IP Library › Granted Patent US 12,384,915
Granted Patent B2
US 12,384,915 · App. 18/004,557 · Granted Aug 12, 2025

Resin tube

Inventors: Tomoaki Hashiguchi (Settsu, JP); Tetsuo Okura (Settsu, JP)
Assignee: KANEKA CORPORATION
C08L67/04A47G21/18C08L2203/18C08L2205/025F16L11/06
View Patent ↗
Loading inventors, assignments & file history…
Monitor This Case
Get email alerts when status or documents change.
Order Certified Copies
Most orders are placed with the USPTO same day — all within 24 business hours.
Order via The Patent Place →
Pre-filled with this patent's details
Quick Facts
Patent No.
US 12,384,915
App. No.
18/004,557
Granted
Aug 12, 2025
Kind
B2
Abstract

Provided is a resin tube containing a poly(3-hydroxyalkanoate) resin component. The poly(3-hydroxyalkanoate) resin component includes at least two poly(3-hydroxyalkanoate) resins differing in types and/or contents of constituent monomers. A 50% fracture energy of the resin tube, as measured by an impact resistance test, is 0.2 J or more.

Claims (21)

1. A resin tube comprising a poly(3-hydroxyalkanoate) resin component, wherein

the poly(3-hydroxy alkanoate) resin component comprises at least two poly(3-hydroxyalkanoate) resins differing in types and/or contents of constituent monomers, and

a 50% fracture energy of the resin tube, as measured by an impact resistance test, is at least 0.2 J.

2. The resin tube according to claim 1 , wherein the poly(3-hydroxyalkanoate) resin component comprises a copolymer of 3-hydroxy butyrate units and other hydroxyalkanoate units.

3. The resin tube according to claim 2 , wherein the poly(3-hydroxyalkanoate) resin component comprises:

a copolymer (A) comprising 3-hydroxybutyrate units and other hydroxyalkanoate units, wherein a content of the other hydroxyalkanoate units in the copolymer (A) is from 1 mol % to 6 mol %; and

a copolymer (B) comprising 3-hydroxybutyrate units and other hydroxyalkanoate units, wherein a content of the other hydroxyalkanoate units in the copolymer (B) is at least 24 mol %.

4. The resin tube according to claim 3 , wherein in the poly(3-hydroxyalkanoate) resin component, a proportion of the copolymer (A) is at least 40 wt %, and a proportion of the copolymer (B) is 60 wt % or less.

5. The resin tube according to claim 2 , wherein an average content of the other hydroxyalkanoate units in total monomer units constituting the poly(3-hydroxyalkanoate) resin component is from 5 mol % to 18 mol %.

6. The resin tube according to claim 2 , wherein the other hydroxyalkanoate units are 3-hydroxyhexanoate units.

7. The resin tube according to claim 1 , wherein a wall thickness of the resin tube is from 0.01 mm to 0.6 mm.

8. The resin tube according to claim 1 , wherein a wall thickness of the resin tube is from 0.7 mm to 10 mm.

9. The resin tube according to claim 5 , wherein the average content of the other hydroxyalkanoate units in total monomer units constituting the poly(3-hydroxyalkanoate) resin component is from 6 mol % to 17 mol %.

10. The resin tube according to claim 5 , wherein the average content of the other hydroxyalkanoate units in total monomer units constituting the poly(3-hydroxyalkanoate) resin component is from 7 mol % to 16 mol %.

11. The resin tube according to claim 4 , wherein, in the poly(3-hydroxyalkanoate) resin component, the proportion of the copolymer (A) is from 40 to 95 wt %, and the proportion of the copolymer (B) is from 5 wt % to 60 wt %.

12. The resin tube according to claim 4 , wherein, in the poly(3-hydroxyalkanoate) resin component, the proportion of the copolymer (A) is from 45 to 80 wt %, and the proportion of the copolymer (B) is from 20 wt % to 55 wt %.

13. The resin tube according to claim 1 , wherein a weight-average molecular weight of the poly(3-hydroxyalkanoate) resin component is from 20×10 4 to 200×10 4 .

14. The resin tube according to claim 1 , wherein the resin tube comprises at least one additional resin in addition to the at least two poly(3-hydroxyalkanoate) resins.

15. The resin tube according to claim 14 , wherein the additional resin is at least one selected from the group consisting of an aliphatic polyester resin and aliphatic-aromatic polyester resin.

16. The resin tube according to claim 14 , wherein a content of the at least one additional resin is 30 parts by weight or less per 100 parts by weight of the total amount of the poly(3-hydroxyalkanoate) resin component.

17. The resin tube according to claim 3 , wherein the content of the other hydroxyalkanoate units in the copolymer (B) is from 24 mol % to 99 mol %.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 8, 2023
From: HASHIGUCHI, TOMOAKI; OKURA, TETSUO
To: KANEKA CORPORATION
Reel/Frame 065494/0685 →
Priority Claims (1)
JP 2020-116980 · Jul 7, 2020 · national
Continuity (1)
Related Publication 20230235170A1 · Jul 27, 2023
References Cited (8)
US 20110171409A1 · Yamashita et al. · 2011 [cited by applicant]
US 20200340020A1 · Arikawa et al. · 2020 [cited by applicant]
US 20210301127A1 · Okura · 2021 [cited by applicant]
JP 2005248117A · 2005 [cited by applicant]
JP 201084143A · 2010 [cited by applicant]
WO WO2019142845A1 · 2019 [cited by applicant]
WO WO2020040093A1 · 2020 [cited by applicant]
International Search Report issued Sep. 7, 2021 in PCT/JP2021/024312, filed on Jun. 28, 2021, 3 pages. [cited by applicant]