Nickel-based superalloy steel and preparation method thereof
The present disclosure belongs to the technical field of alloy preparation and provides a nickel-based superalloy and a preparation method thereof. In the present disclosure, the nickel-based superalloy includes the following components by mass percentage: C: 0.07% to 0.10%, 0<Si≤1.00%, 0<Mn≤1.50%, P≤0.020%, S≤0.005%, Cr: 19.0% to 23.0%, Ni: 31.0% to 34.5%, 0<Cu≤0.75%, Al: 0.15% to 0.60%, Ti: 0.15% to 0.60%, and Fe as a balance. In terms of mass percentage, Ni is adjusted to 31.0% to 34.5%, while P is controlled at less than or equal to 0.020% and S is controlled at less than or equal to 0.005%, thereby improving mechanical properties. The examples show that the nickel-based superalloy has a tensile strength of greater than or equal to 460 MPa, a specified plastic elongation strength of greater than or equal to 180 MPa, and an elongation at break of greater than or equal to 35%.
1. A preparation method of a nickel-based superalloy, the nickel-based superalloy comprising the following components by mass percentage:
C: 0.07% to 0.10%, 0<Si≤1.00%, 0<Mn≤1.50%, P≤0.020%, S≤0.005%, Cr: 19.0% to 23.0%, Ni: 31.0% to 34.5%, 0<Cu≤0.75%, Al: 0.15% to 0.60%, Ti: 0.15% to 0.60%, and Fe as a balance;
the preparation method comprising the following steps:
subjecting an alloy raw material to roughing, refining, degassing in a vacuum oxygen decarburisation converter (VODC), and pouring sequentially to obtain a steel ingot; and
annealing the steel ingot to obtain the nickel-based superalloy;
wherein the roughing comprises electric-arc furnace (EAF) roughing; and
wherein the EAF roughing comprises melting conducted at 4,800 kV·A to 5,000 kV·A and greater than or equal to 1,620° C., oxidation conducted at 4,500 kV·A to 4,800 kV·A and greater than or equal to 1,650° C., and reduction conducted at 4,500 kV·A to 4,800 kV·A and greater than or equal to 1,650° C.
2. The preparation method according to claim 1 , wherein an obtained melting system has less than or equal to 0.004% of P by mass percentage; an obtained oxidation system has less than or equal to 0.15% of C by mass percentage; and an obtained reduction system has 4.8% to 5.2% of slag and less than or equal to 0.005% of S by mass percentage.
3. The preparation method according to claim 1 , wherein the refining comprises ladle furnace (LF) refining conducted at 2,600 kV·A to 2,800 kV·A and greater than or equal to 1,650° C. for greater than or equal to 30 min under nitrogen blowing at a nitrogen flow rate of 50 L/min to 150 L/min.
4. The preparation method according to claim 1 , wherein the degassing in a VODC is conducted at a vacuum degree of less than 1 mbar.
5. The preparation method according to claim 4 , wherein an obtained degassing system has less than or equal to 30 ppm of O and less than or equal to 1.5 ppm of H by mass percentage.
6. The preparation method according to claim 1 , wherein 15 min to 30 min before the pouring, argon is blown into the degassing system for 2 min to 3 min.
7. The preparation method according to claim 1 , wherein the annealing is conducted by heating to 880° C.±10° C. at 50° C./h to 100° C./h and then holding for 8 h to 12 h.
8. A preparation method of a nickel-based superalloy, wherein the nickel-based superalloy comprises the following components by mass percentage:
C: 0.07% to 0.09%, Si: 0.42% to 0.65%, Mn: 1.0% to 1.40%, P≤0.020%, S≤0.005%, Cr: 19% to 23%, Ni: 31.0% to 34%, Cu: 0.02% to 0.25%, Al: 0.20% to 0.30%, Ti: 0.15% to 0.35%, and Fe as the balance;
the preparation method comprising the following steps:
subjecting an alloy raw material to roughing, refining, degassing in a vacuum oxygen decarburisation converter (VODC), and pouring sequentially to obtain a steel ingot; and
annealing the steel ingot to obtain the nickel-based superalloy;
wherein the roughing comprises electric-arc furnace (EAF) roughing; and
wherein the EAF roughing comprises melting conducted at 4,800 kV·A to 5,000 kV·A and greater than or equal to 1,620° C., oxidation conducted at 4,500 kV·A to 4,800 kV·A and greater than or equal to 1,650° C., and reduction conducted at 4,500 kV·A to 4,800 kV·A and greater than or equal to 1,650° C.
9. The preparation method according to claim 8 , wherein an obtained melting system has less than or equal to 0.004% of P by mass percentage; an obtained oxidation system has less than or equal to 0.15% of C by mass percentage; and an obtained reduction system has 4.8% to 5.2% of slag and less than or equal to 0.005% of S by mass percentage.
10. The preparation method according to claim 8 , wherein the refining comprises ladle furnace (LF) refining conducted at 2,600 kV·A to 2,800 kV·A and greater than or equal to 1,650° C. for greater than or equal to 30 min under nitrogen blowing at a nitrogen flow rate of 50 L/min to 150 L/min.
11. The preparation method according to claim 8 , wherein the degassing in a VODC is conducted at a vacuum degree of less than 1 mbar.
12. The preparation method according to claim 11 , wherein an obtained degassing system has less than or equal to 30 ppm of O and less than or equal to 1.5 ppm of H by mass percentage.
13. The preparation method according to claim 8 , wherein 15 min to 30 min before the pouring, argon is blown into the degassing system for 2 min to 3 min.
14. The preparation method according to claim 8 , wherein the annealing is conducted by heating to 880° C.±10° C. at 50° C./h to 100° C./h and then holding for 8 h to 12 h.