Metal Supported Powder Catalyst Matrix and Processes for Multiphase Chemical Reactions
A catalytic membrane composite that includes porous supported catalyst particles durably enmeshed in a porous fibrillated polymer membrane is provided. The porous fibrillated polymer membrane may be manipulated to take the form of a tube, disc, or diced tape and used in multiphase reaction systems. The supported catalyst particles are composed of at least one finely divided metal catalyst dispersed on a porous support substrate. High catalytic activity is gained by the effective fine dispersion of the finely divided metal catalyst such that the metal catalyst covers the support substrate and/or is interspersed in the pores of the support substrate. In some embodiments, the catalytic membrane composite may be introduced to a stirred tank autoclave reactor system, a continuous flow reactor system, or a Parr Shaker reaction system and used to effect the catalytic reaction.
1 . A reaction system for multiphase reactions having at least three phases, said reaction system comprising:
a stirred tank reaction vessel comprising a rotatable impeller shaft having thereon at least one impeller blade, said catalytic article comprising a porous fibrillated polymer membrane that includes supported catalyst particles durably enmeshed within the porous fibrillated polymer membrane;
a liquid phase comprising at least one liquid phase reactant; and
a gas phase comprising at least one gas phase reactant,
wherein the porous fibrillated polymer membrane is in the form of diced tape.
2 . The reaction system of claim 1 , wherein reaction system is configured for hydrogenation.
3 . The reaction system of claim 1 , wherein the catalytic article is not configured as a contactor.
4 . The reaction system of claim 1 , wherein the impeller blade is pitched.
5 . The reaction system of claim 1 , wherein the liquid phase reactant and the gas phase reactant flow across and through the catalytic article.
6 . The reaction system of claim 1 , wherein the porous fibrillated polymer membrane is insoluble to reactants and products in the multiphase chemical reaction.
7 . The reaction system of claim 1 , wherein the porous fibrillated polymer membrane comprises polytetrafluorethylene (PTFE), poly(ethylene-co-tetrafluoroethylene) (ETFE), ultra-high molecular weight polyethylene (UHMWPE), polyparaxylylene (PPX), polylactic acid, and any combination or blend thereof.
8 . The reaction system of claim 1 , wherein the porous fibrillated polymer membrane comprises polytetrafluoroethylene (PTFE), expanded polytetrafluoroethylene (ePTFE), modified PTFE, or a PTFE copolymer.
9 . The reaction system of claim 1 , wherein the porous fibrillated polymer membrane comprises expanded polytetrafluoroethylene (ePTFE).