IP Library Granted Patent US 12,080,444
Granted Patent B2
US 12,080,444 · App. 18/158,154 · Granted Sep 3, 2024

Conductive composite material

Inventors: Hiroyuki Morita (Nagaokakyo, JP); Kosuke Sugiura (Nagaokakyo, JP); Masanori Abe (Nagaokakyo, JP); Akari Seko (Nagaokakyo, JP)
Assignee: MURATA MANUFACTURING CO., LTD.
H01B1/22B05D5/12H01B1/24
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Quick Facts
Patent No.
US 12,080,444
App. No.
18/158,154
Granted
Sep 3, 2024
Kind
B2
Abstract

A conductive composite material that includes: particles of a layered material including one or plural layers, wherein the one or plural layers include a layer body represented by: M m X n , where M is at least one metal of Group 3, 4, 5, 6, or 7, X is a carbon atom, a nitrogen atom, or a combination thereof, n is not less than 1 and not more than 4, m is more than n but not more than 5, and a modifier or terminal T exists on a surface of the layer body, where T is at least one of a hydroxyl group, a fluorine atom, a chlorine atom, an oxygen atom, or a hydrogen atom; and a polymer material that includes a hydrogen acceptor and a hydrogen donor, a ratio of the particles of the layered material is more than 19% by volume but not more than 95% by volume.

Claims (36)

1. A conductive composite material comprising:

particles of a layered material including one or plural layers, wherein the one or plural layers include a layer body represented by:

M m X n

 where M is at least one metal of Group 3, 4, 5, 6, or 7,

X is a carbon atom, a nitrogen atom, or a combination thereof,

n is not less than 1 and not more than 4,

m is more than n but not more than 5, and

a modifier or terminal T exists on a surface of the layer body, where T is at least one selected from the group consisting of a hydroxyl group, a fluorine atom, a chlorine atom, an oxygen atom, or a hydrogen atom; and

a polymer material that includes a hydrogen acceptor that is at least one selected from the group consisting of a fluorine atom, a chlorine atom, an oxygen atom, or a nitrogen atom; and a hydrogen donor that is a hydroxyl group and/or a secondary amino group,

wherein a ratio of the particles of the layered material to the conductive composite material is more than 19% by volume but not more than 95% by volume, and

wherein the polymer material is one or more of polyethylenimine, polypyrrole, polyaniline, polyimide containing a secondary amino group, polyamide imide, polyacrylamide, nylon, deoxyribonucleic acid, acetanilide, and acetaminophen.

2. The conductive composite material according to claim 1 , wherein a hydrogen acceptor of the layer body is at least one selected from the group consisting of the fluorine atom, the chlorine atom, or the oxygen atom; and a hydrogen donor of the layer body is the hydroxyl group and/or a hydrogen atom.

3. The conductive composite material according to claim 1 , wherein the M is at least one selected from the group consisting of Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, or Mn.

4. The conductive composite material according to claim 1 , wherein the M is at least one selected from the group consisting of Ti, V, Cr, or Mo.

5. The conductive composite material according to claim 1 , wherein the layer body includes at least one selected from the group consisting of Ti 3 C 2 , Ti 3 CN, or Ti 2 C.

6. The conductive composite material according to claim 1 , wherein the ratio of the particles of the layered material to the conductive composite material is 30% by volume to 75% by volume.

7. The conductive composite material according to claim 1 , wherein the conductive composite material is in a coating film form.

8. The conductive composite material according to claim 1 , wherein the conductive composite material has an electrical conductivity of 280 S/cm or more.

9. A conductive composite material comprising:

particles of a layered material including one or plural layers, wherein the one or plural layers include a layer body represented by:

M m X n

 where M is at least one metal of Group 3, 4, 5, 6, or 7,

X is a carbon atom, a nitrogen atom, or a combination thereof,

n is not less than 1 and not more than 4,

m is more than n but not more than 5, and

a modifier or terminal T exists on a surface of the layer body, where T is at least one selected from the group consisting of a hydroxyl group, a fluorine atom, a chlorine atom, an oxygen atom, or a hydrogen atom; and

a polymer material that includes a hydrogen acceptor that is at least one selected from the group consisting of a fluorine atom, a chlorine atom, an oxygen atom, or a nitrogen atom; and a hydrogen donor that is a hydroxyl group and/or a secondary amino group,

wherein a ratio of the particles of the layered material to the conductive composite material is more than 19% by volume but not more than 95% by volume, and

wherein the polymer material is one or more of a polyether-based polyurethane, a polycarbonate-based polyurethane, and a polyester-based polyurethane.

10. The conductive composite material according to claim 9 , wherein a hydrogen acceptor of the layer body is at least one selected from the group consisting of the fluorine atom, the chlorine atom, or the oxygen atom; and a hydrogen donor of the layer body is the hydroxyl group and/or a hydrogen atom.

11. The conductive composite material according to claim 9 , wherein the M is at least one selected from the group consisting of Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, or Mn.

12. The conductive composite material according to claim 9 , wherein the M is at least one selected from the group consisting of Ti, V, Cr, or Mo.

13. The conductive composite material according to claim 9 , wherein the layer body includes at least one selected from the group consisting of Ti 3 C 2 , Ti 3 CN, or Ti 2 C.

14. The conductive composite material according to claim 9 , wherein the ratio of the particles of the layered material to the conductive composite material is 30% by volume to 75% by volume.

15. The conductive composite material according to claim 9 , wherein the conductive composite material is in a coating film form.

16. The conductive composite material according to claim 9 , wherein the conductive composite material has an electrical conductivity of 280 S/cm or more.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 23, 2023
From: MORITA, HIROYUKI; SUGIURA, KOSUKE; ABE, MASANORI; SEKO, AKARI
To: MURATA MANUFACTURING CO., LTD.
Reel/Frame 062454/0385 →
Priority Claims (1)
JP 2020-131866 · Aug 3, 2020 · national
Continuity (2)
Continuation PCTJP2021028610 · Aug 2, 2021
Related Publication 20230154642A1 · May 18, 2023
Cited By (1)
US 12,473,424