Anode Active Material for Secondary Battery and Method of Preparing the Same
An anode active material for a lithium secondary battery is provided which includes a composite including: a silicon-based material including a lithium silicate; and a lithium-containing phosphate, wherein a peak intensity ratio B/A is 0.01 to 0.5, wherein A is a peak intensity at 2θ=28.5°, and B is a peak intensity at 2θ=22.3°, when an X-ray diffraction (XRD) analysis is performed using a Cu—Kα ray.
1 . An anode active material for a lithium secondary battery, comprising a composite, the composite comprising:
a silicon-based material including a lithium silicate; and
a lithium-containing phosphate,
wherein the anode active material is characterized by an X-ray diffraction (XRD) pattern having peaks at 22.3 and 28.5 °2θ, wherein the peak intensity ratio B/A is 0.01 to 0.5, wherein A is the intensity of the peak at 2θ=28.5°, and B is the intensity of the peak at 2θ=22.3°, wherein the XRD analysis is performed using a Cu—Kα ray.
2 . The anode active material for a lithium secondary battery of claim 1 , having a phosphorus content of 2.5 wt % or less based on a total weight of the anode active material, and a Li/P ratio of 100 or less.
3 . The anode active material for a lithium secondary battery of claim 1 , wherein the lithium silicate includes a compound represented by the following Chemical Formula 1:
Li x Si y O z (1),
wherein 1≤x≤6, 1≤y≤4, and 0<z≤7.
4 . The anode active material for a lithium secondary battery of claim 3 , wherein the lithium silicate includes one or more of LiSiO 4 , Li 2 SiO 3 , Li 2 SiO 5 , Li 2 Si 2 O 5 , Li 4 SiO 4 , and Li 6 Si 2 O 7 .
5 . The anode active material for a lithium secondary battery of claim 1 , wherein the lithium-containing phosphate includes a compound represented by the following Chemical Formula (2):
Li a P b O c (2),
wherein 1≤a≤4, 1≤b≤4, and 0<c≤7.
6 . The anode active material for a lithium secondary battery of claim 5 , wherein the lithium-containing phosphate includes one or more of Li 3 PO 4 and Li 4 P 2 O 7 .
7 . The anode active material for a lithium secondary battery of claim 1 , wherein the anode active material includes a composite having a core-shell structure comprising:
a core comprising the silicon-based material; and
a shell disposed on a surface of the core and comprising the lithium-containing phosphate.
8 . The anode active material for a lithium secondary battery of claim 1 , further comprising amorphous carbon.
9 . The anode active material for a lithium secondary battery of claim 1 , further comprising one or more of natural graphite and artificial graphite.
10 . A method of preparing an anode active material for a lithium secondary battery, the method comprising:
mixing a silicon-based material including a silicon oxide with a lithium precursor during a pre-lithiation process;
treating the silicon-based material with heat to incorporate lithium into the silicon-based material during a doping process thereby generating a lithium silicate; and
adding the silicon-based material doped with lithium to a phosphate during a compounding process.
11 . The method of claim 10 , wherein the phosphate is NaH 2 PO 4 .
12 . The method of claim 10 , wherein the compounding process includes adding the silicon-based material doped with lithium to a cleaning solution containing a phosphate
13 . The method of claim 12 , wherein a molar concentration of the phosphate to the cleaning solution is more than 0.005M and 2.0M or less.
14 . An anode for a lithium second battery comprising the anode active material for a lithium secondary battery of claim 1 .
15 . A lithium secondary battery comprising the anode of claim 14 .