IP Library Granted Patent US 12,403,159
Granted Patent B2
US 12,403,159 · App. 18/102,474 · Granted Sep 2, 2025

Therapeutic metal complexes and ligands and methods of making and using the same

Inventors: Joseph Beckman (Corvallis, OR); James Hurst (Beaverton, OR); John Sirois (Corvallis, OR); Chris Beaudry (Corvallis, OR)
Assignee: Oregon State University
A61K33/34A61K31/155A61K31/4545A61K45/06C07F1/08
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Quick Facts
Patent No.
US 12,403,159
App. No.
18/102,474
Granted
Sep 2, 2025
Kind
B2
Abstract

Disclosed herein are compound embodiments that are useful for treating a variety of diseases, particularly neurological diseases, motor neuron diseases, copper deficiency-related diseases, and/or mitochondrial deficiencies. The compound embodiments described herein also can be used in PET methods. Also disclosed herein are embodiments of methods of making and using the compound embodiments, as well as pharmaceutical formulations comprising the disclosed compound embodiments.

Claims (24)

1. A method of treating a motor neuron disease and/or a neurological disease, comprising administering (i) a compound having a structure according to Formula A or (ii) a dosage form containing the compound to a subject in need thereof,

wherein

M is copper or a radioactive isotope thereof;

R 1 is aryl-(R 5 ) n or heteroaryl-(R 5 ) n ;

R 2 is selected from aryl, aryl-(R 6 ) n , or CH 3 ;

each of R 5 and R 6 independently is selected from alkoxy, amine, hydroxyl, nitro, halogen, C(CF 3 ) 3 , or CF 3 ;

n is an integer ranging from 1 to 10; and

each of R 3 and R 4 independently is selected from —N(H)(CH 2 ) n′ CH 3 , —N(H)(CH 2 ) n′ CF 3 , —N [(CH 2 ) n′ CH 3 ] 2 , or —N[(CH 2 ) n′ CF 3 ] 2 , wherein each n′ independently is an integer selected from 0 to 9,

wherein the motor neuron disease and/or a neurological disease is amyotrophic lateral sclerosis (ALS), Parkinson's disease, Menkes disease, Lou Gehrig's disease, primary lateral sclerosis, Kennedy's syndrome, frontal temporal dementia associated with ALS, spinal muscular atrophy, or canine degenerative myelopathy.

2. The method of claim 1 , further comprising administering edaravone or riluzole sequentially or simultaneously with the compound or the dosage form.

3. The method of claim 1 , wherein the subject is a human that carries one or more mutations to a superoxide dismutase gene and the mutation is not or is other than a mutation at a G85, H46, or H48 residue of the superoxide dismutase gene; or wherein the subject is a canine and the canine belongs to a breed susceptible to canine degenerative myelopathy.

4. The method of claim 1 , wherein the compound is administered in a loading dosage ranging from 10 mg/day to 100 mg/day.

5. The method of claim 1 , wherein the compound is administered in a maintenance dosage ranging from 1 mg/day to 50 mg/day.

6. The method of claim 1 , wherein the compound has a structure satisfying one or more of Formulas IIA-IIR:

7. The method of claim 1 , wherein M is Cu, Cu 2+ , 60 Cu 2+ , 61 Cu 2+ , 62 Cu 2+ , 63 Cu 2+ , 64 Cu 2+ , or 65 Cu 2+ .

8. The method of claim 1 , wherein each of R 3 and R 4 is —N(H)(CH 2 ) 2 CF 3 or —N[(CH 2 ) 2 CH 3 ] 2 .

9. The method of claim 1 , wherein the compound is selected from

10. The method of claim 1 , wherein the subject further suffers from a copper deficiency-based disease or mitochondrial deficiency.

11. The method of claim 1 , wherein R 1 is selected from pyrimidinyl-(R 5 ) n , phenyl-(R 5 ) n , pyridyl-(R 5 ) n , or naphthyl-(R 5 ) n .

12. The method of claim 11 , wherein each R 5 independently is selected from chloro, bromo, fluoro, iodo, or nitro; and n is 1.

13. The method of claim 1 , wherein R 1 is selected from PhOH; PhOalkyl; —PhN(R)alkyl wherein R is hydrogen or alkyl; or —Ph(Z) 1-5 wherein each Z independently is Cl, F, Br, I, NO 2 , CF 3 , or C(CF 3 ) 3 .

14. The method of claim 1 , wherein R 1 is selected from —PhOH, —PhOMe, —PhCl, —PhNO 2 , —PhCF 3 , —PhC(CF 3 ) 3 , —PhF 5 , or —PhNMe 2 ; and/or R 2 is CH 3 or phenyl.

15. A method of treating Parkinson's disease, comprising administering (i) a compound having a structure according to Formula A or (ii) a dosage form containing the compound to a subject in need thereof,

wherein M is Cu; R 1 is phenyl; R 2 is methyl; and each of R 3 and R 4 independently is —NHMe.

Assignments (2)
CONFIRMATORY LICENSE Recorded Mar 16, 2023
From: OREGON STATE UNIVERSITY
To: UNITED STATES GOVERNMENT
Reel/Frame 063101/0945 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 2, 2023
From: BECKMAN, JOSEPH; HURST, JAMES; SIROIS, JOHN; BEAUDRY, CHRIS
To: OREGON STATE UNIVERSITY
Reel/Frame 062576/0603 →
Continuity (4)
Division 16802410 · Feb 26, 2020
Continuation PCTUS2018049163 · Aug 31, 2018
Provisional Application 62553714 · Sep 1, 2017
Related Publication 20230172977A1 · Jun 8, 2023
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