Base oil or lubricant additive
The present invention is toward a base oil or lubricant additives, methods of using the same, lubricant compositions including the same, and methods of forming the lubricant compositions. A base oil or lubricant additive has Structure I or Structure II as described herein.
1. A base oil or lubricant additive having the structure:
wherein
R 1 , R 2 , R 3 , and R 4 are independently chosen from —H, —(C 1 -C 5 )hydrocarbyl and —R b ,
the base oil or lubricant additive comprises at least one R b ,
at each occurrence, R b is independently chosen from —C(O)—O—R c , —O—R c , —S—R c , and —NH—R c , and
at each occurrence, R c is independently (C 6 -C 30 )hydrocarbyl that is unsubstituted or substituted with —O—(C 6-20 )aryl, wherein the (C 6 -C 30 )hydrocarbyl is interrupted by 0, 1, 2, 3, 4, or 5 groups independently chosen from —O— and —S—.
2. The base oil or lubricant additive of claim 1 , wherein the base oil or lubricant comprises one and not more than one —R b .
3. The base oil or lubricant additive of claim 1 , wherein R 1 , R 2 , R 3 , and R 4 are independently chosen from —H, methyl, and R b .
4. The base oil or lubricant additive of claim 1 , wherein each occurrence, R b is independently chosen from —C(O)—O—R c .
5. The base oil or lubricant additive of claim 1 , wherein at each occurrence, R c is independently (C 13 -C 15 )alkyl.
6. The base oil or lubricant additive of claim 1 , wherein at each occurrence, R c is independently —((CH 2 —CH 2 )—O) n —CH 3 , wherein n is 1 to 10; —(C 6 -C 30 )alkyl-O-phenyl; or —(C 6 -C 30 )alkyl-O-naphthyl.
7. The base oil or lubricant additive of claim 1 , wherein the base oil or lubricant additive is a lubricant additive.
8. The base oil or lubricant additive of claim 1 , wherein
R 1 , R 2 , R 3 , and R 4 are independently chosen from —H and —R b ,
the base oil or lubricant additive comprises one R b and not more than one R b , and
R b is —C(O)—O—(C 8 )alkyl, —C(O)—O—(C 14 )alkyl, —C(O)—O—(C 22 )alkyl, —C(O)—O—(C 10 )alkyl, or —C(O)—O—(C 15 )alkyl.
9. The base oil or lubricant additive of claim 1 , wherein the base oil or lubricant additive has one of the following structures:
10. The base oil or lubricant additive of claim 1 , wherein the base oil or lubricant additive is ocyl coumalate, tetradecyl coumalate, docosyl coumalate, or 4-tetradecyloxy-6-methyl-2-pyrone.
11. The base oil or lubricant additive of claim 1 , wherein the base oil or lubricant additive is 4-tetradecyloxy-6-methyl-2-pyrone.
12. The base oil or lubricant additive of claim 1 , wherein the base oil or lubricant additive is tetradecyl coumalate.
13. The base oil or lubricant additive of claim 1 , wherein the base oil or lubricant additive exhibits anti-wear properties, friction-reducing properties, or a combination thereof.
14. A lubricant composition comprising:
the base oil or lubricant additive of claim 1 .
15. The lubricant composition of claim 14 , wherein the base oil or lubricant additive is a lubricant additive, wherein the lubricant composition further comprises a base lubricant composition oil.
16. The lubricant composition of claim 15 , wherein the lubricant additive is 0.1 wt % to 20 wt % of the lubricant composition.
17. The lubricant composition of claim 15 , wherein the base lubricant composition oil comprises a mineral oil, a synthetic oil, or a combination thereof.
18. The lubricant composition of claim 17 , wherein the mineral oil is an API Group III mineral oil.
19. A method of forming the lubricant composition of claim 15 , the method comprises:
combining the base oil or lubricant additive with one or more other components to form the lubricant composition of claim 15 .
20. A method of lubricating comprising:
applying a base oil or lubricant additive, or a lubricant composition comprising the same, to an apparatus to lubricate the apparatus, wherein the base oil or lubricant additive has the structure:
wherein
R 1 , R 2 , R 3 , and R 4 are independently chosen from —H, —(C 1 -C 5 )hydrocarbyl and —R b ,
the base oil or lubricant additive comprises at least one R b ,
at each occurrence, R b is independently chosen from —C(O)—O—R c , —O—R c , —S—R c , and —NH—R c , and
at each occurrence, R c is independently (C 6 -C 30 )hydrocarbyl that is unsubstituted or substituted with —O—(C 6-20 )aryl, wherein the (C 6 -C 30 )hydrocarbyl is interrupted by 0, 1, 2, 3, 4, or 5 groups independently chosen from —O— and —S—.