Preparation of recycled polyethylene terephthalate pellets, and bottles formed therefrom
A method for recycling polyethylene terephthalate, including obtaining flakes of polyethylene terephthalate which are re-polymerized using heat and/or a chain extender combined with an anti-yellowing agent to yield an average molecular weight of at least 40,000 Da and a tunable intrinsic viscosity of approximately 0.5 dl/g to 0.8 dl/g. Polyethylene terephthalate pellets are produced having a color deviation of approximately 2.5 or less from the re-polymerized 100 percent post-consumer polyethylene terephthalate flakes as raw material for formation of polyethylene terephthalate products. When compared to available rPET bottles, CIELAB color values show indiscernible color differences with the high quality rPET produced. Consequently, the high-quality rPET pellets produced are capable manufacturing PET bottles with 100% PCR content and a high number of repeated recycling cycles.
1 . A method for recycling polyethylene terephthalate, comprising:
obtaining flakes of polyethylene terephthalate from 100 percent post-consumer polyethylene terephthalate products;
re-polymerizing the 100 percent post-consumer polyethylene terephthalate flakes using heat and/or a chain extender combined with an anti-yellowing agent yielding an average molecular weight of at least 40,000 Da and a tunable intrinsic viscosity of approximately 0.7 dl/g to 0.9 dl/g;
creating recycled polyethylene terephthalate pellets from re-polymerized polyethylene terephthalate having a color deviation of approximately 2.5 or less for formation of polyethylene terephthalate products from the pellets.
2 . The method for recycling polyethylene terephthalate according to claim 1 , wherein the re-polymerizing includes using a chain extender selected in an amount of from 0.1 wt. % to 1% wt. %.
3 . The method for recycling polyethylene terephthalate according to claim 1 , wherein the re-polymerizing includes using a chain extender selected in an amount of from 0.3 wt. % to 0.6 wt. %.
4 . The method for recycling polyethylene terephthalate according to claim 2 , wherein the chain extender includes multiple functional groups the group consisting of epoxy groups, ester groups, benzene groups, isocyanate groups, anhydride groups, oxazoline groups, and glycols.
5 . The method for recycling polyethylene terephthalate according to claim 1 , wherein an acetaldehyde clearance agent is added during the re-polymerizing process.
6 . The method for recycling polyethylene terephthalate according to claim 1 , wherein the formed polyethylene terephthalate pellets are food contact grade with a transparent appearance.
7 . The method for recycling polyethylene terephthalate according to claim 1 , wherein the flakes of polyethylene terephthalate have an intrinsic viscosity from 0.5 to 0.8 dl/g.
8 . The method for recycling polyethylene terephthalate according to claim 1 , wherein the re-polymerizing is performed during a twin screw extrusion process.
9 . The method for recycling polyethylene terephthalate according to claim 8 , wherein the twin screw extrusion process is performed at a temperature of between approximately 240° C. to 260° C.
10 . The method for recycling polyethylene terephthalate according to claim 1 , wherein the method further comprises solid state polymerization.
11 . The method for recycling polyethylene terephthalate according to claim 10 , wherein the solid state polymerization comprises treating the polyethylene terephthalate under a vacuum of 5 Pa to 50 Pa and a temperature from 200° C. to 245° C. for a period of time from 18 hours to 48 hours.
12 . The method for recycling polyethylene terephthalate according to claim 1 , further comprising drying at an elevated temperature prior to creating the recycled polyethylene terephthalate pellets.
13 . The method for recycling polyethylene terephthalate according to claim 1 , wherein the polyethylene terephthalate pellets have polyvinyl chloride in an amount less than approximately 30 ppm, acetaldehyde in an amount less than approximately 1.0 ppm, diethylene glycol in an amount less than approximately 1.5%, and limonene in an amount less than approximately 20 ppb.
14 . The method for recycling polyethylene terephthalate according to claim 1 , further comprising blow molding with the formed polyethylene terephthalate pellets as raw material.
15 . The method for recycling polyethylene terephthalate according to claim 14 , wherein the blow molding is performed at an injection temperature from 250° C. to 300° C., a maximum draw ratio of approximately 14 to 18, and a blow molding pressure of approximately 2.0 MPa to 2.5 MPa.