PROCESS FOR PRODUCING VERY HIGH PURITY HELIUM OR HYDROGEN

1 . A method of purifying a gas composed of a product gas and one or more impurity gases, comprising:

combining a feed stream with a second stream thereby forming a combined feed stream,

introducing the combined feed stream into a pressure swing adsorption device, thereby producing a high purity product gas stream and an off-gas stream, and

introducing the off-gas stream into a membrane separation device, thereby producing a gas stream lean in product gas and a permeate stream.

2 . The method of claim 1 , wherein the second stream is the permeate stream.

3 . The method of claim 1 , wherein the product gas is helium.

4 . The method of claim 1 , wherein the product gas is hydrogen.

5 . The method of claim 3 , further comprising;

introducing the feed stream along with an oxygen-containing stream into a catalytic oxidation unit, thereby producing an oxidized stream, and

combining the oxidized stream with the second stream thereby forming the combined feed stream.

6 . The method of claim 1 , further comprising:

introducing the permeate stream into a second pressure swing adsorption device, thereby producing a product gas stream and a second off-gas stream,

combining a second feed stream with the off-gas stream and the second off-gas stream, thereby forming a combined membrane feed stream, and

Introducing the combined membrane feed stream into the membrane separation device, thereby producing the gas stream lean in product gas and the permeate stream.

7 . The method of claim 6 , wherein the product gas is helium.

8 . The method of claim 6 , wherein the product gas is hydrogen.

9 . The method of claim 6 , further comprising;

introducing the permeate stream along with an oxygen-containing stream into a catalytic oxidation unit, thereby producing an oxidized stream, and

introducing the oxidized stream into the second pressure swing adsorption device, thereby producing the product gas stream and the second off-gas stream.

10 . The method of claim 6 , further comprising;

introducing the combined feed stream along with a second oxygen-containing stream into a second catalytic oxidation unit, thereby producing a second oxidized stream, and

introducing the second oxidized stream into the pressure swing adsorption device, thereby producing the high purity product gas stream and the off-gas stream.

11 . The method of claim 1 , further comprising:

introducing the permeate stream into a second pressure swing adsorption device, thereby producing a product gas stream and a second off-gas stream,

combining a second feed stream with the second off-gas stream, thereby forming a combined membrane feed stream,

introducing the combined membrane feed stream into the membrane separation device, thereby producing the gas stream lean in product gas and the permeate stream, and

introducing the off-gas stream into the second pressure swing adsorption device.

12 . The method of claim 11 , wherein the product gas is helium.

13 . The method of claim 11 , wherein the product gas is hydrogen.

14 . The method of claim 12 , further comprising;

introducing the permeate stream along with an oxygen-containing stream into a catalytic oxidation unit, thereby producing an oxidized stream, and

introducing the oxidized stream into the second pressure swing adsorption device, thereby producing the product gas stream and the second off-gas stream.

15 . The method of claim 11 , further comprising;

introducing the combined feed stream along with a second oxygen-containing stream into a second catalytic oxidation unit, thereby producing a second oxidized stream, and

introducing the second oxidized stream into the pressure swing adsorption device, thereby producing the high purity product gas stream and the off-gas stream.

16 . The method of claim 1 , further comprising:

introducing the permeate stream into a second pressure swing adsorption device, thereby producing a product gas stream and a second off-gas stream,

combining a second feed stream with the second off-gas stream, thereby forming a combined membrane feed stream,

introducing the combined membrane feed stream into the membrane separation device, thereby producing the gas stream lean in product gas and the permeate stream,

introducing the off-gas stream into the second pressure swing adsorption device,

dividing the combined feed stream into a first portion and a second portion,

introducing the second portion into a third pressure swing adsorption device, thereby producing a second product gas stream and a third off-gas stream, and

combining the first portion and the third off-gas stream and introducing the combined stream into the pressure swing adsorption device, thereby producing the high purity product gas stream and the off-gas stream.

17 . The method of claim 16 , wherein the product gas is helium.

18 . The method of claim 16 , wherein the product gas is hydrogen.

19 . The method of claim 17 , further comprising;

introducing the permeate stream along with an oxygen-containing stream into a catalytic oxidation unit, thereby producing an oxidized stream, and

introducing the oxidized stream into the second pressure swing adsorption device, thereby producing the product gas stream and the second off-gas stream.

20 . The method of claim 16 , further comprising;

introducing the combined feed stream along with a second oxygen-containing stream into a second catalytic oxidation unit, thereby producing a second oxidized stream,

dividing the second oxidized stream into a first portion and a second portion,

introducing the second portion into a third pressure swing adsorption device, thereby producing a second product gas stream and a third off-gas stream, and

combining the first portion and the third off-gas stream and introducing the combined stream into the pressure swing adsorption device, thereby producing the high purity product gas stream and the off-gas stream.