Antifouling coating and use method and use thereof
The present disclosure provides an antifouling coating and a use method and use thereof. In the antifouling coating of the present disclosure, polyaspartic acid ester is an isocyanate curing agent containing a secondary amine structure. An ester group and aliphatic properties in the polyaspartic acid ester can increase wear resistance of the coating. The polyaspartic acid ester is combined with a polyisocyanate-containing prepolymer in a component A to endow the antifouling coating with desirable toughness and elasticity, such that the antifouling coating has excellent impact and abrasion resistance. In the component A, a polydimethylsiloxane structure is introduced into the hydroxypropyl silicone oil-based isocyanate prepolymer. The polydimethylsiloxane structure can generate microphase separation with a polyurea hard segment and migrate to a surface of the coating, thereby reducing surface energy of the coating to reduce an adhesion between fouling organisms and an interface.
1 . An antifouling coating, comprising a component A and a component B that are separately packaged; wherein
the component A comprises an isocyanate prepolymer; and the isocyanate prepolymer comprises a polypropylene glycol (PPG)-based isocyanate prepolymer and a hydroxypropyl silicone oil-based isocyanate prepolymer;
the component B comprises the following raw materials in parts by weight: 30 parts to 50 parts of polyaspartic acid ester and 1.5 parts to 4 parts of a polyaspartic acid powder; and
the component A and the component B have a weight ratio of (58-96):(31.6-54.2).
2 . The antifouling coating according to claim 1 , wherein a preparation method of the PPG-based isocyanate prepolymer comprises the following steps:
mixing PPG with isophorone diisocyanate (IPDI) to conduct first prepolymerization to obtain the PPG-based isocyanate prepolymer; wherein
the PPG and the IPDI have a mass ratio of (180-300):(65.1-137.9); and
the PPG has a weight-average molecular weight of 2,000 to 3,000.
3 . The antifouling coating according to claim 2 , wherein the first prepolymerization is conducted at 80° C. to 85° C. for 2 h to 3 h.
4 . The antifouling coating according to claim 1 , wherein a preparation method of the hydroxypropyl silicone oil-based isocyanate prepolymer comprises the following steps:
mixing hydroxypropyl silicone oil with IPDI to conduct second prepolymerization to obtain the hydroxypropyl silicone oil-based isocyanate prepolymer; wherein
the hydroxypropyl silicone oil and the IPDI have a mass ratio of (160-220):(65.4-112.4); and the hydroxypropyl silicone oil has a weight-average molecular weight of 1,000 to 2,000.
5 . The antifouling coating according to claim 4 , wherein the second prepolymerization is conducted at 80° C. to 85° C. for 2 h to 3 h.
6 . The antifouling coating according to claim 1 , wherein the PPG-based isocyanate prepolymer and the hydroxypropyl silicone oil-based isocyanate prepolymer have a mass ratio of (6-10):(0-4), and the hydroxypropyl silicone oil-based isocyanate prepolymer has a mass of not 0.
7 . The antifouling coating according to claim 2 , wherein the PPG-based isocyanate prepolymer and the hydroxypropyl silicone oil-based isocyanate prepolymer have a mass ratio of (6-10):(0-4), and the hydroxypropyl silicone oil-based isocyanate prepolymer has a mass of not 0.
8 . The antifouling coating according to claim 3 , wherein the PPG-based isocyanate prepolymer and the hydroxypropyl silicone oil-based isocyanate prepolymer have a mass ratio of (6-10):(0-4), and the hydroxypropyl silicone oil-based isocyanate prepolymer has a mass of not 0.
9 . The antifouling coating according to claim 4 , wherein the PPG-based isocyanate prepolymer and the hydroxypropyl silicone oil-based isocyanate prepolymer have a mass ratio of (6-10):(0-4), and the hydroxypropyl silicone oil-based isocyanate prepolymer has a mass of not 0.
10 . The antifouling coating according to claim 5 , wherein the PPG-based isocyanate prepolymer and the hydroxypropyl silicone oil-based isocyanate prepolymer have a mass ratio of (6-10):(0-4), and the hydroxypropyl silicone oil-based isocyanate prepolymer has a mass of not 0.
11 . The antifouling coating according to claim 6 , wherein the PPG-based isocyanate prepolymer and the hydroxypropyl silicone oil-based isocyanate prepolymer have a mass ratio of 9:1 to 6:4.
12 . The antifouling coating according to claim 7 , wherein the PPG-based isocyanate prepolymer and the hydroxypropyl silicone oil-based isocyanate prepolymer have a mass ratio of 9:1 to 6:4.
13 . The antifouling coating according to claim 8 , wherein the PPG-based isocyanate prepolymer and the hydroxypropyl silicone oil-based isocyanate prepolymer have a mass ratio of 9:1 to 6:4.
14 . The antifouling coating according to claim 1 , wherein the polyaspartic acid powder has a weight-average molecular weight of 2,000 to 5,000.
15 . The antifouling coating according to claim 1 , wherein the component B further comprises a catalyst, and the catalyst is one or more selected from the group consisting of dibutyltin dilaurate, triethylamine, and zinc naphthenate.
16 . The antifouling coating according to claim 15 , wherein 0.1 parts by weight to 0.2 parts by weight of the catalyst is used.
17 . A use method of the antifouling coating according to claim 1 , comprising the following steps:
mixing the component A with the component B to obtain the antifouling coating; and
coating the antifouling coating on a substrate and conducting curing.
18 . The use method according to claim 17 , wherein the substrate is prepared by one or more selected from the group consisting of glass, steel, wood, bakelite, and plastic.
19 . The use method according to claim 17 , wherein the curing is conducted at 80° C.±2° C.
20 . The antifouling coating according to claim 1 , wherein the antifouling coating is used in the field of marine antifouling.