a re-circulation path connected between the reactor volume and the reservoir to re-circulate the liquid material from the reactor volume to the reservoir, a gas outlet connected to the reactor volume configured to outlet hydrogen gas from the reactor volume, and at least one filter connected to the gas outlet to remove entrained solid product from the hydrogen gas.
1. An apparatus to decompose a hydrocarbon reactant into a gaseous product and a solid product comprising:
a reactor volume;
a reservoir of liquid metal material;
a plurality of nozzles connected to the reservoir of liquid metal material, the plurality of nozzles configured to distribute the liquid metal material into the reactor volume from the reservoir as a liquid mist to initially contact hydrocarbon gas reactant;
a gas inlet connected to a hydrocarbon gas source to receive the hydrocarbon gas reactant;
a distributor connected to the inlet to distribute the hydrocarbon gas reactant into the reactor volume;
a heat source located next to the reactor volume configured to heat the reactor volume;
a separator to separate the solid product from the liquid metal material;
a re-circulation path connected between the reactor volume and the reservoir to re-circulate the liquid metal material from the reactor volume to the reservoir;
a gas outlet connected to the reactor volume configured to outlet hydrogen gas from the reactor volume; and
at least one filter connected to the gas outlet to remove entrained solid product from the hydrogen gas.
2. The apparatus as claimed in claim 1 , wherein the liquid metal material has a melting point between −40° C. and 1400° C.
3. The apparatus as claimed in claim 1 , wherein the liquid metal material comprises:
a first element of a concentration of up to 90 weight percent, the first element selected from the group consisting of lithium; sodium; calcium; potassium; cadmium; aluminum; antimony; bismuth; cerium; copper; gallium; indium; lanthanum; lead; magnesium; mercury; silver; tin and zinc; and
a second element of a concentration of at least 10 weight percent, the second element selected from the group consisting of nickel; iron; cobalt; manganese; chromium scandium; titanium; vanadium; molybdenum; silicon; tantalum; technetium; tungsten; ruthenium; and palladium.
4. The apparatus as claimed in claim 1 , wherein the liquid metal material comprises one or more components, wherein at least one of the one or more components has an activation energy barrier for hydrocarbon pyrolysis of less than 300 kJ per mole.
5. The apparatus as claimed in claim 1 , wherein the liquid metal material comprises one or more components, wherein a least one of the one or more components has a carbon solubility of at least 1 atomic percent.
6. The apparatus as claimed in claim 1 , wherein the liquid metal material reservoir is positioned adjacent the heat source.
7. The apparatus as claimed in claim 1 , wherein the plurality of nozzles to distribute the liquid metal material comprises a plurality of nozzles configured to produce the mist of liquid metal material that has a surface area to volume ratio greater than 1 cm 2 per 1 cm 3 of reactor volume.
8. The apparatus as claimed in claim 1 , wherein the plurality of nozzles to distribute the liquid metal material comprises a plurality of nozzles configured to produce the mist as liquid droplets having a size of a mass-averaged diameter between 0.1 and 1,000 microns.
9. The apparatus as claimed in claim 1 , where the nozzles comprise a plurality of misting nozzles to produce a mist of liquid metal material in the reactor volume through breakup of a liquid jet.
10. The apparatus as claimed in claim 1 , wherein the nozzles comprise a plurality of misting nozzles to accelerate the breakup of a liquid jet through patterned grooves within the misting nozzles.
11. The apparatus as claimed in claim 1 , wherein the reactor volume is configured to process one of co-current, counter-current, or cross-current flows of hydrocarbon reactant and liquid metal material mist.
12. The apparatus as claimed in claim 1 , wherein the liquid metal material is introduced into the reactor volume through an outlet at the top, side, or bottom of the reactor volume.
13. The apparatus as claimed in claim 1 , wherein the hydrocarbon reactant comprises at least one selected from group consisting of: natural gas, liquefied petroleum gas, gasoline, diesel, kerosene, naphtha, kerosene-based fuel, methane, ethane, propane, butane, pentane, hexane, benzene, xylene, toluene, and any combination thereof; alkynes, alkenes, alkanes, arenes, cyclic compounds, and any combination thereof having a boiling point less than 600° C.