Methods for producing an etch resist pattern on a metallic surface
Methods and composition sets for forming etch-resist masks on a metallic surface are provided. The method may include depositing a first aqueous composition comprising a first reactive component onto a metallic layer of a substrate; depositing a second aqueous composition comprising a second reactive component on selected portions of the deposited first aqueous composition to form, from a chemical reaction between the first reactive component and the second reactive component, a bi-component material mask in a pattern to protect selected regions of the metallic layer; and depositing an etch solution to remove the metallic layer in regions not protected by the bi-component material mask.
1. A method comprising:
depositing a first aqueous composition comprising a first reactive component comprising a reactive polymer, a long-chain quaternary amine, or a metal cation onto a substrate;
depositing a second aqueous composition comprising a second reactive component comprising an anionic material onto the substrate, wherein, upon contact between the first aqueous composition and the second aqueous composition, the first reactive component chemically reacts with the second reactive component to form an immobilized bi-component mask, wherein one or more of depositing the first aqueous composition and depositing the second aqueous composition is a patterned deposition comprising non-impact printing, and one or more of the first aqueous composition and the second aqueous composition is deposited directly onto a metallic layer of the substrate;
removing unreacted portions of the first aqueous composition, the second aqueous composition, or both to expose portions of the metallic layer; and
depositing an etch solution to remove the exposed portions of the metallic layer.
2. The method of claim 1 , wherein the first reactive component is a fixating reactive component and the second reactive component is an etch-resist reactive component.
3. The method of claim 1 , wherein the first reactive component is an etch-resist reactive component and the second reactive component is a fixating reactive component.
4. The method of claim 1 , wherein:
the first reactive component comprises at least one imine group, at least one amine group, or both; and
the anionic material comprises at least one phosphate group, at least one sulfonate group, at least one acrylate group, or any combination thereof.
5. The method of claim 1 , wherein at least one of the first reactive component and the second reactive component comprises a polymer.
6. The method of claim 1 , wherein the bi-component mask is insoluble in at least one of water and the etch solution.
7. The method of claim 1 , wherein the first and second aqueous compositions are deposited on the substrate sequentially in a first deposition and a second deposition, and further comprising drying the material deposited in the first deposition before performing the second deposition.
8. The method of claim 1 , wherein the removing the unreacted portions and depositing of the etch solution are performed concurrently.
9. The method of claim 1 , further comprising removing the bi-component mask after depositing the etch solution.
10. The method of claim 1 , wherein the patterned deposition comprises inkjet printing.
11. The method of claim 1 , wherein the metallic layer comprises copper.
12. The method of claim 1 , wherein at least one of the first aqueous composition and the second aqueous composition further comprises a dye.
13. The method of claim 1 , wherein both the first and the second aqueous compositions are deposited by inkjet printing.
14. The method of claim 1 , wherein:
the first reactive component comprises a first reactive polymer and the second reactive component comprises a second reactive polymer.
15. The method of claim 14 , wherein the first reactive polymer comprises one or more of a polyethyleneimine, a heteropolymer of vinyl pyrrolidone, a poly-quaternary amine, and a polyamine in a natural form or as an ammonium salt.
16. The method of claim 14 , wherein the second reactive polymer comprises one or both of acrylate and styrene acrylate.
17. The method of claim 1 , wherein depositing the first aqueous composition comprises depositing the first aqueous composition as a continuous coating on the metallic layer.
18. The method of claim 1 , wherein, in a dried state, a thickness of the bi-component mask ranges from 0.01 μm to 12 μm.
19. A method comprising:
depositing a first aqueous composition comprising a first reactive component directly onto a metallic layer of a substrate;
depositing a second aqueous composition comprising a second reactive component onto the substrate in contact with the first aqueous composition, wherein upon contact the first and the second reactive components undergo a chemical reaction to form an immobilized bi-component mask, wherein depositing the first aqueous composition comprises non-impact printing, depositing the second aqueous composition comprises non-impact printing, or both;
removing unreacted material from the substrate to expose portions of the metallic layer; and
applying an etch solution to the substrate to remove the exposed portions of the metallic layer,
wherein each of the first and second reactive components comprises a material chosen from the group consisting of reactive polymers, long-chain quaternary amines, a metal cation, and an anionic component.