IP Library Granted Patent US 12,128,051
Granted Patent B2
US 12,128,051 · App. 17/961,765 · Granted Oct 29, 2024

Administration and dosage of diaminophenothiazines

Inventors: Claude Michel Wischik (Aberdeen, GB); Bjorn Olaf Schelter (Aberdeen, GB); Damon Jude Wischik (Cambridge, GB); John Mervyn David Storey (Aberdeen, GB)
Assignee: WisTa Laboratories Ltd.
A61K31/5415A23L33/105A23L33/12A23L33/15A23P10/28A23P10/30A61K45/06A61P25/28B65D75/36A23V2002/00B65D2203/02
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Quick Facts
Patent No.
US 12,128,051
App. No.
17/961,765
Granted
Oct 29, 2024
Kind
B2
Abstract

The invention provides novel regimens for treatment of neurodegenerative disorders utilising methylthioninium (MT)-containing compounds. The regimens are based on novel findings in relation to the dosage of MT compounds, and their interaction with symptomatic treatments based on modulation of acetylcholinesterase levels.

Claims (39)

1. A method of therapeutic treatment of a neurodegenerative disorder of protein aggregation in a subject,

which method comprises orally administering two or more times per day to said subject a methylthioninium (MT)-containing compound,

wherein said administration provides a total daily dose of between 0.5 and 20 mg of MT to the subject per day,

wherein the MT-containing compound is a compound of the following formula (“LMTX”):

wherein each of H n A and H n B (where present) are protic acids which may be the same or different,

and wherein p=1 or 2; q=0 or 1; n=1 or 2; (p+q)×n=2,

and wherein said neurodegenerative disorder is selected from the group consisting of: Alzheimer's disease, Pick's disease, progressive supranuclear palsy, frontotemporal dementia (FTD), FTD with parkinsonism linked to chromosome 17, frontotemporal lobar degeneration syndromes, disinhibition-dementia-parkinsonism-amyotrophy complex, pallido-ponto-nigral degeneration, Guam-ALS syndrome, pallido-nigro-luysian degeneration, cortico-basal degeneration, dementia with argyrophilic grains, dementia pugilistica, chronic traumatic encephalopathy, Down's syndrome, subacute sclerosing panencephalitis, Niemann-Pick disease type C, Sanfilippo syndrome type B, a myotonic dystrophy DM1 or DM2, Huntington's disease, spinal bulbar muscular atrophy, dentatorubropallidoluysian atrophy, spinocerebellar ataxias, a TDP-43 proteinopathy which is FTLD-TDP, Parkinson's disease, dementia with Lewy bodies, multiple system atrophy, hereditary cerebral angiopathy, amyotrophic lateral sclerosis, and familial encephalopathy with neuronal inclusion bodies.

2. The method as claimed in claim 1 , wherein the total daily dose of MT is 2 to 15 mg.

3. The method as claimed in claim 1 , wherein;

(a) the compound has the following formula, wherein HA and HB are different mono-protic acids:

or

(b) compound has the following formula, wherein each of H n X is a protic acid:

or

(c) the compound has the following formula, wherein H 2 A is a di-protic acid:

4. The method as claimed in claim 1 , wherein the compound has the following formula and is a bis-monoprotic acid salt:

5. The method as claimed in claim 1 , wherein the or each protic acid is an inorganic acid.

6. The method as claimed in claim 1 , wherein the or each protic acid is an organic acid.

7. The method as claimed in claim 6 , wherein the or each protic acid is selected from the group consisting of H 2 CO 3 , CH 3 COOH, methanesulfonic acid, 1,2-ethanedisulfonic acid, ethanesulfonic acid, naphthalenedisulfonic acid, and p-toluenesulfonic acid.

8. The method as claimed in claim 7 , wherein the compound is LMTM:

9. The method as claimed in claim 8 , wherein said therapeutic treatment with the MT-containing compound comprises a total daily dose of LMTM of 0.8 to 33 mg/day.

10. The method as claimed in claim 9 , wherein said therapeutic treatment with the MT-containing compound comprises a dose of LMTM of 9 mg/day.

11. The method as claimed in claim 1 , wherein the compound is selected from the group consisting of:

12. A method of prophylactic treatment of a neurodegenerative disorder of protein aggregation in a subject,

which method comprises orally administering two or more times per day to said subject a methylthioninium (MT)-containing compound,

wherein said administration provides a total daily dose of between 0.5 and 20 mg of MT to the subject per day,

wherein the MT-containing compound is a compound of the following formula (“LMTX”):

wherein each of H n A and H n B (where present) are protic acids which may be the same or different,

and wherein p=1 or 2; q=0 or 1; n=1 or 2; (p+q)×n=2,

and wherein said neurodegenerative disorder is selected from the list consisting of:

Alzheimer's disease, Pick's disease, progressive supranuclear palsy, frontotemporal dementia (FTD), FTD with parkinsonism linked to chromosome 17, frontotemporal lobar degeneration syndromes, disinhibition-dementia-parkinsonism-amyotrophy complex, pallido-ponto-nigral degeneration, Guam-ALS syndrome, pallido-nigro luysian degeneration, cortico-basal degeneration, dementia with argyrophilic grains, dementia pugilistica, chronic traumatic encephalopathy, Down's syndrome, subacute sclerosing panencephalitis, Niemann-Pick disease, type C, Sanfilippo syndrome type B, a myotonic dystrophy DM1 or DM2, Huntington's disease, spinal bulbar muscular atrophy, dentatorubropallidoluysian atrophy, spinocerebellar ataxias, a TDP-43 proteinopathy which is FTLD-TDP, Parkinson's disease, dementia with Lewy bodies, multiple system atrophy, hereditary cerebral angiopathy, amyotrophic lateral sclerosis, and familial encephalopathy with neuronal inclusion bodies.

13. The method as claimed in claim 1 , wherein the subject has not historically received treatment with an acetylcholinesterase inhibitor or an N-methyl-D-aspartate receptor antagonist.

14. The method as claimed in claim 1 , wherein the subject has historically received treatment with an acetylcholinesterase inhibitor and/or an N-methyl-D-aspartate receptor antagonist, but ceased that medication at least week prior to treatment with the MT-containing compound.

15. The method as claimed in claim 1 , wherein the subject is selected as one who is receiving treatment with an acetylcholinesterase inhibitor and/or an N-methyl-D-aspartate receptor antagonist,

wherein said treatment with the acetylcholinesterase inhibitor and/or an N-methyl-D-aspartate receptor antagonist is discontinued prior to treatment with the MT-containing compound.

16. The method as claimed in claim 2 , wherein the total daily dose of MT is 3 to 10 mg.

17. The method as claimed in claim 9 , wherein the total daily dose of LMTM is 6 to 12 mg/day.

18. The method as claimed in claim 14 , wherein the subject has historically received treatment with an acetylcholinesterase inhibitor and/or an N-methyl-D-aspartate receptor antagonist, but ceased that medication at least 2 weeks prior to treatment with the MT-containing compound.

19. The method as claimed in claim 14 , wherein the subject has historically received treatment with an acetylcholinesterase inhibitor and/or an N-methyl-D-aspartate receptor antagonist, but ceased that medication at least 3 weeks prior to treatment with the MT-containing compound.

20. The method as claimed in claim 14 , wherein the subject has historically received treatment with an acetylcholinesterase inhibitor and/or an N-methyl-D-aspartate receptor antagonist, but ceased that medication at least 4 weeks prior to treatment with the MT-containing compound.

Assignments (2)
CORRECTIVE ASSIGNMENT TO CORRECT THE SIGNATURE DATE OF INVENTOR SCHELTER PREVIOUSLY RECORDED ON REEL 61674 FRAME 748. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT. Recorded Jan 24, 2025
From: WISCHIK, CLAUDE MICHEL; SCHELTER, BJÖRN OLAF; STOREY, JOHN MERVYN DAVID; WISCHIK, DAMON JUDE
To: WISTA LABORATORIES LTD.
Reel/Frame 070004/0216 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 7, 2022
From: WISCHIK, CLAUDE MICHEL; SCHELTER, BJÖRN OLAF; STOREY, JOHN MERVYN DAVID; WISCHIK, DAMON JUDE
To: WISTA LABORATORIES LTD.
Reel/Frame 061674/0748 →
Priority Claims (2)
GB 1612863 · Jul 25, 2016 · national
GB 1710382 · Jun 29, 2017 · national
Continuity (3)
Continuation 17349427 · Jun 16, 2021
Continuation 16320148
Related Publication 20230165877A1 · Jun 1, 2023
Cited By (1)
US 12,310,973