Sliding member and method of manufacturing sliding member
To provide a sliding member having improved wear resistance, and a method of manufacturing the sliding member. A femoral head ball according to an aspect of the present disclosure includes a composite ceramic containing alumina and at least one oxide other than alumina. A surface roughness Ra of the sliding surface when the femoral head ball slides against a constituent member constituting an artificial joint is not more than 0.01 μm. The sliding surface includes a plurality of recessed portions each having an opening diameter of not more than 2 μm.
1 . A method for manufacturing a sliding member, the method comprising:
immersing a surface of a base material in a one or more strong acid solution or acid washing the surface of the base material, the base material comprising a composite ceramic, the composite ceramic including an alumina and at least one oxide except alumina, wherein
the composite ceramic comprises from 65 to 96 wt % of alumina and from 4 to 34.4 wt % of zirconia, wherein
the sliding member is an artificial bone head, and
the surface of the base material is configured to be in contact with a member when the artificial bone head and the member are used in a human body, the member being an acetabular cup or a liner.
2 . The method according to claim 1 , further comprising
sanding the surface of the base material before the immersing or the acid washing.
3 . The method according to claim 2 , wherein, after the sanding, a surface roughness Ra of the surface before the immersing or the acid washing is not more than 0.01 μm, and the surface roughness Ra of the surface after the acid washing is also not more than 0.01 μm.
4 . The method according to claim 1 , wherein a recessed portion is formed by the immersing or the acid washing, and the recessed portion is not more than 2 μm in depth from an opening to a bottom.
5 . The method according to claim 1 , wherein, by the immersing or the acid washing, at least 10,000 recessed portions are formed in a sliding surface per square millimeter, the sliding surface being configured to slide against a constituent member constituting an artificial joint.
6 . The method according to claim 1 , wherein the one or more strong acid solution is one or more selected from the group consisting of a hydrochloric acid aqueous solution, a sulfuric acid aqueous solution, and a nitric acid aqueous solution.
7 . The method according to claim 6 , wherein, in the immersing or acid washing, the surface is brought into contact with the hydrochloric acid aqueous solution for no less than 5 minutes.
8 . The method according to claim 6 , wherein, in the immersing or acid washing, the surface is brought into contact with the hydrochloric acid aqueous solution for no less than 30 minutes.
9 . The method according to claim 6 , wherein, in the immersing or acid washing, the surface is brought into contact with the hydrochloric acid aqueous solution for no less than 150 minutes.