Three-dimensional printing with epoxy and amine compounds
The present disclosure is drawn to multi-fluid kits for three-dimensional to printing, three-dimensional printing kits, and methods of making three-dimensional printed articles. In one example, a multi-fluid kit for three-dimensional printing can include a fusing agent, a first reactive agent, and a second reactive agent. The fusing agent can include water and a radiation absorber. The first reactive agent can include a first liquid vehicle and an epoxy compound having multiple epoxide groups. The second reactive agent can include a second liquid vehicle and an amine compound having multiple amino groups.
1. A three-dimensional printing kit, comprising:
a powder bed material comprising polymer particles;
a fusing agent comprising water and a radiation absorber to selectively apply to the powder bed material;
an epoxy compound having multiple epoxide groups, wherein the epoxy compound is present in: a) the powder bed material or b) the fusing agent; and
an amine compound having multiple amino groups, wherein the amine compound is: a) an amino group-containing polymer included in the polymer particles of the powder bed material, b) a non-polymeric amine compound mixed with the polymer particles of the powder bed material, or c) present in the fusing agent,
wherein the amine compound and the epoxy compound are not present together in the powder bed material or the fusing agent.
2. The three-dimensional printing kit of claim 1 , wherein the polymer particles have an average particle size from about 20 pm to about 100 pm and include nylon 6, nylon 9, nylon 11, nylon 12, nylon 66, nylon 612, polyethylene, thermoplastic polyurethane, polypropylene, polyester, polycarbonate, polyether ketone, polyacrylate, polystyrene powder, wax, or a combination thereof.
3. The three-dimensional printing kit of claim 1 , wherein the epoxy compound comprises ethylene glycol diglycidyl ether and tris(4-hydroxyphenyl) methane triglycidyl ether and the amine compound comprises diaminodiphenyl sulfone.
4. The three-dimensional printing kit of claim 1 , wherein the radiation absorber is a metal dithiolene complex.
5. The three-dimensional printing kit of claim 1 , further comprising a detailing agent comprising a detailing compound to selectively apply to the powder bed material.
6. A method of making a three-dimensional printed article using the three-dimensional printing kit of claim 1 , comprising:
iteratively applying individual build material layers of the powder bed material to a powder bed;
based on a three-dimensional object model, selectively jetting the fusing agent onto the individual build material layers; and
exposing the powder bed to energy to selectively fuse the polymer particles in contact with the radiation absorber at individual build material layers.
7. The method of claim 6 , further comprising post-curing the three-dimensional article at a temperature from about 100° C. to about 200° C. for a time from about 30 minutes to about 24 hours.
8. The three-dimensional printing kit of claim 1 , wherein the epoxy compound is 2-ethylhexyl glycidyl ether, phenol glycidyl ether, p-tert-butylphenyl glycidyl ether, dibromo phenyl glycidyl ether, lauryl alcohol glycidyl ether, resorcinol diglycidyl ether, neopentyl glycol diglycidyl ether, 1,6-hexanediol diglycidyl ether, glycerol polyglycidyl ether, trimethylolpropane polyglycidyl ether, pentaerythritol polyglycidyl ether, diglycerol polyglycidyl ether, polyglycerol polyglycidyl ether, sorbitol polyglycidyl ether, diglycidyl terephthalate, diglycidyl o-phthalate, N-glycidyl phthalimide, ethylene glycol diglycidyl ether, polyethylene glycol diglycidyl ether, tris(4-hydroxyphenyl) methane triglycidyl ether, or a combination thereof.
9. The three-dimensional printing kit of claim 1 , wherein the amine compound is aniline sulfonamide, tetraethylenepentamine, diethylaminopropylamine, N-aminoethylpiperazine, bis(2-ethylhexyl)amine, methanediamine, methylphenyl diamine, methylphenylenediamine, diaminodiphenyl sulfone, diethylenetriamine, triethylenetetramine, or a combination thereof.
10. The three-dimensional printing kit of claim 1 , wherein:
the epoxy compound is present in the powder bed material in an amount from about 0.1 wt % to about 10 wt % of a total weight of the powder bed material; and
the amine compound is present in the fusing agent.
11. The three-dimensional printing kit of claim 1 , wherein:
the epoxy compound is present in the fusing agent;
the amine compound is the non-polymeric amine compound mixed with the polymer particles of the powder bed material; and
the amine compound is present in the powder bed material in an amount from about 0.1 wt % to about 10 wt % of a total weight of the powder bed material.