Solvents and slurries comprising a poly(carboxylic acid) binder for silicon electrode manufacture
An silicon-containing electrode is formed by coating a silicon-containing slurry onto a conductive current collector. The slurry comprises a binder solution comprising a poly(carboxylic acid) binder dissolved in a mixed solvent system comprising an amide solvent of Formula I, as described herein, and a second solvent which can be water and/or an organic solvent. The binder preferably comprises poly(acrylic acid). The mixed solvent system comprises about 10 to about 99 vol % of the amide solvent of Formula I. The binder solution is utilized as a solvent for a slurry of silicon-containing particles for preparing the silicon-containing electrode. The slurries comprising the mixed solvent system have higher viscosity and are more stable than slurries containing the same concentrations of silicon particles, carbon particles, and binder in water as the sole solvent.
1. A silicon-containing electrode formed by coating a silicon-containing slurry onto a conductive current collector, and drying the resulting coating; wherein the slurry comprises:
a poly(carboxylic acid) binder and a particulate anode active material in a mixed solvent system comprising a first solvent and a second solvent that is miscible with the first solvent; wherein first solvent is an amide of Formula I:
R 1 , R 2 , and R 3 each independently is H, alkyl, alkoxy, or a polyether group;
the second solvent is selected from the group consisting of water, and organic solvent, and a combination thereof;
the first solvent and the second solvent are present in the mixed solvent system in a respective volume ratio of about 99:1 to about 1:9;
the organic solvent comprises one or more material selected from the group consisting of an alcohol, an ether, a nitrile, and an amide that is different from the amide of the first solvent; and
the particulate anode active material comprises silicon-containing particles, or a combination of silicon-containing particles and carbon particles;
wherein the poly(carboxylic acid) binder comprises at least one material selected from the group consisting of poly(aspartic acid), poly(glutamic acid), poly(methacrylic acid), and poly(4-vinylbenzoic acid).
2. The electrode of claim 1 , wherein the slurry comprises about 50 to about 90 percent by weight (wt %) of the anode active material and about 10 to about 50 wt % of the poly(carboxylic acid) binder based on the combined weight of the anode active material and the binder present in the slurry.
3. The electrode of claim 1 , wherein the silicon-containing particles comprise at least one material selected from the group consisting of silicon nanoparticles, carbon coated silicon nanoparticles, and silicon/silicon oxide nanocomposite particles.
4. The electrode of claim 1 , wherein the silicon-containing particles comprise silicon nanoparticles.
5. The electrode of claim 4 , wherein the silicon nanoparticles have a particle size in the range of about 10 to about 200 nm as determined by transmission electron microscopy.
6. The electrode of claim 1 , wherein the slurry comprises about 10 to about 90 wt % of the silicon-containing particles.
7. The electrode of claim 1 , wherein the slurry comprises about 5 to about 85 wt % of the carbon particles.
8. The electrode of claim 7 , wherein the carbon particles comprise at least one material selected from the group consisting of graphite, carbon black, carbon nanotubes, carbon nanofibers, hard carbon, and graphene.
9. The electrode of claim 7 , wherein the carbon particles comprise graphite.
10. The electrode of claim 1 , wherein the anode active material comprises a mixture of the silicon-containing particles and the carbon particles in a respective weight ratio of about 1:9 to about 9:1.
11. The electrode of claim 1 , wherein the mixed solvent comprises about 10 to about 90 vol % N-methylacetamide in water.
12. The electrode of claim 1 , wherein the coating is performed on a reverse comma roll coating apparatus.
13. A lithium electrochemical cell comprising an anode, a cathode, a lithium ion-conducting separator between the anode and the cathode, and a lithium ion-containing electrolyte contacting the anode, the cathode, and the separator; wherein the anode is the electrode of claim 1 .
14. A battery comprising a plurality of electrochemical cells of claim 13 electrically connected together in series, in parallel, or in both series and parallel.
15. A silicon-containing electrode formed by coating a silicon-containing slurry onto a conductive current collector, and drying the resulting coating; wherein the slurry comprises: a poly(carboxylic acid) binder and a particulate anode active material in a solvent comprising about 10 to about 90 vol % N-methylacetamide in water; wherein the particulate anode active material comprises silicon nanoparticles, or a combination of silicon nanoparticles and carbon particles; the slurry comprises 50 to about 90 wt % of the anode active material and about 10 to about 50 wt % of the binder based on the combined weight of the anode active material and binder present in the slurry, and the carbon particles comprise one or more materials selected from the group consisting of graphite, carbon black, carbon nanotubes, carbon nanofibers, hard carbon, and graphene; and wherein the coating is performed on a reverse comma roll coating apparatus;
wherein the poly(carboxylic acid) binder comprises at least one material selected from the group consisting of poly(aspartic acid), poly(glutamic acid), poly(methacrylic acid), and poly(4-vinylbenzoic acid).
16. The electrode of claim 15 , wherein the anode active material comprises a mixture of the silicon nanoparticles and the graphite particles in a respective weight ratio of about 1:9 to about 9:1.
17. A lithium electrochemical cell comprising an anode, a cathode, a lithium ion-conducting separator between the anode and the cathode, and a lithium ion-containing electrolyte contacting the anode, the cathode, and the separator; wherein the anode is the electrode of claim 15 .
18. A battery comprising a plurality of electrochemical cells of claim 17 electrically connected together in series, in parallel, or in both series and parallel.