Method for pyrolysis of waste material in an industrial process
A method for pyrolysis of a mass of waste material, includes: providing a screw arrangement adapted to supply heat to the mass by mechanical shear; providing a reactor after the screw arrangement, adapted to supply heat to the mass in the absence of oxygen by heating the reactor wall; heating the mass to an exit temperature and increasing the pressure to an exit pressure in the screw arrangement; thermally degrading the mass in the reactor. The mass is brought into an extreme condition at the exit temperature and exit pressure by the screw arrangement, such that during the pressure drop pyrolysis occurs, thereby forming gaseous hydrocarbons within the connecting element.
1. A method for pyrolysis of a mass of waste material, comprising:
providing a screw arrangement adapted to supply heat to said mass by mechanical shear;
providing a connecting element, wherein said connecting element is connected to an exit of said screw arrangement;
providing a reactor downstream of said connecting element, wherein said reactor is adapted to supply heat to said mass in absence of oxygen by heating a reactor wall with an external heat source;
heating said mass in said screw arrangement to an exit temperature such that said mass is at least partially melted;
transporting said mass through said connecting element; and
thermally degrading said mass in said reactor such that carbon-carbon bonds in said mass are broken by pyrolysis and volatile hydrocarbons are formed,
wherein said method further comprises:
increasing a pressure of said mass through said screw arrangement to an exit pressure; and
expanding said mass in said connecting element, with a pressure drop from said exit pressure to a lower pressure;
wherein said mass is brought into an extreme condition at said exit temperature and exit pressure by said screw arrangement, such that during said pressure drop pyrolysis occurs, thereby forming gaseous hydrocarbons within said connecting element.
2. The method according to claim 1 , wherein increasing said pressure through said screw arrangement is such that during said heating in said screw arrangement pyrolysis of said mass is avoided, or such that at most 1% mass percentage of hydrocarbons present in said mass at an entrance of said screw arrangement is converted into gaseous hydrocarbons during said heating in said screw arrangement.
3. The method according to claim 2 , wherein gaseous hydrocarbons released during said heating in said screw arrangement leave said screw arrangement via one or more outlet ports on said screw arrangement.
4. The method according to claim 1 , wherein said method further comprises:
evacuating water vapor, being released from said mass during said heating in said screw arrangement, via a first outlet port on said screw arrangement;
evacuating gases comprising halogens, being released from said mass during said heating in said screw arrangement, via a second outlet port on said screw arrangement;
evacuating gaseous hydrocarbons, being released from said mass during said heating in said screw arrangement, via a third outlet port on said screw arrangement.
5. The method according to claim 1 , wherein said connecting element provides a direct connection between said screw arrangement and said reactor, and said pressure drop is from said exit pressure to a reactor pressure lower than said exit pressure, or
said connecting element provides a connection between said screw arrangement and a buffer tank placed between said screw arrangement and said reactor and said pressure drop is from said exit pressure to a pressure in said buffer tank lower than said exit pressure.
6. The method according to claim 5 , wherein said method further comprises:
transporting said mass through said connecting element, wherein said gaseous hydrocarbons formed during said pressure drop, are carried by a mass flowing towards said reactor or towards said buffer tank.
7. The method according to claim 1 , wherein gaseous hydrocarbons formed in said connecting element during said pressure drop, occur as gas bubbles present within a melted mass.
8. The method according to claim 1 , wherein a pressure difference between said exit pressure and said lower pressure causes said mass to flow, thereby transporting said mass through said connecting element.
9. The method according to claim 1 , wherein said mass of waste material comprises at least 80 mass % of PolyEthylene and/or PolyPropylene, and said exit temperature is higher than 330° C.
10. The method according to claim 1 , wherein said reactor comprises a reservoir adapted to be filled to a filling level with said mass, wherein said reservoir optionally includes a mixing arrangement positioned inside said reservoir and adapted to mix said mass;
no arrangement is present for transporting said mass through said reservoir.
11. The method according to claim 10 , wherein said reactor is operated alternately in a continuous mode and in a batch mode, wherein
in said continuous mode, mass is continuously fed into said reactor during said thermally degrading, and
in said batch mode, no mass is fed into said reactor during said thermally degrading.
12. The method according to claim 1 , wherein during said thermally degrading said reactor wall is heated such that a pyrolysis temperature prevails inside said reactor, wherein said pyrolysis temperature is 50° C. to 150° C. higher than said exit temperature, and
wherein said pyrolysis temperature in said reactor during said batch mode is higher than said pyrolysis temperature during said continuous mode by 60° C. to 100° C.
13. The method according to claim 1 , wherein
said screw arrangement comprises three different outlet ports, adapted to evacuate water vapor, gases comprising halogens, and gaseous hydrocarbons from said screw arrangement;
said connecting element comprises a closed wall and is adapted to transport a mass comprising gaseous hydrocarbons formed during said expanding by allowing said mass to flow through said connecting element in presence of said exit pressure.
14. The method according to claim 1 , wherein said connecting element comprises one or more pipes, and
wherein an inner surface of said one or more pipes is provided with a coating having anti-sticking properties, said coating being adapted to reduce sticking of said mass to said inner surface.
15. Method according to claim 1 , wherein said method further comprises detecting, by means of a measurement, gaseous hydrocarbons being released from said mass in said screw arrangement.