Reforming catalyst pattern for fuel cell operated with enhanced CO
A reforming element for a molten carbonate fuel cell stack and corresponding methods are provided that can reduce or minimize temperature differences within the fuel cell stack when operating the fuel cell stack with enhanced CO 2 utilization. The reforming element can include at least one surface with a reforming catalyst deposited on the surface. A difference between the minimum and maximum reforming catalyst density and/or activity on a first portion of the at least one surface can be 20% to 75%, with the highest catalyst densities and/or activities being in proximity to the side of the fuel cell stack corresponding to at least one of the anode inlet and the cathode inlet.
1. A fuel cell stack comprising:
a molten carbonate fuel cell comprising an anode and a cathode;
a reforming element associated with the anode, the reforming element comprising a first surface, the first surface comprising a first portion comprising a reforming catalyst, a reforming catalyst density on the first portion of the first surface comprising a monotonically decreasing catalyst density, the reforming catalyst density on the first portion of the first surface having a difference between a maximum catalyst density and a minimum catalyst density of 20% to 75%, wherein the difference is calculated by subtracting the minimum catalyst density from the maximum catalyst density and then dividing by the maximum catalyst density; and
a separator plate between the anode and the reforming element.
2. The fuel cell stack of claim 1 , wherein the maximum catalyst density is in proximity to an anode inlet, or wherein the maximum catalyst density is in proximity to a cathode inlet.
3. The fuel cell stack of claim 1 , wherein the minimum catalyst density is in proximity to an anode outlet, or wherein the minimum catalyst density is in proximity to a cathode outlet.
4. The fuel cell stack of claim 1 , wherein the first surface further comprises a second portion, the second portion being in proximity to a cathode inlet or in proximity to an anode inlet, the second portion comprising a constant catalyst density.
5. The fuel cell stack of claim 1 , wherein the reforming catalyst comprises parallel lines of catalyst particles.
6. The fuel cell stack of claim 1 , wherein the difference between a maximum catalyst density and a minimum catalyst density is 20% to 40%.
7. The fuel cell stack of claim 1 , wherein the first surface comprises an interior surface of the anode.
8. A fuel cell stack comprising:
a molten carbonate fuel cell comprising an anode and a cathode;
a reforming element comprising a first surface, the first surface comprising a reforming catalyst, a reforming catalyst density on the first surface comprising a monotonically decreasing catalyst density, the reforming catalyst density on the first surface having a difference between a maximum catalyst density and a minimum catalyst density of 20% to 75%, wherein the difference is calculated by subtracting the minimum catalyst density from the maximum catalyst density and then dividing by the maximum catalyst density; and
a separator plate between the anode and the reforming element.
9. The fuel cell stack of claim 8 , wherein the maximum catalyst density is in proximity to an anode inlet, or wherein the maximum catalyst density is in proximity to a cathode inlet.
10. The fuel cell stack of claim 8 , wherein the minimum catalyst density is in proximity to an anode outlet or wherein the minimum catalyst density is in proximity to a cathode outlet.
11. The fuel cell stack of claim 8 , wherein the difference between a maximum catalyst density and a minimum catalyst density is 20% to 50%.
12. The fuel cell stack of claim 8 , wherein the first surface comprises an interior surface of the reforming element.
13. A fuel cell stack comprising:
a molten carbonate fuel cell comprising an anode and a cathode; and
the anode comprising a first surface, the first surface comprising a reforming catalyst, a reforming catalyst density on the first surface comprising a monotonically decreasing catalyst density, the reforming catalyst density on the first surface having a difference between a maximum catalyst density and a minimum catalyst density of 20% to 75%, wherein the difference is calculated by subtracting the minimum catalyst density from the maximum catalyst density and then dividing by the maximum catalyst density.
14. The fuel cell stack of claim 13 , wherein the maximum catalyst density is in proximity to an anode inlet or wherein the maximum catalyst density is in proximity to a cathode inlet.
15. The fuel cell stack of claim 13 , wherein the minimum catalyst density is in proximity to an anode outlet or wherein the minimum catalyst density is in proximity to a cathode outlet.
16. The fuel cell stack of claim 13 , wherein the reforming catalyst comprises parallel lines of catalyst particles.
17. The fuel cell stack of claim 13 , wherein the first surface comprises an interior surface of the anode.
18. The fuel cell stack of claim 8 , wherein the difference between a maximum catalyst density and a minimum catalyst density is 20% to 40%.