NON-AQUEOUS ELECTROLYTIC SOLUTION SECONDARY BATTERY AND METHOD FOR PRODUCING NON- AQUEOUS ELECTROLYTIC SOLUTION SECONDARY BATTERY
The present disclosure provides a non-aqueous electrolytic solution secondary battery capable of suppressing increase of initial resistance when an isocyanate group-containing compound is added to a non-aqueous electrolytic solution. The non-aqueous electrolytic solution secondary battery according to one embodiment of the present disclosure has: a wound type electrode body in which a positive electrode and a negative electrode are wound with a separator interposed therebetween; and a battery case for housing the wound type electrode body and the non-aqueous electrolytic solution. The relation between a nitrogen element concentration A1 derived from an isocyanate group-containing compound in an outermost circumferential surface 2 a of the wound type electrode body, and a nitrogen element concentration B derived from an isocyanate group-containing compound in an inner region located further in than the outermost circumferential surface of the wound type electrode body, satisfies A1>B.
1 - 7 . (canceled)
8 . A non-aqueous electrolyte secondary battery comprising:
a wound electrode assembly including a positive electrode, a negative electrode, and a separator, the positive electrode and the negative electrode that are wound with the separator interposed between the positive electrode and the negative electrode;
a non-aqueous electrolyte; and
a battery case housing the wound electrode assembly and the non-aqueous electrolyte, wherein
a nitrogen element concentration A1 derived from an isocyanate group-containing compound in an outermost peripheral surface of the wound electrode assembly and a nitrogen element concentration B derived from an isocyanate group-containing compound in an inner region inside the outermost peripheral surface of the wound electrode assembly satisfy a relation of A1 > B.
9 . A non-aqueous electrolyte secondary battery comprising:
a wound electrode assembly including a positive electrode, a negative electrode, and a separator, the positive electrode and the negative electrode that are wound with the separator interposed between the positive electrode and the negative electrode;
a non-aqueous electrolyte; and
a battery case housing the wound electrode assembly and the non-aqueous electrolyte, wherein
a nitrogen element concentration A2 derived from an isocyanate group-containing compound in an inner wall of the battery case and a nitrogen element concentration B derived from an isocyanate group-containing compound in an inner region inside an outermost peripheral surface of the wound electrode assembly satisfy a relation of A2 > B.
10 . The non-aqueous electrolyte secondary battery according to claim 8 , wherein a ratio of the nitrogen element concentration B in the inner region of the wound electrode assembly to the nitrogen element concentration A1 in the outermost peripheral surface of the wound electrode assembly (B/A1) is 0.5 or less.
11 . The non-aqueous electrolyte secondary battery according to claim 9 , wherein a ratio of the nitrogen element concentration B in the inner region of the wound electrode assembly to the nitrogen element concentration A2 in the inner wall of the battery case (B/A2) is 0.5 or less.
12 . The non-aqueous electrolyte secondary battery according to claim 8 , wherein the isocyanate group-containing compound is a compound represented by the chemical formula 1: X—N═C═O or the chemical formula 2: O═C═N—X—N═C═O wherein X represents a C1 to C12 aliphatic hydrocarbon group optionally having a heteroatom, or a C6 to C20 aromatic hydrocarbon group optionally having a heteroatom.
13 . The non-aqueous electrolyte secondary battery according to claim 9 , wherein the isocyanate group-containing compound is a compound represented by the chemical formula 1: X—N═C═O or the chemical formula 2: O═C═N—X—N═C═O wherein X represents a C1 to C12 aliphatic hydrocarbon group optionally having a heteroatom, or a C6 to C20 aromatic hydrocarbon group optionally having a heteroatom.
14 . A method for manufacturing a non-aqueous electrolyte secondary battery, the method comprising the steps of:
applying an isocyanate group-containing compound to an outermost peripheral surface of a wound electrode assembly in which a positive electrode and a negative electrode are wound with a separator interposed between the positive electrode and the negative electrode; and
housing the wound electrode assembly to which the isocyanate group-containing compound is applied and a non-aqueous electrolyte in a battery case, wherein
the isocyanate group-containing compound is a compound represented by the chemical formula 1: X—N═C═O or the chemical formula 2: O═C═N—X—N═C═O wherein X represents a C1 to C12 aliphatic hydrocarbon group optionally having a heteroatom, or a C6 to C20 aromatic hydrocarbon group optionally having a heteroatom.
15 . A method for manufacturing a non-aqueous electrolyte secondary battery, the method comprising the steps of:
applying an isocyanate group-containing compound to an inner wall of a battery case; and
housing a wound electrode assembly in which a positive electrode and a negative electrode are wound with a separator interposed between the positive electrode and the negative electrode and a non-aqueous electrolyte in the battery case to which the isocyanate group-containing compound is applied, wherein
the isocyanate group-containing compound is a compound represented by the chemical formula 1: X—N═C═O or the chemical formula 2: O═C═N—X—N═C═O wherein X represents a C1 to C12 aliphatic hydrocarbon group optionally having a heteroatom, or a C6 to C20 aromatic hydrocarbon group optionally having a heteroatom.