Liquid concentrate fire retardant compositions containing mixtures of ammonium phosphates
Described herein are liquid fire retardant concentrate compositions comprising mixtures of ammonium phosphate fire retardants. Specifically, liquid fire retardant concentrate compositions comprising one or more of monoammonium phosphate (MAP), diammonium phosphate (DAP), and ammonium polyphosphate (APP) are described herein. The ammonium phosphate fire retardant(s) is typically suspended and/or dissolved in a liquid, typically with the fire retardant(s) incorporated into the composition in powder, or granular form. In certain aspects of the present invention, the compositions provided may exhibit one or more advantages as compared to current liquid concentrate fire retardants, including enhanced strength (i.e., a higher proportion of fire retardant component per unit volume), reduced toxicity, and/or reduced corrosion.
1 . A liquid fire retardant solution composition, the composition comprising:
ammonium phosphate-based fire retardants, the fire retardants comprising monoammonium phosphate (MAP) and diammonium phosphate (DAP) in a weight ratio of MAP to DAP of from 40:60 to 60:40;
a suspending agent comprising micronized clay selected from the group consisting of attapulgite clays, kaolinite clays, halloysite clays, bentonite clays, and combinations thereof;
a corrosion inhibitor system comprising a molybdate corrosion inhibitor and/or an azole corrosion inhibitor;
a biopolymer selected from the group consisting of xanthan gum, rhamsan gum, welan gum, diutan gum, and mixtures thereof; and
water, wherein:
the pH of the fire retardant solution is from about 4.0 to about 8.0; and
the weight ratio of suspending agent to biopolymer is from 1:1 to 4:1.
2 . The composition of claim 1 wherein the pH of the fire retardant solution is from about 6.0 to about 8.0.
3 . The composition of claim 1 wherein the pH of the fire retardant solution is from about 6.0 to about 7.0.
4 . The composition of claim 1 wherein the fire retardants are incorporated as powdered fire retardant(s).
5 . The composition of claim 1 wherein the fire retardants comprise MAP and DAP in a weight ratio of MAP to DAP of from 45:55 to 55:45.
6 . The composition of claim 1 wherein the molybdate corrosion inhibitor comprises sodium molybdate and the azole corrosion inhibitor comprises tolytriazole and/or benzotriazole.
7 . The composition of claim 1 comprising less than about 2% by weight of micronized clay.
8 . The composition of claim 1 comprising less than about 1% by weight of micronized clay.
9 . The composition of claim 1 wherein the micronized clay is selected from the group consisting of attapulgite clays, kaolinite clays, and combinations thereof.
10 . The composition of claim 1 wherein the biopolymer is selected from the group consisting of xanthan gum, diutan gum, and mixtures thereof.
11 . The composition of claim 10 wherein the weight ratio of micronized clay to biopolymer is from about 1:1 to about 3:1.
12 . The composition of claim 1 further comprising a pigment or a dye.
13 . The composition of claim 1 further comprising a fugitive color system.
14 . The composition of claim 1 wherein the composition exhibits an aluminum corrosion rate equal to or less than 2.0 milli-inches or less than 1.0 milli-inches per year; and/or exhibits a mild steel corrosion rate equal to or less than 5.0 milli-inches per year; and/or exhibits a brass corrosion rate equal to or less than 5.0 milli-inches per year.
15 . The composition of claim 1 wherein the composition meets one or more of the required criteria for of U.S. Department of Agriculture, Forest Service, Specification Number 5100-304d, January 2020, including any and all amendments.
16 . The composition of claim 1 wherein the composition:
meets one or more of the required criteria for corrosion and/or stability of U.S. Department of Agriculture, Forest Service, Specification Number 5100-304d, January 2020, including all amendments; and/or
meets all of the required criteria for corrosion of U.S. Department of Agriculture, Forest Service, Specification Number 5100-304d, January 2020, including all amendments; and/or
meets all of the required criteria for stability of U.S. Department of Agriculture, Forest Service, Specification Number 5100-304d, January 2020, including all amendments; and/or
meets all of the required criteria for corrosion and stability of U.S. Department of Agriculture, Forest Service, Specification Number 5100-304d, January 2020, including all amendments; and/or
meets all of the required criteria of U.S. Department of Agriculture, Forest Service, Specification Number 5100-304d, January 2020, including all amendments.
17 . The composition of claim 1 wherein the composition exhibits a viscosity in the range of from about 100 cPs to about 1500 cPs, when measured in accordance with Specification 5100-304d, January 2020, including any and all amendments.
18 . A liquid fire retardant solution composition, the composition comprising:
ammonium phosphate-based fire retardants, the fire retardants comprising monoammonium phosphate (MAP) and diammonium phosphate (DAP) in a weight ratio of MAP to DAP of from 40:60 to 60:40;
a suspending agent comprising micronized clay selected from the group consisting of attapulgite clays, kaolinite clays, halloysite clays, bentonite clays, and combinations thereof, wherein the suspending agent constitutes from about 0.25% to about 0.75% by weight of the solution;
a corrosion inhibitor system comprising a molybdate corrosion inhibitor and an azole corrosion inhibitor;
a biopolymer selected from the group consisting of xanthan gum, rhamsan gum, welan gum, diutan gum, and mixtures thereof; and
water, wherein:
the weight ratio of suspending agent to biopolymer is from 1:1 to 3:1; and
the composition meets all of the required criteria for corrosion and stability of U.S. Department of Agriculture, Forest Service, Specification Number 5100-304d, January 2020, including all amendments.
19 . A liquid fire retardant solution composition, the composition comprising:
ammonium phosphate-based fire retardants, the fire retardants comprising monoammonium phosphate (MAP) and diammonium phosphate (DAP) in a weight ratio of MAP to DAP of from 40:60 to 60:40;
a suspending agent comprising micronized clay selected from the group consisting of attapulgite clays, kaolinite clays, halloysite clays, bentonite clays, and combinations thereof, wherein the suspending agent constitutes from about 0.25% to about 0.75% by weight of the solution;
a corrosion inhibitor system comprising a molybdate corrosion inhibitor and an azole corrosion inhibitor;
a biopolymer selected from the group consisting of xanthan gum, rhamsan gum, welan gum, diutan gum, and mixtures thereof; and
water, wherein:
the weight ratio of suspending agent to biopolymer is from 1:1 to 3:1; and
the composition meets all of the required criteria of U.S. Department of Agriculture, Forest Service, Specification Number 5100-304d, January 2020, including all amendments.