Spark plug
A spark plug includes a tubular metallic shell, a tubular insulator held in the metallic shell and having an axial hole, a center electrode held at one end of the axial hole, a metallic terminal member held at the other end of the axial hole, and a resistor element disposed between the center electrode and the metallic terminal member in the axial hole and containing glass and an electrically conductive material. The resistor element has a first resistor layer disposed on the center electrode side and closest to the center electrode and containing titanium oxide, and a second resistor layer disposed on the metallic terminal member side in relation to the first resistor layer and whose titanium oxide content is lower than that of the first resistor layer. The titanium oxide content decreases from the center electrode side toward the metallic terminal member side.
1. A spark plug comprising:
a tubular metallic shell;
a tubular insulator held in the metallic shell and having an axial hole extending in an axial direction;
a center electrode held at one end of the axial hole;
a metallic terminal member held at the other end of the axial hole;
a resistor element disposed between the center electrode and the metallic terminal member in the axial hole and containing glass and an electrically conductive material; and
two seal members between which the resistor element is disposed, wherein
the resistor element has:
a titanium oxide containing region which is disposed on a side toward the center electrode and closest to the center electrode and contains titanium oxide; and
a titanium oxide reduced region which is disposed on a side toward the metallic terminal member in relation to the titanium oxide containing region and whose titanium oxide content is lower than that of the titanium oxide containing region or which contains no titanium oxide, and
as a whole, the titanium oxide content of the resistor element decreases from the center electrode side toward the metallic terminal member side.
2. The spark plug according to claim 1 , wherein the titanium oxide content of the titanium oxide containing region is 1 mass % or more and 15 mass % or less.
3. The spark plug according to claim 1 , wherein the resistor element has, as the titanium oxide reduced region, a titanium oxide free region which contains no titanium oxide.
4. The spark plug according to claim 1 , wherein the titanium oxide content of the resistor element decreases stepwise from the center electrode side toward the metallic terminal member side.
5. The spark plug according to claim 1 , wherein the titanium oxide content of the resistor element decreases gradually from the center electrode side toward the metallic terminal member side.
6. The spark plug according to claim 1 , wherein the titanium oxide containing region has a length of 1 mm or more.
7. The spark plug according to claim 1 , wherein an end of the titanium oxide reduced region on the metallic terminal member side is closer to the metallic terminal member than to the metallic shell.
8. A spark plug according to claim 1 , wherein the resistor element contains only titanium oxide having a rutile-type crystal structure.
9. The spark plugs according to claim 1 , further comprising:
another titanium oxide reduced region that contains less titanium oxide than that of the titanium oxide reduced region, wherein
the contents of titanium oxide in the resistor element decreases stepwise from the center electrode side toward the metallic terminal member side.
10. The spark plugs according to claim 9 , wherein
the other titanium oxide reduced region is located between the titanium oxide reduced region and the metallic terminal member.
11. The spark plugs according to claim 1 , wherein the titanium oxide reduced region contains titanium oxide.